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91.
92.
In a previous paper (Chassefière et al. 2013 ), we have shown that most volcanic sulfur released to the early Mars atmosphere could have been trapped in the upper cryosphere under the form of CO2‐SO2 clathrates. Huge amounts of sulfur, up to the equivalent of an ~1 bar atmosphere of SO2, would have been stored in the Noachian upper cryosphere, then massively released to the atmosphere during the Hesperian due to rapidly decreasing CO2 pressure. It could have resulted in the formation of the large sulfate deposits observed mainly in Hesperian terrains, whereas no or little sulfates are found at the Noachian. In the present paper, we first clarify some aspects of our previous work. We discuss the possibility of a smaller cooling effect of sulfur particles, or even of a net warming effect. We point out the fact that CO2‐SO2 clathrates formed through a progressive enrichment of a pre‐existing reservoir of CO2 clathrates and discuss processes potentially involved in the slow formation of a SO2‐rich upper cryosphere. We show that episodes of sudden destabilization at the Hesperian may generate 1000 ppmv of SO2 in the atmosphere and contribute to maintaining the surface temperature above the water freezing point.  相似文献   
93.
The Maâdna structure is located approximately 400 km south of Algiers (33°19′ N, 4°19′ E) and emplaced in Upper‐Cretaceous to Eocene limestones. Although accepted as an impact crater on the basis of alleged observations of shock‐diagnostic features such as planar deformation features (PDFs) in quartz grains, previous works were limited and further studies are desirable to ascertain the structure formation process and its age. For this purpose, the crater was investigated using a multidisciplinary approach including field observations, detailed cartography of the different geological and structural units, geophysical surveys, anisotropy of magnetic susceptibility, paleomagnetism, and petrography of the collected samples. We found that the magnetic and gravimetric profiles highlight a succession of positive and negative anomalies, ones that might indicate the occurrence of a causative material which is at least in part identical. Geophysical analysis and modeling suggest the presence of this material within the crater at a depth of about 100 m below the surface. Using soil magnetic susceptibility measurements, the shallowest magnetized zone in the central part of the crater is identified as a recently deposited material. Paleomagnetic and rock magnetic experiments combined with petrographic observations show that detrital hematite is the main magnetic carrier although often associated with magnetite. A primary magnetization is inferred from a stable remanence with both normal and reverse directions, carried by these two minerals. Although this is supposed to be a chemical remagnetization, its normal polarity nature is considered to be a Pliocene component, subsequent to the crater formation. The pole falls onto the Miocene‐Pliocene part of the African Apparent Polar Wander Path (APWP). Consequently, we estimate the formation of the Maâdna crater to have occurred during the time period extending from the Late Miocene to the Early Pliocene. Unfortunately, our field and laboratory investigations do not allow us to confirm an impact origin for the crater as neither shatter cones, nor shocked minerals, were found. A dissolved diapir with inverted relief is suggested as an alternative to the impact hypothesis, which can still be considered as plausible. Only a drilling may provide a definite answer.  相似文献   
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Abstract

Carbonyl sulphide (OCS) is an important precursor of sulphate aerosols and consequently a key species in stratospheric ozone depletion. The SPectromètre InfraRouge d'Absorption à Lasers Embarqués (SPIRALE) and shortwave infrared (SWIR) balloon-borne instruments have flown in the tropics and in the polar Arctic, and ground-based measurements have been performed by the Qualité de l'Air (QualAir) Fourier Transform Spectrometer in Paris. Partial and total columns and vertical profiles have been obtained to study OCS variability with altitude, latitude, and season. The annual total column variation in Paris reveals a seasonal variation with a maximum in April–June and a minimum in November–January. Total column measurements above Paris and from SWIR balloon-borne instrument are compared with several MkIV measurements, several Network for the Detection of Atmospheric Composition Change (NDACC) stations, aircraft, ship, and balloon measurements to highlight the OCS total column decrease from tropical to polar latitudes. OCS high-resolution in situ vertical profiles have been measured for the first time in the altitude range between 14 and 30?km at tropical and polar latitudes. OCS profiles are compared with Atmospheric Chemistry Experiment (ACE) satellite measurements and show good agreement. Using the correlation between OCS and N2O from SPIRALE, the OCS stratospheric lifetime has been accurately determined. We find a stratospheric lifetime of 68?±?20 years at polar latitudes and 58?±?14 years at tropical latitudes leading to a global stratospheric sink of 49?±?14?Gg?S?y?1.  相似文献   
97.
The geochemical partitioning of bromine between hydrous haplogranitic melts, initially enriched with respect to Br and aqueous fluids, has been continuously monitored in situ during decompression. Experiments were carried out in diamond anvil cells from 890 °C to room temperature and from 1.7 GPa to room pressure, typically from high P, T conditions corresponding to total miscibility (presence of a supercritical fluid). Br contents were measured in aqueous fluids, hydrous melts and supercritical fluids. Partition coefficients of bromine were characterized at pressure and temperature between fluids, hydrous melts and/or glasses, as appropriate: DBrfluid/melt = (Br)fluid/(Br)melt, ranges from 2.18 to 9.2 ± 0.5 for conditions within the ranges 0.66-1.7 GPa, 590-890 °C; and DBrfluid/glass = (Br)fluid/(Br)glass ranges from 60 to 375 at room conditions. The results suggest that because high pressure melts and fluids are capable of accepting high concentrations of bromine, this element may be efficiently removed from the slab to the mantle source of arc magmas. We show that Br may be highly concentrated in subduction zone magmas and strongly enriched in subduction-related volcanic gases, because its mobility is strongly correlated with that of water during magma degassing. Furthermore, our experimental results suggest that a non negligible part of Br present in the subducted slab may remain in the down-going slab, being transported toward the transition zone. This indicates that the Br cycle in subduction zones is in fact divided in two related but independent parts: (1) a shallower one where recycled Br may leave the slab with a water and silica-bearing “fluid” leading to enriched arc magmas that return Br to the atmosphere. (2) A deeper cycle where Br may be recycled back to the mantle maybe to the transition zone, where it may be present in high pressure water-rich metasomatic fluids.  相似文献   
98.
In France, the Devonian–Carboniferous Variscan orogeny developed at the expense of continental crust belonging to the northern margin of Gondwana. A Visean–Serpukhovian crustal melting has been recently documented in several massifs. However, in the Montagne Noire of the Variscan French Massif Central, which is the largest area involved in this partial melting episode, the age of migmatization was not clearly settled. Eleven U–Th–Pbtot. ages on monazite and three U–Pb ages on associated zircon are reported from migmatites (La Salvetat, Ourtigas), anatectic granitoids (Laouzas, Montalet) and post-migmatitic granites (Anglès, Vialais, Soulié) from the Montagne Noire Axial Zone are presented here for the first time. Migmatization and emplacement of anatectic granitoids took place around 333–326 Ma (Visean) and late granitoids emplaced around 325–318 Ma (Serpukhovian). Inherited zircons and monazite date the orthogneiss source rock of the Late Visean melts between 560 Ma and 480 Ma. In migmatites and anatectic granites, inherited crystals dominate the zircon populations. The migmatitization is the middle crust expression of a pervasive Visean crustal melting event also represented by the “Tufs anthracifères” volcanism in the northern Massif Central. This crustal melting is widespread in the French Variscan belt, though it is restricted to the upper plate of the collision belt. A mantle input appears as a likely mechanism to release the heat necessary to trigger the melting of the Variscan middle crust at a continental scale.  相似文献   
99.
HydroCube: an entity-relationship hydrogeological data model   总被引:1,自引:1,他引:0  
Managing, handling and accessing hydrogeological information depends heavily on the applied hydrogeological data models, which differ between institutions and countries. The effective dissemination of hydrogeological information requires the convergence of such models to make hydrogeological information accessible to multiple users such as universities, water suppliers, and administration and research organisations. Furthermore, because hydrogeological studies are complex, they require a wide variety of high-quality hydrogeological data with appropriate metadata in clearly designed and coherent structures. A need exists, therefore, to develop and implement hydrogeological data models that cover, as much as possible, the full hydrogeological domain. A new data model, called HydroCube, was developed for the Walloon Region in Belgium in 2005. The HydroCube model presents an innovative holistic project-based approach which covers a full set of hydrogeological concepts and features, allowing for effective hydrogeological project management. The model stores data relating to the project locality, hydrogeological equipment, and related observations and measurements. In particular, it focuses on specialized hydrogeological field experiments such as pumping and tracer tests. This logical data model uses entity-relationship diagrams and it has been implemented in the Microsoft Access environment. It has been enriched with a fully functional user interface.  相似文献   
100.
The former tidal inlet Lake Veere was turned into a stagnant brackish lake in 1961. Ever since, the system has shown a continuous degradation. The current study shows the monitoring results for the macrozoobenthic communities and the abiotic conditions for the period 1990–2008. This includes the first step to remediation, the restoration of the exchange between the tidal marine Eastern Scheldt and Lake Veere in 2004. A continuous decline in water clearance co-occurring with decreasing macrofauna densities and richness was observed till 2004. Water quality (e.g., secchi depth, nutrient levels, and oxygen conditions) improved significantly after the measure at a higher salinity level with less variation. But the macrofauna densities, biomass, and diversity did not improve yet. First indications of changes in the benthic communities by arrival of new and returning species are however observed and show that restoration at macrofauna level follows the improved abiotic conditions with a delay of several years.  相似文献   
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