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41.
We report on simultaneous optical and infrared observations of the Halley Family comet 8P/Tuttle performed with the ESO Very Large Telescope. Such multi-wavelength and coordinated observations are a good example of what can be done to support space missions. From high resolution optical spectroscopy of the CN (0,0) 388 nm and NH2 (0,9,0) 610 nm bands using UVES at UT2 we determined 12C/13C = 90 ± 10 and 14N/15N = 150 ± 20 in CN and we derived a nuclear spin temperature of NH3 of 29 ± 1 K. These values are similar to those found in Oort-Cloud and Jupiter Family comets. From low resolution long slit spectroscopy with FORS1 at UT2 we determined the CN, C3 and C2 production rates and the parent and daughter scale lengths up to 5.2 105 km tailward. From high resolution IR spectroscopy with CRIRES at UT1 we measured simultaneously the production rates and mixing ratios of H2O, HCN, C2H2, CH4, C2H6, and CH3OH.  相似文献   
42.
Comet 73P-B/Schwassmann-Wachmann 3 was observed with IRCS/Subaru at geocentric distance of 0.074 AU on UT 10 May 2006. Multiple H2O emission lines were detected in non-resonant fluorescence near 2.9 μm. No significant variation in total H2O production rate was found during the (3 h) duration of our observations. H2O rotational temperatures and ortho-to-para abundance ratios were measured for several positions in the coma. The temperatures extracted from two different time intervals show very similar spatial distributions. For both, the rotational temperature decreased from ∼110 to ∼90 K as the projected distance from the nucleus increased from ∼5 to ∼30 km. We see no evidence for OPR change in the coma. The H2O ortho-para ratio is consistent with the statistical equilibrium value (3.0) for all spatially resolved measurements. This implies a nuclear spin temperature higher than ∼45 K.  相似文献   
43.
Cathodoluminescence (CL) analyses were carried out on maskelynite and lingunite in L6 chondrites of Tenham and Yamato-790729. Under CL microscopy, bright blue emission was observed in Na-lingunite in the shock veins. Dull blue-emitting maskelynite is adjacent to the shock veins, and aqua blue luminescent plagioclase lies farther away. CL spectroscopy of the Na-lingunite showed emission bands centered at ~330, 360–380, and ~590 nm. CL spectra of maskelynite consisted of emission bands at ~330 and ~380 nm. Only an emission band at 420 nm was recognized in crystalline plagioclase. Deconvolution of CL spectra from maskelynite successfully separated the UV–blue emission bands into Gaussian components at 3.88, 3.26, and 2.95 eV. For comparison, we prepared K-lingunite and experimentally shock-recovered feldspars at the known shock pressures of 11.1–41.2 GPa to measure CL spectra. Synthetic K-lingunite has similar UV–blue and characteristic yellow bands at ~550, ~660, ~720, ~750, and ~770 nm. The UV–blue emissions of shock-recovered feldspars and the diaplectic feldspar glasses show a good correlation between intensity and shock pressure after deconvolution. They may be assigned to pressure-induced defects in Si and Al octahedra and tetrahedra. The components at 3.88 and 3.26 eV were detectable in the lingunite, both of which may be caused by the defects in Si and Al octahedra, the same as maskelynite. CL of maskelynite and lingunite may be applicable to estimate shock pressure for feldspar-bearing meteorites, impactites, and samples returned by spacecraft mission, although we need to develop more as a reliable shock barometer.  相似文献   
44.

The temperature distribution at depth is a key variable when assessing the potential of a supercritical geothermal resource as well as a conventional geothermal resource. Data-driven estimation by a machine-learning approach is a promising way to estimate temperature distributions at depth in geothermal fields. In this study, we developed two methodologies—one based on Bayesian estimation and the other on neural networks—to estimate temperature distributions in geothermal fields. These methodologies can be used to supplement existing temperature logs, by estimating temperature distributions in unexplored regions of the subsurface, based on electrical resistivity data, observed geological/mineralogical boundaries, and microseismic observations. We evaluated the accuracy and characteristics of these methodologies using a numerical model of the Kakkonda geothermal field, Japan, where a temperature above 500 °C was observed below a depth of about 3.7 km. When using geological and geophysical knowledge as prior information for the machine learning methods, the results demonstrate that the approaches can provide subsurface temperature estimates that are consistent with the temperature distribution given by the numerical model. Using a numerical model as a benchmark helps to understand the characteristics of the machine learning approaches and may help to identify ways of improving these methods.

  相似文献   
45.
Volatile organic iodine compounds (VOIs) emitted from the ocean surface to the air play an important role in atmospheric chemistry. Shipboard observations were conducted in Funka Bay, Hokkaido, Japan, bimonthly or monthly from March 2012 to December 2014, to elucidate the seasonal variations of VOI concentrations in seawater and their sea-to-air iodine fluxes. The bay water exchanges with the open ocean water of the North Pacific twice a year (early spring and autumn). Vertical profiles of CH2I2, CH2ClI, CH3I, and C2H5I concentrations in the bay water were measured bimonthly or monthly within an identified water mass. The VOI concentrations began to increase after early April at the end of the diatom spring bloom, and represented substantial peaks in June or July. The temporal variation of the C2H5I profile, which showed a distinct peak in the bottom layer from April to July, was similar to the PO4 3? variation profile. Correlation between C2H5I and PO4 3? concentrations (r = 0.93) suggests that C2H5I production was associated with degradation of organic matter deposited on the bottom after the spring bloom. CH2I2 and CH2ClI concentrations increased substantially in the surface and subsurface layers (0–60 m) in June or July resulted in a clear seasonal variation of the sea-to-air iodine flux of the VOIs (high in summer or autumn and low in spring).  相似文献   
46.
In the chemical evolution of the Galaxy, Type II supernovae (SNe II)have contributed to the early metal enrichment and later Type Iasupernovae (SNe Ia) have contributed to the delayed enrichment of Fe.In principle, hypothetical pre-galactic population III objects couldcause the earliest heavy element enrichment. Here we present our twonew findings. 1) The peculiar abundance pattern among iron peakelements (Cr, Mn, Co, and Fe) in the very metal poor can be reproducedwith SN II nucleosynthesis yields without invoking the contributionfrom Pop III objects. 2) The observed chemical evolution in the solarneighborhood is well reproduced with the metallicity dependentoccurrence of SNe Ia, where SNe Ia do not occur if the iron abundanceof the progenitors is as low as [Fe/H] ≲ -1. We make theprediction that the cosmic SN Ia rate drops at z ∼ 1-2 because ofthe low-iron abundance, which can be observed with the Next GenerationSpace Telescope. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
47.
We have developed a rapid and accurate method for the determination of Mo, Sb and W in geological samples using isotope dilution inductively coupled plasma-mass spectrometry with a flow injection system (ID-FI-ICP-MS). The chemical procedure requires HF digestion of the sample with a Mo-Sb-W mixed spike, subsequent evaporation and dissolution of Mo, Sb and W from Mg and Ca fluorides with HF. Recovery yields of Mo, Sb and W in the extraction were > 94% for samples of peridotite, basalt and andesite composition, with the exception of W in samples of peridotite composition for which recovery was 81%. No matrix effects were observed in the determination of the isotope ratios of Mo, Sb and W in solutions prepared from peridotite, basalt and andesite samples down to a dilution factor of 100. Detection limits of Mo, Sb and W in silicate materials were at the several ng g−1 level. Analysis of the silicate reference materials PCC-1, DTS-1, BCR-1, BHVO-1, AGV-1 from the US Geological Survey and JP-1, JB-1, -2, -3, JA-1, -2, and -3 from the Geological Survey of Japan as well as the Smithsonian reference Allende powder yielded reliable Mo, Sb and W concentrations. The repeatability in the analysis of basalts and andesites was < 9%. This technique requires only 0.2 ml sample solution, and is therefore suitable for analyzing small and/or precious samples such as meteorites, mantle peridotites and their mineral separates.  相似文献   
48.
We have developed a rapid and accurate method to determine Zr, Nb, Hf and Ta (denoted as HFSE) in geological samples by inductively coupled plasma-mass spectrometry fitted with a flow injection system (FI-ICP-MS). The method involves sample decomposition by HF followed by HF dissolution of HFSE coprecipitated with insoluble M and Ca fluoride residues formed during the initial HF attack. This HF solution was directly nebulized into an ICP mass spectrometer. An external calibration curve method and an isotope dilution method (ID) were applied for the determination of Nb and Ta, and of Zr and Hf, respectively. Recovery yields of HFSE were > 96% for peridotite, basalt and andesite compositions, apart from Zr and Hf for peridotite (> 85%). No matrix effects for either signal intensities of HFSE or isotope ratios of Zr and Hf were observed in basalt, andesite and peridotite solutions down to a dilution factor of 100. Detection limits in silicate rocks were 40, 2, 1 and 0.1 ng g-1 for Zr, Nb, Hf and Ta, respectively. This technique required only 0.1 ml of sample solution, and thus is suitable for analysing small and/or precious samples such as meteorites, mantle peridotites and their mineral separates. We also present newly determined data for the Zr, Nb, Hf and Ta concentrations in USGS silicate reference materials DTS-1, PCC-1, BCR-1, BHVO-1 and AGV-1, GSJ reference materials JB-1, -2, -3, JA-1, -2 and -3, and the Smithsonian reference Allende powder.  相似文献   
49.
50.
This study was conducted to evaluate and compare the litterfall dynamics of three mangrove species in the family Rhizophoraceae: Rhizophora stylosa, Kandelia obovata, and Bruguiera gymnorrhiza, in Manko Wetland, Okinawa Island, Japan. Over 3?years, these species showed highest litterfall of leaves and stipules in summer and the lowest litterfall in winter. Litterfall of flowers and fruits peaked in July for R. stylosa, and in August and again in October?CNovember for K. obovata. Litterfall of flower buds, flowers, and propagules occurred throughout the year for B. gymnorrhiza, but was highest in summer. Litterfall of propagules was highest in September and May for R. stylosa and K. obovata, respectively. Kendall??s coefficient of concordance revealed that the monthly changes for leaf, stipule, flower, and fruit litterfalls of all the species were strongly and significantly concordant among the years. The conversion rate of flowers to propagules was 2.3?% in R. stylosa, 5.9?% in K. obovata, and 10.3?% in B. gymnorrhiza. Total annual litterfall in R. stylosa was significantly different from K. obovata and B. gymnorrhiza; however, the latter two species showed no significant differences. Leaves contributed the most to the total litterfall of all three species, and represented 58.4, 54.0, and 50.4?% of the total litterfall for R. stylosa, K. obovata, and B. gymnorrhiza, respectively. Except for branches and flower bud primordia, all other components of litterfall had clear annual cycles for all three species. Rhizophora stylosa and K. obovata showed a negative correlation between leaf production and reproductive organ production, but B. gymnorrhiza tended to increase leaf production with increasing reproductive organ production.  相似文献   
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