DFT study of the cation arrangements in the octahedral and tetrahedral sheets of dioctahedral 2:1 phyllosilicates     

Alfonso Hernández-Laguna  Elizabeth Escamilla-Roa  Vicente Timón  Martin T. Dove  C. Ignacio Sainz-Díaz 《Physics and Chemistry of Minerals》2006,33(10):655-666

Quantum mechanical calculations based on the density functional theory (DFT) are used to study the crystal structures of dioctahedral 2:1 phyllosilicates. The isomorphous cation substitution is investigated by exploring different substitutions of octahedral Al³⁺ by Mg²⁺ or Fe³⁺, tetrahedral substitution of Si⁴⁺ by Al³⁺, and different interlayer cations (IC) (Na⁺, K⁺, Ca²⁺, and Mg²⁺). Samples with different kinds of layer charges are studied: only tetrahedrally charged, only octahedrally charged, or mixed octahedral/tetrahedral charged. The effect of the relative arrangements of these substitutions on the lattice parameters and total energy is studied. The experimental observation of segregation tendency of Fe³⁺ and dispersion tendency of Mg²⁺ in the octahedral sheet is reproduced and explained with reference to the relative energies of the octahedral cation arrangements. These energies are higher than those due to the IC/tetrahedral and IC/octahedral relative arrangements. The tetrahedral and octahedral substitutions that generate charged layers also tend to be dispersed. The octahedral cation exchange potentials change with the IC-charge/ionic radius value.  相似文献   

Microdeformation of lacustrine laminite sequences from Late Miocene formations of SE Spain: an interpretation of loop bedding   总被引：2，自引：0，他引：2  

Jose P. Calvo  Miguel Rodriguez-Pascua  Silvia Martin-Velazquez  Sergio Jimenez  & Gerardo De Vicente 《Sedimentology》1998,45(2):279-292

Lacustrine laminated sediments (laminites) present in Late Miocene formations of the Híjar Basin, SE Spain, display well developed loop bedding, a structure consisting of bundles of laminae that are sharply constricted at intervals, giving a morphology of loops or links of a chain. The laminite sequences, which are interbedded with turbidite marlstones, were accumulated on the bottom of a permanently stratified lake developed in a rapidly subsiding basin limited by 010° and 105° normal faults. As deduced from both macro- and microdeformational analyses, the basin evolved under an extensional stress field throughout the Late Miocene. Four main types of loops, simple and complex loops with subcategories, have been recognized within the laminite sequence. Simple loops of type 1 show the best definite pattern, quite similar to ' pinch and swell structures ', a type of boudinage typical of stretching of alternating beds where the competence contrast is not strongly marked. The remaining loop types display contortion and occasional breakage of laminae (microfaulted edges) indicative of microdeformation near the boundary between the ductile-brittle deformational fields. The distribution of the various loop types across the laminite sequence reflects an interplay between progressive lithification of the laminites as sedimentation progressed and tectonic stresses which affected the sediment sequence. Accordingly, a mechanism of deformation under an extensional stress field, ultimately related to the creep movement of the main basin faults which resulted in successive seismic shocks of low magnitude, is proposed to explain the formation of loop bedding in the laminites.  相似文献   

Geodetic methods for detecting volcanic unrest: a theoretical approach     

José Fernández  José M. Carrasco  John B. Rundle  Vicente Araña 《Bulletin of Volcanology》1999,60(7):534-544

In this paper we study the application of different geodetic techniques to volcanic activity monitoring, using theoretical analysis. This methodology is very useful for obtaining an idea of the most appropriate (and efficient) monitoring method, mainly when there are no records of geodetic changes previous to volcanic activity. The analysis takes into account the crustal structure of the area, its geology, and its known volcanic activity to estimate the deformation and gravity changes that might precede eruptions. The deformation model used includes the existing gravity field and vertical changes in the crustal properties. Both factors can have a considerable effect on computed deformation and gravity changes. Topography should be considered when there is a steep slope (greater than 10°). The case study of Teide stratovolcano (Tenerife, Canary Islands), for which no deformation or gravity changes are available, is used as a test. To avoid considering topography, we worked at the lowest level of Las Cañadas and examined a smaller area than the whole caldera or island. Therefore, the results are only a first approach to the most adequate geodetic monitoring system. The methodology can also be applied to active areas where volcanic risk is not associated with a stratovolcano but instead with monogenetic scattered centers, especially when sites must be chosen in terms of detection efficiency or existing facilities. The Canary Islands provide a good example of this type of active volcanic areas, and we apply our model to the island of Lanzarote to evaluate the efficiency of the monitoring system installed at the existing geodynamic station. On this island topography is not important. The results of our study show clearly that the most appropriate geodetic volcano monitoring system is not the same for all different volcanic zones and types, and the particular properties of each volcano/zone must be taken into account when designing each system.  相似文献   

Analysis of the impact of large scale seismic retrofitting strategies through the application of a vulnerability-based approach on traditional masonry buildings     

Tiago Miguel Ferreira  Rui Maio  Romeu Vicente 《地震工程与工程振动(英文版)》2017,16(2):329-348

The buildings’ capacity to maintain minimum structural safety levels during natural disasters, such as earthquakes, is recognisably one of the aspects that most influence urban resilience. Moreover, the public investment in risk mitigation strategies is fundamental, not only to promote social and urban and resilience, but also to limit consequent material, human and environmental losses. Despite the growing awareness of this issue, there is still a vast number of traditional masonry buildings spread throughout many European old city centres that lacks of adequate seismic resistance, requiring therefore urgent retrofitting interventions in order to both reduce their seismic vulnerability and to cope with the increased seismic requirements of recent code standards. Thus, this paper aims at contributing to mitigate the social and economic impacts of earthquake damage scenarios through the development of vulnerability-based comparative analysis of some of the most popular retrofitting techniques applied after the 1998 Azores earthquake. The influence of each technique individually and globally studied resorting to a seismic vulnerability index methodology integrated into a GIS tool and damage and loss scenarios are constructed and critically discussed. Finally, the economic balance resulting from the implementation of that techniques are also examined.  相似文献   

Do the shallow‐water habitats of a hypersaline tropical estuary act as nursery grounds for fishes?          下载免费PDF全文

Natalice dos Santos Sales  Alexandra Sofia Baptista Vicente Baeta  Lidiane Gomes de Lima  André Luiz Machado Pessanha 《Marine Ecology》2018,39(1)

Fish assemblages were studied in a hypersaline tropical estuary in Northeastern Brazil. A total of 104 species were collected by beach seine during the dry and rainy seasons of 2012. Two families, Atherinopsidae and Gerreidae, were numerically dominant in all zones of the estuary; juveniles of Atherinella brasiliensis, Eucinostomus argenteus, Lile piquitinga, Ulaema lefroyi, Lutjanus analis and Sphoeroides greeleyi contributed 77% of the total catch. The factors that best explained the fish abundance pattern were salinity and depth, which were related to spatial segregation. Species richness was lowest in the upper zone, an area with high salinity and shallow depth. The distinct roles of structurally different habitats (submerged macrophyte beds and mangrove prop‐roots) and the influence of physicochemical conditions in the middle zone of the estuary may influence taxonomic diversity. The middle zone of the estuary is the one most attractive to juveniles of reef species (Lutjanidae and Serranidae). The fish assemblages are clearly dominated by marine estuarine dependent species, highlighting the importance of the ecosystem as a nursery ground for marine species of the Brazilian coast.  相似文献   

Cenozoic thick-skinned deformation and topography evolution of the Spanish Central System   总被引：4，自引：2，他引：2  

G. de Vicente  R. Vegas  A. Muoz Martín  P.G. Silva  P. Andriessen  S. Cloetingh  J.M. Gonzlez Casado  J.D. Van Wees  J. lvarez  A. Carb  A. Olaiz 《Global and Planetary Change》2007,58(1-4):335

The Spanish Central System is a Cenozoic pop-up with an E–W to NE–SW orientation that affects all the crust (thick-skinned tectonics). It shows antiform geometry in the upper crust with thickening in the lower crust. Together with the Iberian Chain it constitutes the most prominent mountainous structure of the Pyrenean foreland.The evolutionary patterns concerning the paleotopography of the interior of the Peninsula can be established by an analysis of the following data: gravimetric, topographical, macro and micro tectonic, sedimentological (infilling of the sedimentary basins of the relative foreland), P–T–t path from apatite fission tracks, paleoseismic and instrumental seismicity.Deformation is clearly asymmetric in the Central System as evidenced by the existence of an unique, large (crustal-scale) thrust at its southern border, while in the northern one there is a normal sequence of north verging thrusts, towards the Duero Basin, whose activity ended during the Lower Miocene. This deformation was accomplished under triaxial compression, Oligocene–Lower Miocene in age, marked by NW–SE to NNW–SSE shortening. Locally orientations of paleostresses deviate from that of the regional tensor, following a period of relative tectonic quiescence. During the Upper Miocene–Pliocene, a reactivation of constrictive stress occurred and some structures underwent rejuvenation as a consequence of the action of tectonic stresses similar to those of today (uniaxial extension to strike–slip with NW–SE shortening direction). However, the westernmost areas show continuous activity throughout the whole of the Tertiary, with no apparent pulses. At the present time there is a moderate seismic activity in the Central System related to faults that were active during the Cenozoic, with the same kinematic characteristics.  相似文献   

Simulated Urban Climate Response to Historical Land Use Modification in the Basin of Mexico   总被引：4，自引：0，他引：4  

Arón Jazcilevich  Vicente Fuentes  Ernesto Jauregui  Esteban Luna 《Climatic change》2000,44(4):515-536

Numerical simulations of thermal field variation due to land use changes, such as the reduction of the lacustrine system and the growth of the urban area, in the Basin of Mexico are presented. It is shown that the historically recorded warming in the basin could be attributed, not only to the growth of the urban area, but more importantly to the drastic reduction in the lacustrine system that existed in the basin.  相似文献   

Sedimentary response of lake El Tobar,Spain, to climate: lake level changes after the Maunder Minimum          下载免费PDF全文

Charo López‐Blanco  Julian Andrews  Paul Dennis  María Rosa Miracle  Eduardo Vicente 《第四纪科学杂志》2016,31(8):905-918

  相似文献   

The Cretaceous–Palaeogene boundary at Gorgonilla Island,Colombia, South America          下载免费PDF全文

Hermann D. Bermúdez  Jenny García  Wolfgang Stinnesbeck  Gerta Keller  José Vicente Rodríguez  Michael Hanel  Jens Hopp  Winfried H. Schwarz  Mario Trieloff  Liliana Bolívar  Francisco J. Vega 《地学学报》2016,28(1):83-90

The discovery of a new Cretaceous/Palaeogene (K/Pg) bathyal marine sequence on Gorgonilla Island, SW Colombia, extends the presence of Chicxulub impact spherule deposits to the Pacific region of northern South America and to the Eastern Pacific Ocean. The Gorgonilla spherule layer is approximately 20 mm thick and consists of extraordinarily well‐preserved glass spherules up to 1.1 mm in diameter. About 70–90% of the spherules are vitrified, and their chemical composition is consistent with Haiti (Beloc) impact glass spherules. Normal size‐grading, delicate spherule textures, welded melt components and an absence of bioturbation or traction transport suggest that the Gorgonilla spherule layer represents an almost undisturbed settling deposit.  相似文献   

Exploring the relationships between perceived neighborhood boundaries and street network orientation     

Vicente Tang  Marco Painho 《Transactions in GIS》2023,27(3):877-899

The neighborhood is a core unit of analysis in urban research, planning, and policy-making. However, perceptual and historical processes oftentimes result in neighborhoods that are not tied to sub-urban jurisdictions. For instance, historic neighborhoods might lack official spatial definitions, hampering neighborhood-based tasks in local offices. In this case, urban practitioners can benefit from readily available spatial proxies, such as the local street network. In this study, we conducted an exploratory analysis that combines neighborhood mapping and street network modeling. By retrieving participants' sketched boundaries and quantifying spatial orientations of sketched polygons and local network patterns, we were able to measure and compare the relationships between the urban fabric and the perceived extents of two historic neighborhoods in Lisbon, Portugal. The results provided insights for enhancing existing definitions of non-official neighborhoods, outlining new urban districts as well as for discussions about the role of the urban form in shaping people's perceptions.  相似文献