Antigorite equation of state and anomalous softening at 6 GPa: an in situ single-crystal X-ray diffraction study   总被引：1，自引：0，他引：1  

Fabrizio Nestola  Ross J. Angel  Jing Zhao  Carlos J. Garrido  Vicente López Sánchez-Vizcaíno  Giancarlo Capitani  Marcello Mellini 《Contributions to Mineralogy and Petrology》2010,160(1):33-43

The compressibility of antigorite has been determined up to 8.826(8) GPa, for the first time by single crystal X-ray diffraction in a diamond anvil cell, on a specimen from Cerro del Almirez. Fifteen pressure–volume data, up to 5.910(6) GPa, have been fit by a third-order Birch–Murnaghan equation of state, yielding V ₀ = 2,914.07(23) Å³, K _T0 = 62.9(4) GPa, with K′ = 6.1(2). The compression of antigorite is very anisotropic with axial compressibilities in the ratio 1.11:1.00:3.22 along a, b and c, respectively. The new equation of state leads to an estimation of the upper stability limit of antigorite that is intermediate with respect to existing values, and in better agreement with experiments. At pressures in excess of 6 GPa antigorite displays a significant volume softening that may be relevant for very cold subducting slabs.  相似文献   

Seismic vulnerability and risk assessment: case study of the historic city centre of Coimbra, Portugal   总被引：5，自引：4，他引：1  

Romeu Vicente  Sonia Parodi  Sergio Lagomarsino  Humberto Varum  J. A. R. Mendes Silva 《Bulletin of Earthquake Engineering》2011,9(4):1067-1096

Seismic risk evaluation of built-up areas involves analysis of the level of earthquake hazard of the region, building vulnerability and exposure. Within this approach that defines seismic risk, building vulnerability assessment assumes great importance, not only because of the obvious physical consequences in the eventual occurrence of a seismic event, but also because it is the one of the few potential aspects in which engineering research can intervene. In fact, rigorous vulnerability assessment of existing buildings and the implementation of appropriate retrofitting solutions can help to reduce the levels of physical damage, loss of life and the economic impact of future seismic events. Vulnerability studies of urban centres should be developed with the aim of identifying building fragilities and reducing seismic risk. As part of the rehabilitation of the historic city centre of Coimbra, a complete identification and inspection survey of old masonry buildings has been carried out. The main purpose of this research is to discuss vulnerability assessment methodologies, particularly those of the first level, through the proposal and development of a method previously used to determine the level of vulnerability, in the assessment of physical damage and its relationship with seismic intensity. Also presented and discussed are the strategy and proposed methodology adopted for the vulnerability assessment, damage and loss scenarios for the city centre of Coimbra, Portugal, using a GIS mapping application.  相似文献   

150 years of anthropogenic metal input in a Biosphere Reserve: the case study of the Cananéia–Iguape coastal system, Southeastern Brazil     

Michel Michaelovitch de Mahiques  Rubens Cesar Lopes Figueira  Alexandre Barbosa Salaroli  Daniel Pavani Vicente Alves  Cristina Gonçalves 《Environmental Earth Sciences》2013,68(4):1073-1087

The Cananéia–Iguape system consists of a complex of estuarine and lagoonal channels located in the coastal region of southeastern Brazil known as Lagamar, a Biosphere Reserve recognized by the United Nations Educational, Scientific and Cultural Organization (UNESCO) in 1991. The area suffered dramatic environmental changes along the last ca. 150 years initiated by the 1852 opening of an artificial channel, the Valo Grande, connecting the Ribeira de Iguape River to the estuarine system. Due to Au, Ag, Zn, and Pb mining activities that took place in the upstream regions of the Ribeira de Iguape River since the seventeenth century, the system has acted as a final destination of contaminated sediments. Analysis of cores located along the estuarine system revealed a history of contamination, with an increase of anthropogenic metal input between the decades of 1930 and 1990. The anthropogenic influence can be traced in locations as far as 20 km from the mouth of the artificial channel.  相似文献   

Multi-technique approach to characterise the effects of cryopreservation on larval development of the Pacific oyster (Crassostrea gigas)     

S Suneja  AB Rusk  JR Morrish  HR Tervit  LT McGowan 《新西兰海洋与淡水研究杂志》2014,48(3):335-349

Cryopreservation experiments were conducted on D-stage larvae of the Pacific oyster (Crassostrea gigas) to investigate the effects of two cryoprotectant solutions and three cooling rates on larval development from 1 to 22 days post-fertilisation. Cryoprotectant solutions were made up to final concentrations (after 1:1 dilution with larvae) of 10% ethylene glycol, 1% polyvinylpyrrolidone and either 0.2 or 0.4 M trehalose. Three cooling rates (0.5, 1 and 2 °C min^?1 between ?10 and ?35 °C post-holding) were tested in an orthogonal design with the two cryoprotectants. Results indicate that control larvae out-performed all cryopreservation treatments for survival, feeding consumption and shell length parameters. However, larvae exposed to 0.4 M trehalose did considerably better than those exposed to 0.2 M trehalose, regardless of cooling rate conditions. Scanning electron and light microscopy observations were used to assess larval morphology and organogenesis, indicating that treatments with surviving larvae were morphologically and developmentally similar to control larvae.  相似文献   

Estimation of daytime downward longwave radiation under clear and cloudy skies conditions over a sub-humid region   总被引：1，自引：0，他引：1  

Facundo Carmona  Raúl Rivas  Vicente Caselles 《Theoretical and Applied Climatology》2014,115(1-2):281-295

Downward longwave radiation (LW _↓ ) is a relevant variable for meteorological and climatic studies. Good estimates of this term are vitally important in correct determining of the net radiation, which, in turn, modulates the magnitude of the terms in the surface energy budget (e.g., evaporation). In remote sensing applications, the determination of daytime LW_↓ is required for estimation of the net radiation using satellite data. LW_↓ is not directly measured in weather stations and then is estimated using models with surface air temperature and humidity as input. In this paper, we identify the best models to estimate daytime downward longwave radiation from meteorological data in the sub-humid Pampean region. Several well-known models to estimate LW_↓ under clear and cloudy skies were tested. We use downward radiation components and meteorological data registered at Tandil (Argentina) from 2006 to 2010 (840 days). In addition, we propose two multiple linear regression models (MLRM-1 and MLRM-2) to estimate LW_↓ at the surface for all sky conditions. The new equations show better performance than the others models tested with root mean square errors between 12 and 16 W m^?2, bias close to zero and best agreements with measured data (r ²?≥?0.85).  相似文献   

Seismic vulnerability assessment of historical urban centres: case study of the old city centre in Seixal, Portugal   总被引：1，自引：1，他引：0  

Tiago Miguel Ferreira  Romeu Vicente  J. A. R. Mendes da Silva  Humberto Varum  Aníbal Costa 《Bulletin of Earthquake Engineering》2013,11(5):1753-1773

The seismic vulnerability assessment of old masonry buildings is essential not only to buildings with recognised historical and heritage value but also to ordinary residential masonry buildings. This paper approaches the seismic vulnerability assessment of masonry buildings by applying a simplified methodology to the old city centre of Seixal in Portugal. The methodology adopted in this study was based on a vulnerability index used for the evaluation of damage and the study of loss scenarios on a large scale. Over 500 buildings were assessed using this methodology, and the results were analysed using an integrated Geographical Information System tool. The integration of the vulnerability and loss results could allow city councils or regional authorities to plan interventions based on a global view of the site under analysis, leading to more accurate and comprehensive risk mitigation strategies that support the requirements of safety and emergency planning.  相似文献   

Primary production in Lake La Cruz (Spain) over the last four centuries: reconstruction based on sedimentary signal of photosynthetic pigments     

Lidia Romero-Viana  Brendan J. Keely  Antonio Camacho  Eduardo Vicente  M. Rosa Miracle 《Journal of Paleolimnology》2010,43(4):771-786

We analysed photosynthetic pigments in annually laminated sediment of meromictic Lake La Cruz, Spain, to cope with the timing and characterisation of primary productivity changes over the last four centuries. The photosynthetic pigments identified included chlorophyll a and b (and its derivatives) and specific carotenoids of different algal groups, such as zeaxanthin, lutein, alloxanthin, diadinoxanthin and diatoxanthin among others. Marker pigments of phototrophic sulfur bacteria were also observed, including bacteriochlorophyll a derivatives, homologue series of bacteriophaeophytins d and bacterial carotenoids okenone and chlorobactene. We investigated the diagenetic processes of pigment alteration in anoxic sediments and the possible implications for paleoproductivity reconstruction and interpretation. The lack of systematic down-core changes in diagenetic indicators suggests that variability of sedimentary pigment concentrations is the result of changes in lake productivity. The lower concentration of algal photosynthetic pigments in the bottom of sediment sequence corresponds to the onset of meromictic conditions. Before that, sediment was not continuously anoxic and the preservation of pigments was reduced. Regarding photosynthetic bacteria, green sulfur bacteria derivatives indicate that population growth was limited until the settled organic matter was sufficient to provide enough sulphide. Moreover, the presence of bacterioviridine, an oxidised derivative of bacteriochlorophyll a, suggest the competitive relation among photosynthetic bacteria. The high relative abundance of zeaxanthin indicates the dominance of picocyanobacteria in the primary productivity over the last centuries. Fluctuations of the pigment signal observed in the sediment sequence during the meromictic period were well correlated with fluctuations of solar activity.  相似文献   

Variation in transparent exopolymer particles in relation to biological and chemical factors in two contrasting lake districts     

Inmaculada de Vicente  Eva Ortega-Retuerta  Ignacio P. Mazuecos  Michael L. Pace  Jonathan J. Cole  Isabel Reche 《Aquatic Sciences - Research Across Boundaries》2010,72(4):443-453

In inland waters, transparent exopolymer particles (TEP) can affect carbon export and sequestration in sediments with consequences for lake C budgets. We measured TEP concentration in 32 lakes from two contrasting lake districts covering wide ranges in biological and chemical characteristics. North temperate lakes, located in a wet region, have low to moderate ionic strength and low to high dissolved organic carbon with corresponding variation in color (light absorbance). Mediterranean lakes located in a semiarid region were characterized by high ionic strength and high concentrations of dissolved organic carbon but low color. TEP concentrations were large relative to the living portion of the particulate organic carbon pool in both Mediterranean (36%) and north temperate (33%) lakes. TEP concentrations ranged from 36 to 1,462 μg [as Gum Xanthan equivalents (GX eq)] L⁻¹ in north temperate lakes. In the Mediterranean lakes, concentrations were higher that previously reported for other systems and ranged from 66 to 9,038 μg GX eq L⁻¹. TEP concentration was positive and significantly related to chlorophyll a (chl a) in north temperate lakes and in the entire data set. Although a significant and positive relationship between TEP and chl a was also detected in the Mediterranean lakes, bacterial abundance was most strongly related to TEP. In contrast with the positive influence of phytoplankton and bacteria on TEP, there were weaker relationships between TEP and the chemical variables tested. We observed a significant and positive relationship between pH and TEP (for all lakes) but this relationship was indirectly driven by a co-variation of pH with phytoplankton biomass based on multiple regression analysis. For the Mediterranean lakes, the negative (but not significant) trends between TEP and both conductivity and divalent cations suggest thresholds above which TEP will likely be destabilized. Under these conditions, TEP may flocculate or disperse in the water column.  相似文献   

Impacts of human activities on recharge in a multilayered semiarid aquifer (Campo de Cartagena,SE Spain)   总被引：1，自引：0，他引：1       下载免费PDF全文

Paul Baudron  Florent Barbecot  José Luis García Aróstegui  Christian Leduc  Yves Travi  David Martinez‐Vicente 《水文研究》2014,28(4):2223-2236

The development of intense agriculture in semiarid areas modifies intensity and spatial distribution of groundwater recharge by summing irrigation return flow to limited rainfall infiltration. Environmental tracers provide key information, but their interpretation is complicated by more complex groundwater flow patterns. In multilayered aquifers, the real origin of the groundwater samples is hard to assess because of local mixing processes occurring inside long‐screened boreholes. We use environmental tracers (¹⁴C, ¹³C, ²H, ¹⁸O, ³H) to investigate the long‐term evolution of recharge in the five‐layer Campo de Cartagena aquifer in South‐Eastern Spain, in addition to high‐resolution temperature loggings to identify the depth of origin of groundwater. Despite the complex background, this methodology allowed a reliable interpretation of the geochemistry and provided a better understanding of the groundwater flow patterns. The tritium method did not give good quantitative results because of the high variability of the recharge signal but remained an excellent indicator of recent recharge. Nonetheless, both pre‐anthropization and post‐anthropization recharge regime could be identified and quantified by radiocarbon. Before the development of agriculture, recharge varied from 17 mm.year^‐1 at the mountain ranges to 6 mm.year^‐1 in the plain, whereas the mean annual rainfall is about 300 mm. In response to the increase of agricultural activity, recharge fluxes to the plain were amplified and nowadays reach up to 210 mm.year^‐1 in irrigated areas. These values are strengthened by global water budget and local unsaturated zone studies. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Thermal structure and energy budget in a small high mountain lake: La Caldera,Sierra Nevada,Spain     

Miguel Rodríguez‐Rodríguez  Enrique Moreno‐Ostos  Inmaculada De Vicente  Luis Cruz‐Pizarro  Sergio Luiz Rodrigues Da Silva 《新西兰海洋与淡水研究杂志》2013,47(5):879-894

This work examines the diel change of energy storage and its associated patterns of thermal stratification during the ice‐free period in a high mountain lake (La Caldera Lake, Sierra Nevada, Spain), in response to meteorological conditions. Bihourly data have been implemented to a standard methodology of surface heat exchange calculations in lakes. Strong variations have been observed on the diverse components of the energy budget at different time scales, ranging from diel to seasonal. Additionally, time‐series analyses have been applied to reveal the underlying periodicities involved in relation to the different variables studied. The results obtained from this study provided realistic conditions for the environmental modelling of such processes, which are very sensitive in time scale.  相似文献