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Preliminary investigation of mercury in bone tissues of skua and penguin in Antarctica using AFS and Synchrotron Radiation X-ray Fluorescence(SR-XRF) 
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下载免费PDF全文 <正> Mercury(Hg)was investigated in bone tissues of skua(Catharacta mac-cormick)and penguin(Pygoscelis adeliae)collected in the maritime Antarctic usingatomic fluorescence spectrometry(AFS)and synchrotron radiation X-ray fluorescence(SR-XRF)method.The total levels of mercury in bone tissues of penguin and skuaare much lower than those in other organs(e.g.,kidney,liver).The toxic effects ofmercury in bone tissues of seabirds in polar region are not known.We have used SR-XRF method to map the distribution of trace levels of mercury in bones.The levels ofmercury are found to be enriched somewhere near the periosteal surface and/or endos-teal surface.The distribution of mercury shows strongly correlation with that of someessential elements and probably poses negative effect on the bone metabolism inferringfrom the relationship of mercury with the other elements.These studies represent afirst step toward understanding the toxic effects of mercury on bone of polar animals bysuggesting the possible microscopic investigation. 相似文献
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中国东海、南海等近海临近琉球海沟、马尼拉海沟等俯冲带,地震频发。过去的海啸研究主要关注历史文献分析、海啸数值模拟等,据此评估中国近岸海啸灾害的历史和风险。历史时期是否引发了海啸,特别是具有特大致灾风险的大海啸记录,目前还不明确。近年来,本课题组通过对海岛、海洋沉积和海岸带及其岛屿的沉积过程、海啸遗迹和历史记录研究,阐述了确定古海啸的系列研究方法。首先通过对南海西沙群岛东岛湖泊沉积序列、大量砗磲和珊瑚块在海岛分布的特征分析,识别出距今千年的一次海啸事件。以此为标志,根据湖泊沉积结构作为识别海岛海啸沉积的特征。同时提出了确定海岛海啸发生时代的样品采集和定年方法,其中包括根据事件沉积层顶部和底部植物残体14C年龄定年和历史文献记录的印证。首次确定在过去1 300年中,南海发生过一次海啸,其发生时间为公元1076年。为了寻找更古老的海啸记录,结合对东海闽浙沿岸过去两千年海洋泥质沉积的分析,发现南海海啸在沉积序列中留下记录,但除此之外沉积记录中并无更强的扰动,因此东海在过去两千年中受到海啸的影响较小。1076年的海啸同时冲击了南海沿岸,通过对广东南澳岛考察发现,岛屿东南海岸保存着距今约1 000年的海啸沉积层,其中夹杂着宋代陶器瓷器残片。对遗迹数量变化的分析显示,岛上的文化受海啸破坏出现了长达500年的文化中断,直至明代中后期设镇之后才逐渐恢复。根据海啸层植物残体、贝壳14C测年、覆盖海啸层的海砂光释光定年以及瓷器碎片的年代鉴定了海啸的发生时代,并据此提出了海岸带古海啸沉积的定年方法。此外,不同环境下海啸沉积的特征也存在较大区别,需要结合地形、沉积物来源以及地球化学特征等多种指标进行识别。有迹象表明海南岛东侧海岸带有海啸破坏的明显证据,需要进行深入的研究。 相似文献
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Penguin and skua in the maritime Antarctic have high salt loadings in the body due to almost exclusive diet consumption of marine invertebrates. However, the storage and turnover of sodium and potassium in these animals are poorly investigated. Here we determined the concentration and microscopic distribution of the two elements in the bones of penguin and skua. The average concentrations of sodium and potassium in penguin bone were comparable with that in skua bone (0.18% and 0.82% for penguin bone; 0.19% and 0.76% for skua bone in dry weight). The ratios of sodium to calcium and potassium to calcium (0.0330 and 0.0075 for penguin, 0.0335 and 0.0082 for skua in average by weight) were somewhat higher than the reported ratios for terrestrial animals, indicating these marine animals' bone enrichment of salt. The ratios of sodium to potassium in average by weight were 6.75 and 4.65 for penguin and skua, respectively. This value is much lower compared with the bulk sea water ratio of about 27.0, implying that potassium is favorable to reside in the bone rather than sodium. Both sodium and potassium were found to significant correlation with the content of organic materials in bone based upon the intensity of native signal determined by electron paramagnetic resonance (EPR). It was estimated that almost all of potassium is kept within the organic phases, while about 30% of sodium is stored in organic phases and the other 70% within mineral phase. The microscopic distributions of potassium in the cross-section and/or surface were revealed by synchrotron radiation X-ray fluorescence (SR-XRF) technique. The ratio of potassium to calcium based upon the SR-XRF intensity counter varied considerably from the surface to the interior, and on the surface the highest concentration of potassium was observed in the middle section with decreasing amounts toward the edge. This indirectly documented that exchange of potassium between fluid and bone organic phase maybe occur. 相似文献
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Synchrotron radiation X-ray fluorescence （SR-XRF） approach was applied to analyzing of Chinstrap penguin （ Pygoscelis Antarctica） cortical bone. The method enabled the in situ determination of Ca and P concentrations and the Ca/P ratio in cortical bone. The preliminary results show that ： （ 1 ） there is the bone site-related difference for Ca and P concentrations. The mean values for the investigated parameters （ on a dry-weight basis） are： 30.7% （Ca） and 14.9% （P） for the femoral cortical bone, 21.4% （Ca） and 11.5% （P） for wing cortical bone. （2） The variation for the Ca/P ratio in cortical bone is lower than those for Ca and P separately. This is in agreement with the previous report that the specificity of the Ca/P ratio is better than that of Ca and P concentrations and is more reliable for the diagnosis of bone disorders. The authors suggest that further studies be conducted to establish norreal values of Ca, P and Ca/P ratio for polar animals and provide a basis for the diagnosis of bone disorders. 相似文献
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应用计算机数字影像学原理,建立了对磷质胶结微细纹层研究的数值化方法,研究了西沙东岛珊瑚砂砾屑灰岩磷质胶结物的胶结结构和微纹层特征,定量地刻画了微条纹的宽度和颜色变化信息。东岛珊瑚砂砾屑灰岩磷质胶结物的形成以沉淀胶结为主,不同时期形成的胶结物微条纹系列,由于受到气候、生态因素的影响,具有不同的宽度、明暗度组合;对3个层次磷质胶结物的分析表明,在2900~5700 aBP西沙群岛东岛存在至少3次鸟类和植物的繁盛期;不同时期微纹层的气候、生态记录对比发现,相对稳定的气候条件有利于岛屿海鸟数量的扩大;提供了一种新的方法来探索岛屿鸟粪磷质胶结物的结构和生态环境意义。 相似文献
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本文统计分析了南极DomeC冰芯中汞含量和降水指征参数δ1 8O值、1 0 Be浓度的关系 ,发现冰芯中Hg含量和δ1 8O值、1 0 Be浓度变化一致 ,表明DomeC冰芯汞含量受到冰雪积累率的影响 ,而且三者变化的高度同步性可能说明其原始驱动力也是一致的 ,从而冰芯中Hg含量可以和1 0 Be浓度一样作为冰雪积累率估算的替代性指标。此外 ,利用δ1 8O数据 ,系统估算了 340 0 0年以来南极汞沉降通量的变化。结果表明 ,DomeC冰芯汞沉降通量在末次冰盛期 (LGM)最高 ,为 3.80pgcm- 2 a- 1 ,约是全新世汞沉降通量 ( 1 .0 8pgcm- 2 a- 1 )的 3.5倍 ,该变化可能主要受到汞的自然排放量影响。 相似文献
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本文应用同步辐射加速器X荧光(SR-XRF)分析技术并结合电感耦合等离子体质谱(ICP-MS)方法对中国首次北极考察采集的气溶胶样品进行了定量分析。SR-XRF方法对6种元素的分辨率分别为1.1ng/cm2(Ca)、39.7ng/cm2(V)、17.6ng/cm2(Fe)、2.3ng/cm2(Ni)、1.8ng/cm2(Zn)、6.4ng/cm2(Pb)。6种元素的浓度分别为117.3(ng/m3,Ca)、16.5(ng/m3,V)、19.3(ng/m3,Fe)、3.4(ng/m3,Ni)、4.5(ng/m3,Zn)、1.4(ng/m3,Pb)。该结果与文献报道的相应海区夏季气溶胶化学成分含量具有可比性。由于SR-XRF方法灵敏度高,属于无损分析,在极地气溶胶研究中具有广泛的应用前景。 相似文献
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本文对采自东南极拉斯曼丘陵中山站区的莫愁湖沉积物的元素、氨基酸和Sr同位素组成进行了详细的地球化学分析。结果表明莫愁湖沉积物中Zn、Cu、F、S、P、Se等六种元素具有共同的物质来源,其标型组合特征很可能揭示了莫愁湖沉积物在历史时期曾受到过企鹅等海鸟粪的影响,沉积物中酸溶相Sr同位素组成则确认了海洋源Sr的生物地球化学转移过程。酸溶相87Sr/86Sr值和研究区的新鲜海鸟粪酸溶相Sr同位素组成基本一致,都非常接近于海洋来源锶同位素组成(87Sr/86Sr=0.7092),并且沉积物中的生物元素Zn、Cu、F、S、P、Se含量和酸溶相Sr浓度具有非常高的统计相关性。酸溶相的87Sr/86Sr比值和反映湖泊中藻类等生物自然生成量的氨基酸含量表现出明显的负相关关系,进一步揭示了莫愁湖沉积物在历史时期曾受到企鹅等海鸟活动的影响。上述研究结果为更深入地研究该地区的生态、气候和环境的演变历史及其相互作用提供了有价值的参考资料。 相似文献