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991.
Environmental impact of heavy-metal dispersion in the Huerva River (Iberian Range,NE Spain) 总被引:1,自引:0,他引:1
P. Acero J. Mandado J. Gómez M. Gimeno L. Auqué F. Torrijo 《Environmental Geology》2003,43(8):950-956
In this study, the methodology of geochemical prospecting has been applied to the study of cadmium, lead, copper and zinc dispersion in the fine sediments of the upper course of the Huerva River (Iberian Range, NE Spain). The survey was organised in two stages: (1) general sampling along the river and its tributary channels, aimed at selecting the sections with the highest contents of the target elements, and (2) detailed study of those sections, aimed at an interpretation of possible positive geochemical anomalies and identification of their sources. The results of this study prove the existence of multiple and complex sources, with a significant influence of sources related to anthropogenic activity. However, the system shows a good ability to depurate itself under current conditions. 相似文献
992.
Summary ¶Rock zones containing a high fracture density and/or soft, low cohesion materials can be highly problematic when encountered during tunnel excavation. For example in the eastern Aar massif of central Switzerland, experiences during the construction of the Gotthard highway tunnel showed that heavily fractured areas within shear zones were responsible for overbreaks in the form of chimneys several metres in height. To understand and estimate the impact of the shear zones on rock mass behaviour, knowledge concerning the rock mass strength and deformation characteristics is fundamental. A series of laboratory triaxial tests, performed on samples from granite- and gneiss-hosted shear zones revealed that with increasing degree of tectonic overprint, sample strength decreases and rock behaviour shows a transition from brittle to ductile deformation. These trends may be explained by increasing fracture densities, increasing foliation intensity, increasing thickness of fine-grained, low cohesion fracture infill, and increasing mica content associated with the increasing degree of tectonic overprint. As fracture density increases and the influence of discrete, persistent discontinuities on rock mass strength decreases, behaviour of the test samples becomes more and more representative of rock mass behaviour, i.e. that of a densely fractured continuum. For the purpose of numerical modeling calculations, the shear zones may be subdivided with respect to an increasing fracture density, foliation intensity and mica content into a strongly foliated zone, a fractured zone and a cohesionless zone, which in turn exhibit brittle, brittle-ductile and ductile rock mass constitutive behaviour, respectively.Received December 17, 2001; accepted January 9, 2003
Published online April 29, 2003 相似文献
993.
994.
Kinetic study of the dehydroxylation of chrysotile asbestos with temperature by in situ XRPD 总被引:6,自引:0,他引:6
The kinetics of the dehydroxylation of chrysotile was followed in situ at high temperature using real-time conventional and
synchrotron powder diffraction (XRPD). This is the first time kinetics parameters have been calculated for the dehydroxylation
of chrysotile. The value of the order of the reaction mechanism calculated using the Avrami model indicates that the rate-limiting
step of the reaction is a one-dimensional diffusion with an instantaneous nucleation or a deceleratory rate of nucleation
of the reaction product. Hence, the rate-limiting step is the one-dimensional diffusion of the water molecules formed in the
interlayer region by direct condensation of two hydrogen atoms and an oxygen atom. The calculated apparent activation energy
of the reaction in the temperature range 620–750 °C is 184 kJ mol−1. The diffusion path is along the axis of the fibrils forming the fibers. The amorphous or short-range ordered dehydroxylate
of chrysotile is extremely unstable because forsterite readily nucleates in the Mg-rich regions. Moreover, it is less stable
than the dehydroxylate of kaolinite, the so-called metakaolinite, which forms mullite at about 950 °C. This difference is
interpreted in terms of the different nature of the two ions Mg2+ and Al3+ and their function as glass modifier and glass-forming ion, respectively.
Received: 10 April 2002 / Accepted: 7 January 2003
Acknowledgements This work is part of a COFIN project (04 Scienze della Terra, NR 17, 2000) supported by MURST. Dr Dapiaggi is kindly acknowledged
for help during the data collection at the Dipartimento di Scienze della Terra, University of Milan. 相似文献
995.
Is Prediction of Future Landslides Possible with a GIS? 总被引:5,自引:0,他引:5
Fabbri Andrea G. Chung Chang-Jo F. Cendrero Antonio Remondo Juan 《Natural Hazards》2003,30(3):487-503
This contribution explores a strategy for landslide hazard zonation inwhich layers of spatial data are used to represent typical settings inwhich given dynamic types of landslides are likely to occur. Theconcepts of assessment and prediction are defined to focus on therepresentation of future hazardous events and in particular on themyths that often provide obstacles in the application of quantitativemethods. The prediction rate curves for different applications describethe support provided by the different data layers in experiments inwhich the typical setting of hazardous events is approximated bystatistically integrating the spatial information. 相似文献
996.
Compositional Geometry and Mass Conservation 总被引:1,自引:0,他引:1
Robert F. Shurtz 《Mathematical Geology》2003,35(8):927-937
A geometrical structure is imposed on compositional data by physical and chemical laws, principally mass conservation. Therefore, statistical or mathematical investigation of possible relations between data values and such laws must be consistent with this structure. This demands that geometrical concepts, such as points that specify both mass and composition in linear space, and lines in projective space that specify composition only, be clearly defined and consistent with mass conservation. Mass thus becomes the norm in composition space in place of the Euclidean norm of ordinary space. Coordinate transformations inconsistent with this geometry are accordingly unnatural and misleading. They are also unnecessary because correlation arising from the constant mass presents no unusual difficulty in the analysis of the underlying quadratic form. 相似文献
997.
Hazard Zoning for Landslides Connected to Torrential Floods in the Jerte Valley (Spain) by using GIS Techniques 总被引:2,自引:0,他引:2
Carrasco R.M. Pedraza J. Martin-Duque J.F. Mattera M. Sanz M.A. Bodoque J.M. 《Natural Hazards》2003,30(3):361-381
The Jerte Valley is anortheast-southwest tending graben located in the mountainous region of west central Spain (Spanish Central System). Mass movements have been a predominant shaping process on the Valley slopes during the Quaternary. Present day activity is characterized as either `first-time failure' (shallow debris slides and debris flows) or `reactivations' of pre-existing landslides deposits.A delineation of landslide hazard zoningwithin the Valley has been carried out by using the detailed documentation of a particular event (a debris slide and a sequel torrential flood, which occurred on the Jubaguerra stream gorge), and GIS techniques. The procedure has had four stages, which are: (1) the elaboration of a susceptibility map (spatial prediction) of landslides; (2) the elaboration of a map of `restricted susceptibility' in the particular case of slopes that are connected to streams and torrents (gorges); (3) the elaboration of a digital model which relates the altitude to the occurrence probability of those particular precipitation conditions which characterized the Jubaguerra event and (4) the combination of the probability model with the `restricted susceptibility map', to establish `critical zones' or areas which are more prone to the occurrence of phenomena that have same typology as this one. 相似文献
998.
Philippe Telouk Estelle F. Rose-Koga Francis Albarede 《Geostandards and Geoanalytical Research》2003,27(1):5-11
Preliminary results are given from an excimer 157 nm laser ablation multiple-collector inductively coupled plasma-mass spectrometer (LA-MC-ICP-MS), used for the isotopic measurements of solid materials. Elements of geological interest with different volatilities such as Pb and U (e.g. zircon geochronology) and Cu and Zn (as examples of geochemical/biochemical tracers) were analysed. The range of ablation rates of 20-150 nm s-1 enabled us to ablate the sample down to a depth of 45 μm for a 50 μm diameter pit. The Cu and Zn isotopic measurements gave values that were very stable with, on average, a 0.01 % standard error, comparable with that achieved in liquid mode measurements. 相似文献
999.
ABSTRACT Maar craters often contain exceptionally preserved fossils and maar sediments may reflect detailed environmental changes. Volcanosedimentary processes in a Middle Eocene maar crater lake are illustrated by the deposits of Eckfeld Maar in the Tertiary Hocheifel Volcanic Field (Rhenish Massif, Germany). The maar origin of the basin is evident from a circular negative gravity anomaly which indicates a low-density funnel-shaped basin filling. From the facies analysis of an Eocene (Eckfeld) and a Pleistocene (Döttingen) maar we develop a lithozone classification for the interpretation of maar sediments: syn-/post-eruptive breccias are followed by a fining-upwards sequence of lacustrine mud with coarse layers and final swamp deposits. From the facies analysis and regional geological data we reconstruct the pre- to post-eruptive history of a maar crater prior to post-Eocene uplift. These observations can be used for the interpretation of Tertiary and Quaternary maar craters that are ideal fossil and sediment traps. 相似文献
1000.
Several Triassic and earliest Jurassic sedimentary units from the Colorado Plateau region have distributions of virtual geomagnetic poles (VGPs) that are highly elongate along the path of apparent polar wander (APW). This suggests that the remanent magnetizations measured in these units were acquired over an extended period of time, possibly approaching 35 m.y., and are not precisely coeval with the stratigraphic age of the rock. Comparison with other paleomagnetic studies shows that the observed elongation is not a general attribute of the age of the rock, nor is it related to paleolatitude. The rocks that yield elongate VGP distributions are dominantly red to brown mudstones, and it is possible that their remanence is dominated by a slowly acquired chemical remanent magnetization, as suggested by Larson et al. [J. Geophys. Res. 87 (1982) 1081] and other authors. However, several superficially similar units from the Colorado Plateau have nearly circular VGP distributions. The process by which remanence is acquired in clastic sedimentary rocks merits further study. 相似文献