High-Precision Trace Element Data for the USGS Reference Materials BCR-1, BCR-2, BHVO-1, BHVO-2, AGV-1, AGV-2, DTS-1, DTS-2, GSP-1 and GSP-2 by ID-TIMS and MIC-SSMS   总被引：2，自引：0，他引：2  

Ingrid Raczek  Brigitte Stoll  Albrecht W. Hofmann  Klaus Peter Jochum 《Geostandards and Geoanalytical Research》2001,25(1):77-86

Different batches of the new US Geological Survey (USGS) reference materials (RMs) BCR-2, BHVO-2, AGV-2, DTS-2 and GSP-2 and the original USGS RMs BCR-1, BHVO-1, AGV-1, DTS-1 and GSP-1 have been analysed by isotope dilution using thermal ionisation mass spectrometry (ID-TIMS) and by multi-ion counting spark source mass spectrometry (MIC-SSMS). The concentrations of K, Rb, Sr, Ba and the rare earth elements were determined with overall analytical uncertainties of better than 1% (ID-TIMS) and 3% (MIC-SSMS). The analyses of different aliquots and batches of BCR-2, BHVO-2, AGV-2 and GSP-2, respectively, agree within 1%, i.e. approximately the analytical uncertainties of the data. This indicates an homogeneous distribution of the trace elements in these RMs. Differences in element concentrations of up to 17% in different aliquots of the depleted RM DTS-2 are outside the analytical uncertainty of our data. They may be attributed to a slightly heterogeneous distribution of trace elements in this dunite sample. Our trace element data for BCR-2, BHVO-2, AGV-2 and GSP-2 agree within about 3% with preliminary reference values published by the USGS. They also agree within 1-6% with those of the original RMs BCR-1, BHVO-1, AGV-1 and GSP-1. Large compositional differences are found between DTS-2 and DTS-1, where the concentrations of K, Rb, Sr and the light REE differ by factors of 2 to 24.  相似文献   

Parameters of “Macromaturity” (PMM): novel rank and type related indices from chemical degradation of macromolecular network of coals     

Ph. Blanc  P. Albrecht   《Organic Geochemistry》1991,17(6)

Benzene polycarboxylic acids formed upon oxidative degradation of the macromolecular network of a set of French coals with ruthenium tetroxide are proposed as the basis of new coal rank indices. Their distribution probably reflects the degree of condensation of the polyaromatic subunits occurring in the network of the coals. This feature is illustrated in the case of the benzene tetracarboxylic acids. Application of these molecular indices to Gondwana coals, as well as to maceral concentrates indicates that they are also type related. They could prove particularly useful in the case of coals or kerogens having undergone secondary alteration processes.  相似文献   

Intercomparison of sediment sampling techniques by means of radionuclide and heavy metal analysis     

Dr. Hartmut Nies  Dr. Horst Albrecht  Volker Rechenberg  Ingo Goroncy  Dr. Henning Dahlgaard  Dietmar Weiß  Prof. Dr. Lutz Brügmann 《Ocean Dynamics》1990,43(1):27-53

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Chemical differentiation of the Earth: the relationship between mantle, continental crust, and oceanic crust   总被引：59，自引：0，他引：59  

Albrecht W. Hofmann 《Earth and Planetary Science Letters》1988,90(3)

The average chemical compositions of the continental crust and the oceanic crust (represented by MORB), normalized to primitive mantle values and plotted as functions of the apparent bulk partition coefficient of each element, form surprisingly simple, complementary concentration patterns. In the continental crust, the maximum concentrations are on the order of 50 to 100 times the primitive-mantle values, and these are attained by the most highly incompatible elements Cs, Rb, Ba, and Th. In the average oceanic crust, the maximum concentrations are only about 10 times the primitive mantle values, and they are attained by the moderately incompatible elements Na, Ti, Zr, Hf, Y and the intermediate to heavy REE.This relationship is explained by a simple, two-stage model of extracting first continental and then oceanic crust from the initially primitive mantle. This model reproduces the characteristic concentration maximum in MORB. It yields quantitative constraints about the effective aggregate melt fractions extracted during both stages. These amount to about 1.5% for the continental crust and about 8–10% for the oceanic crust.The comparatively low degrees of melting inferred for average MORB are consistent with the correlation of Na₂O concentration with depth of extrusion [1], and with the normalized concentrations of Ca, Sc, and Al ( 3) in MORB, which are much lower than those of Zr, Hf, and the HREE ( 10). Ca, Al and Sc are compatible with clinopyroxene and are preferentially retained in the residual mantle by this mineral. This is possible only if the aggregate melt fraction is low enough for the clinopyroxene not to be consumed.A sequence of increasing compatibility of lithophile elements may be defined in two independent ways: (1) the order of decreasing normalized concentrations in the continental crust; or (2) by concentration correlations in oceanic basalts. The results are surprisingly similar except for Nb, Ta, and Pb, which yield inconsistent bulk partition coefficients as well as anomalous concentrations and standard deviations.The anomalies can be explained if Nb and Ta have relatively large partition coefficients during continental crust production and smaller coefficients during oceanic crust production. In contrast, Pb has a very small coefficient during continental crust production and a larger coefficient during oceanic crust production. This is the reason why these elements are useful in geochemical discrimination diagrams for distinguishing MORB and OIB on the one hand from island arc and most intracontinental volcanics on the other.The results are consistent with the crust-mantle differentiation model proposed previously [2]. Nb and Ta are preferentially retained and enriched in the residual mantle during formation of continental crust. After separation of the bulk of the continental crust, the residual portion of the mantle was rehomogenized, and the present-day internal heterogeneities between MORB and OIB sources were generated subsequently by processes involving only oceanic crust and mantle. During this second stage, Nb and Ta are highly incompatible, and their abundances are anomalously high in both OIB and MORB.The anomalous behavior of Pb causes the so-called “lead paradox”, namely the elevated U/Pb and Th/Pb ratios (inferred from Pb isotopes) in the present-day, depleted mantle, even though U and Th are more incompatible than Pb in oceanic basalts. This is explained if Pb is in fact more incompatible than U and Th during formation of the continental crust, and less incompatible than U and Th during formation of oceanic crust.  相似文献   

The Preparation and Preliminary Characterisation of Eight Geological MPI-DING Reference Glasses for In-Situ Microanalysis   总被引：13，自引：4，他引：9  

Klaus Peter Jochum  Donald B. Dingwell  Alexander Rocholl  Brigitte Stoll  Albrecht W. Hofmann  S. Becker  A. Besmehn  D. Bessette  H.-J. Dietze  P. Dulski  J. Erzinger  E. Hellebrand  P. Hoppe  I. Horn  K. Janssens  G.A. Jenner  M. Klein  W.F. McDonough  M. Maetz  K. Mezger  C. Müker  I.K. Nikogosian  C. Pickhardt  I. Raczek  D. Rhede  H.M. Seufert  S.G. Simakin  A.V. Sobolev  B. Spettel  S. Straub  L. Vincze  A. Wallianos  G. Weckwerth  S. Weyer  D. Wolf  M. Zimmer 《Geostandards and Geoanalytical Research》2000,24(1):87-133

Eight silicate glasses were prepared by directly fusing and stirring 50-100 g each of basalt, andesite, komatiite, peridotite, rhyolite, and quartz-diorite. These are referred to as MPI-DING glasses and were made for the purpose of providing reference materials for geochemical, in-situ microanalytical work. Results from various analytical techniques indicate that individual glass fragments are well homogenised with respect to major and trace elements at the μm to mm scale. Heterogeneities due to quench crystallisation of olivine have been observed in small and limited areas of the two komatiitic glasses. In order to obtain concentration values for as many elements as possible, the glasses were analysed by a variety of bulk and microanalytical methods in a number of laboratories. The analytical uncertainties of most elements are estimated to be between 1% and 10%. From the analytical data, preliminary reference values for more than sixty elements were calculated. The analytical uncertainties of most elements are estimated to be between 1% and 10%.  相似文献   

Pressure effects on regional mean sea level trends in the German Bight in the twenty-first century     

Frauke Albrecht  Ralf Weisse 《Ocean Dynamics》2014,64(5):633-642

The effect of large-scale atmospheric pressure changes on regional mean sea level projections in the German Bight in the twenty-first century are considered. A developed statistical model is applied to climate model data of sea level pressure for the twenty-first century to assess the potential contribution of large-scale atmospheric changes to future sea level changes in the German Bight. Using 78 experiments, an ensemble mean of 1.4-cm rise in regional mean sea level is estimated until the end of the twenty-first century. Changes are somewhat higher for realisations of the special report on emission scenarios (SRES) A1B and A2, but generally do not exceed a few centimeters. This is considerably smaller than the changes expected from steric and self-gravitational effects. Large-scale changes in sea level pressure are thus not expected to provide a substantial contribution to twenty-first century sea level changes in the German Bight.  相似文献   

Petrogenetic and metallogenetic responses to Miocene slab flattening: new constraints from the El Indio-Pascua Au–Ag–Cu belt,Chile/Argentina     

Thomas?BissigEmail author  Alan?H.?Clark  James?K.?W.?Lee  Albrecht?von?Quadt 《Mineralium Deposita》2003,38(7):844-862

The Eocene–Miocene volcanic and hypabyssal rocks of the El Indio-Pascua Au–Ag–-Cu belt in the southern central Andean flat-slab region are medium–high-K calc-alkaline arc suites, ranging in composition from andesite to rhyolite. A significant transition in magmatic trace element chemistry, coinciding with a pronounced reduction in magma output, occurred in the late-Middle Miocene as documented by ⁴⁰Ar–³⁹Ar geochronology. The upper Eocene–lower-Middle Miocene rocks exhibit low Sr/Y ratios (<50), minor heavy REE fractionation with Sm/Yb ratios not exceeding 3.5 and, in some cases, minor negative Eu anomalies. In contrast, the largely dacitic rocks erupted after ca. 13 Ma are depleted in Y (10 ppm), have generally high, but variable Sr/Y ratios (30–200), exhibit moderate middle and heavy REE fractionation (Sm/Yb: 3.7–5.9) and lack negative Eu anomalies. The latter features are characteristic of adakitic suites (i.e. slab-melts), but the regional temporal and spatial distribution of arc magmatism precludes a major magma source in the downgoing slab. This evolution is interpreted as reflecting a progressive increase in pressure and the availability of water in the lower-crustal site of magma generation, establishing both garnet and hornblende as major stable phases in the residuum. The pressure in the lower crust increased in response to episodic crustal thickening related to the shallowing of the slab, a process recorded by the incision of three regional pediplains over the period 17–6 Ma. Elimination of the subarc asthenospheric mantle and much of the lithospheric mantle by ca. 10 Ma permitted direct incursion of slab-derived, highly oxidised metal- and volatile-rich supercritical fluids into the lower crust, stimulating melting of mafic, garnet amphibolitic and eclogitic assemblages.The igneous suites emplaced from 36–11 Ma were associated with widespread, and locally intense, epizonal hydrothermal activity, but this was barren of base and precious metals. The shallow-crustal availability of abundant water highlighted in earlier models was therefore not a metallogenetic determinant. Moreover, economic Au–Ag–Cu mineralization, associated with small volumes of dacitic magma, was restricted to the interval 9.5–5 Ma, and was not initiated until at least 3.5 my after the inception of high-pressure magma generation. In contrast to previous metallogenetic studies, we therefore suggest that this petrochemical transition was not inherently favourable for ore formation. We propose that the incursion of highly oxidized supercritical fluids from the slab into the lower crust was ultimately responsible for the brief Late Miocene metallogenetic episode.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial handling: V. Bouchot  相似文献   

The European HST science data archive     

F. Pasian  B. Pirenne  R. Albrecht  G. Russo 《Experimental Astronomy》1992,2(6):377-389

The design of the Data Management Facility (DMF), the system to handle the data from HST, has been based on the concepts of modularity and flexibility, so that changes inevitably due to occur during the long lifetime of the project could be gracefully accomodated. At the Space Telescope European Coordinating Facility (ST-ECF), new constraints have led the archive group to evolve the system, so to allow a more efficient ingesting of the data imported from the Space Telescope Science Institute (STScI), an easier browsing of the HST catalogue of observations, and a more efficient servicing of archive researchers' retrieval requests. In this paper, the European Science Data Archive of HST data is described, with particular reference to dataflow, hardware and software system structure, operations, differences with DMF, and foreseen developments.Affiliated with the Astrophysics Division, Space Science Dept., ESAThe observations of the NASA/ESA Hubble Space Telescope are obtained at the Space Telescope Science Institute, which is operated by AURA, Inc., under NASA contract NAS 5-26555.  相似文献   

Pre-Variscan geological events in the Austrian part of the Bohemian Massif deduced from U–Pb zircon ages     

Gertrude?FriedlEmail author  Fritz?Finger  Jean-Louis?Paquette  Albrecht?von?Quadt  Neal?J.?McNaughton  Ian?R.?Fletcher 《International Journal of Earth Sciences》2004,93(5):802-823

In an attempt to elucidate the pre-Variscan evolution history of the various geological units in the Austrian part of the Bohemian Massif, we have analysed zircons from 12 rocks (mainly orthogneisses) by means of SHRIMP, conventional multi-grain and single-grain U–Pb isotope-dilution/mass-spectrometry. Two of the orthogneisses studied represent Cadomian metagranitoids that formed at ca. 610 Ma (Spitz gneiss) and ca. 580 Ma (Bittesch gneiss). A metagranite from the Thaya batholith also gave a Cadomian zircon age (567±5 Ma). Traces of Neoproterozoic zircon growth were also identified in several other samples, underlining the great importance of the Cadomian orogeny for the evolution of crust in the southern Bohemian Massif. However, important magmatic events also occurred in the Early Palaeozoic. A sample of the Gföhl gneiss was recognised as a 488±6 Ma-old granite. A tonalite gneiss from the realm of the South Bohemian batholith was dated at 456±3 Ma, and zircon cores in a Moldanubian metagranitic granulite gave similar ages of 440–450 Ma. This Ordovician phase of magmatism in the Moldanubian unit is tentatively interpreted as related to the rifting and drift of South Armorica from the African Gondwana margin. The oldest inherited zircons, in a migmatite from the South Bohemian batholith, yielded an age of ca. 2.6 Ga, and many zircon cores in both Moravian and Moldanubian meta-granitoid rocks gave ages around 2.0 Ga. However, rocks from the Moldanubian unit show a striking lack of zircon ages between 1.8 and 1.0 Ga, reflecting an ancestry from Armorica and the North African part of Gondwana, respectively, whereas the Moravian Bittesch gneiss contains many inherited zircons with Mesoproterozoic and Early Palaeoproterozoic ages of ca. 1.2, 1.5 and 1.65–1.8 Ga, indicating a derivation from the South American part of Gondwana.  相似文献   

Exposure history of glass and breccia phases of lunar meteorite EET87521     

O. Eugster  Ch. Thalmann  A. Albrecht  G. F. Herzog  J. S. Delaney  J. Klein  R. Middleton 《Meteoritics & planetary science》1996,31(2):299-304

Abstract— Glass-rich separates were prepared from a sample of the basaltic lunar meteorite EET87521 rich in dark glass. Noble gas isotopic abundances and ²⁶Al and ¹⁰Be activities were measured to find out whether shock effects associated with lunar launch helped to assemble these phases. Similar ¹⁰Be and ²⁶Al activities indicate that all materials in EET87521 had a common exposure history in the last few million years before launch. However, the glass contains much higher concentrations of trapped gases and records a much longer cosmic-ray exposure, 100 Ma–150 Ma, in the lunar regolith than does the bulk sample. The different histories show that the glass existed long before the ejection of EET87521. The trapped ⁴⁰Ar/³⁶Ar ratio of 1.6 ± 0.1 implies that the lunar exposure that produced most of the stable cosmogenic noble gases began 500 Ma ago. Cosmogenic and trapped noble gas components correlate strongly in various temperature-release fractions and phases of EET87521, which is probably because the glass contains most of the gas. The trapped solar ratios, ²⁰Ne/²²Ne = 12.68 ± 0.20 and ³⁶Ar/³⁸Ar = 5.24 ± 0.05 can be understood as resulting from a mixture consisting of ～60% solar wind and 40% solar energetic particles (SEP). All EET87521 phases show a ⁴⁰K-⁴⁰Ar gas retention age of ～3300 Ma, which is in the range of typical lunar mare basalts.  相似文献