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1.

The temperature distribution at depth is a key variable when assessing the potential of a supercritical geothermal resource as well as a conventional geothermal resource. Data-driven estimation by a machine-learning approach is a promising way to estimate temperature distributions at depth in geothermal fields. In this study, we developed two methodologies—one based on Bayesian estimation and the other on neural networks—to estimate temperature distributions in geothermal fields. These methodologies can be used to supplement existing temperature logs, by estimating temperature distributions in unexplored regions of the subsurface, based on electrical resistivity data, observed geological/mineralogical boundaries, and microseismic observations. We evaluated the accuracy and characteristics of these methodologies using a numerical model of the Kakkonda geothermal field, Japan, where a temperature above 500 °C was observed below a depth of about 3.7 km. When using geological and geophysical knowledge as prior information for the machine learning methods, the results demonstrate that the approaches can provide subsurface temperature estimates that are consistent with the temperature distribution given by the numerical model. Using a numerical model as a benchmark helps to understand the characteristics of the machine learning approaches and may help to identify ways of improving these methods.

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2.
Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ34S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ34S values in the lower bedded chert, and an upward‐increasing trend in δ34S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides.  相似文献   
3.
Polybrominated diphenyl ethers (PBDEs) and organochlorine compounds (OCs) were determined in the blubber, liver and kidney of Indo-Pacific humpback dolphins (Sousa chinensis) and finless porpoises (Neophocaena phocaenoides) stranded in Hong Kong coastal waters during 1995–2001. Among the organohalogen compounds analyzed, DDTs were the most dominant contaminants with concentrations ranging from 9.9 to 470 μg/g lipid wt. PBDEs in Hong Kong cetaceans, which are reported for the first time, were detected in all the samples with values ranging from 0.23 to 6.0 μg/g lipid wt., with a predominance of BDE-47. Results from this study suggest PBDEs should be classified as priority pollutants in Asia. Higher concentrations were found in humpback dolphins than in finless porpoises, and this was attributed mainly to differences in habitat. Elevated residues of PCBs and DDTs in some cetaceans suggest these species may be at risk.  相似文献   
4.
Blubber samples of Baikal seals pups (Phoca sibirica) collected in 2001 and 2002 were analyzed for persistent organochlorines (OCs) such as PCBs (polychlorinated biphenyls), DDTs (dichlorodiphenyltrichloroethane and its metabolites), HCHs (hexachlorocyclohexane isomers), CHLs (chlordane related compounds), TCPMe [tris(4-chlorophenyl)methane] and TCPMOH [tris(4-chlorophenyl)methanol]. The distribution pattern of OCs was in the following order: DDTs>PCBs>CHLs>HCHs>TCPMOH>TCPMe. Organochlorine concentrations and composition patterns in eight pup blubber samples (2002) analyzed in the present study were compared with the corresponding levels in juvenile Baikal seals from 1992 survey, and it was found that residue levels of OC compounds have declined during the 10 year period. In particular, concentrations of PCBs, HCHs and CHLs in seals collected in 2002 were approximately two times lower, while DDTs levels were three times lower than the corresponding levels in 1992. Furthermore, higher ratios of beta-HCH/HCHs and p,p(')-DDE/DDTs were found in 2002 samples. While comparing the OC levels with those in other seal pups it appeared that all the OC concentrations were lower than the levels in seals from coastal California known as one of the most polluted areas. PCB and DDT concentrations in the present specimens were higher than that in Arctic seal pups. The proportions of tri-, tetra-, penta- and hexachlorobiphenyls in pups captured in 2002 were higher than those in 1992. TEQ concentrations of non- and mono-ortho coplanar PCBs in Baikal seals collected in 2002 were higher than those in seals collected from some locations in the world, where human and industrial activities are extensive, suggesting potential for toxic implications of coplanar PCBs in Baikal seals.  相似文献   
5.
NOAA/AVHRR Global Vegetation Index (GVI) data of Asia in 1983 and 1987 were used to evaluate their usefulness for global land cover monitoring. Color composite images of monthly GVI data and color composite images of principal components from 12 successive monthly GVI data were found to be useful for visual interpretation of seasonal vegetation dynamics. The results of cluster analysis applied to monthly GVI data for a one‐year period, indicate that unsupervised classification method is useful for global or continental land cover classification without ground truth. In order to detect land cover changes, the difference between the 1983 and 1987 12‐month GVI data was calculated. The results show that it is difficult to detect land cover changes due to cloud contamination in monthly GVI data and poor registration of GVI products.  相似文献   
6.
7.
Abstract. A series of mudstones corresponding to N.8 to N.17 of Blow from the Uyashinai Mudstone Member, the Onnagawa Formation and the Funakawa Formation in the Taiheizan area of the central Green Tuff region, northeast Japan, was examined by chemical analysis. According to conventional chemical systematics, the mudstones are analyzed in terms of detrital, biogenic-A (siliceous), biogenic-B (calcareous) and hydrogenous components. The relative contribution of the biogenic-A (siliceous) component increases in upward succession in the Uyashinai and Onnagawa mudstones, whereas the contribution of the biogenic-B (calcareous) component is restricted to the lower Uyashinai mudstones. The contribution of hydrogenous components Zn, Pb, Cu and Ba tends to increase during the Nishikurosawa stage, and decreases near the Nishikurosawa/Onnagawa boundary (Pb and Ba) or in the Onnagawa stage (Zn and Cu). The observed enrichment of heavy metals in the Uyashinai mudstones is attributed to the onset of vigorous upwelling of deep water with higher nutrient and metal content associated with a contemporaneous change in global deep-water circulation.  相似文献   
8.
Abstract. A comprehensive investigation was carried out on the distribution of both trace fossils and sulfur isotopes in mud-stones in the Hokuroku district, northeast Japan, in the hope of delineating the depositional environment of the mudstones in which the Kuroko deposits are embedded. The mudstones are generally massive in structure and usually contain large trace fossils, being indicative of an aerobic biofacies. On the other hand, some mudstones in and above the Kuroko ore horizon are partly laminated and usually contain smaller trace fossils, being assignable to an anaerobic or dysaerobic biofacies. The δ34S values of sulfides in the mudstones above and below the ore horizon range from -40 to -12 %o, indicating mostly oxic depositional conditions in equilibrium with the inferred aerobic biofacies. In the mudstones in the ore horizon, the δ34S values exhibit regionally discriminated variations: -44 to -12 %o in areas far (>1 km) from the known Kuroko deposits and -24 to +6 %o in areas closer to them. The latter high δ34S group implies the temporal occurrence of local anoxic basins in the vicinity of the known Kuroko deposits. At the time of late Nishikurosawa Stage (i.e. the currently assumed Kuroko metallogenic epoch), an intense oceanic stagnation is suggested to have taken place to form the local anoxic basins responsible for the formation and preservation of Kuroko deposits. This oceanic environmental event is considered to be most likely due to increasing biological productivity primarily triggered and enhanced by upwelling of NADW in the paleo-Sea of Japan at that time.  相似文献   
9.
Abstract. Chemical and sulfur isotopic compositions were obtained for a series of rocks within the chert‐clastic sequence surrounding the Kajika massive sulfide ore horizon at Shibukawasawa in the Ashio copper‐mining district, Ashio Terrane, central Japan. The sequence is lithologically classified into three units: chert, siliceous shale with basic volcanics, and sandstone‐shale, in ascending stratigraphic order. The Kajika ore horizon corresponds to the lowermost part of the unit that contains siliceous shale with basic volcanics. The rocks around the Kajika ore horizon are enriched in P2O5 (max. 0.22 %), Ba (max. 2400 ppm), Cu (595 ppm), V (323 ppm), Pb (168 ppm), Zn (124 ppm), and Mo (24 ppm) in siliceous shale; and Ba (4220 ppm), Zr (974 ppm), Cr (718 ppm), Ni (492 ppm), V (362 ppm), Zn (232 ppm), Nb (231 ppm), and Co (71 ppm) in the basic volcanics. The siliceous shale is enriched in a number of redox‐sensitive elements such as Cu, V, Pb, Zn, and Mo, which are known to be enriched in black shale and anoxic and hydrothermal sediments. The δ34S values of sulfides in the chert and sandstone‐shale lie in the range of 0±2 %, and those in the siliceous shale range from ‐5 to ‐14 %. The measured δ34S values in the basic volcanics are ‐0.3, ‐2.7, and ‐31.5 %. These heavier δ34S signatures (around 0 %) recorded throughout the sequence indicate that the rocks formed under anoxic bottom‐water conditions. Slightly lighter δ34S values recorded in siliceous shale might reflect significant mixing of sulfides that formed by sulfate‐reducing bacteria in an overlying oxic environment. The long‐term duration of anoxic conditions indicated by the heavier δ34S signature is considered to have played an important role in protecting the Kajika sulfide ores from oxidative decomposition and preserving the ores in sedimentary accumulations.  相似文献   
10.
Organochlorine compounds (OCs) such as polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethane and its metabolites (DDTs), chlordane related compounds, hexachlorocyclohexane isomers (HCHs), hexachlorobenzene (HCB), tris(4-chlorophenyl) methane (TCPMe) and tris(4-chlorophenyl) methanol were determined in the blubber of Dall's porpoises (Phocoenoides dalli) collected from Japanese coastal waters in 1998/1999. Among OCs analyzed, PCBs were the predominant contaminants with concentrations ranging from 1.5 to 39 microg/g on a wet weight basis. OCs concentrations were relatively low and less variable in mature females possibly due to the lactational excretion from their bodies, while in males the concentrations were increased with body length. Concentrations and compositions of DDTs and HCHs showed significant differences between the truei-type population off the Pacific coast of northern Japan and dalli-type from the Sea of Japan/Okhotsk, suggesting its usefulness to discriminate different populations. OCs levels detected in truei-type porpoises collected in 1998/1999 were lower than those collected in 1984, except TCPMe. On the other hand, except DDTs, the residue levels of other organochlorines in dalli-type porpoises showed no significant decrease since 1984.  相似文献   
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