Quantitative elemental mapping of granulite-facies monazite: Textural insights and implications for petrochronology     

Owen M. Weller  Simon Jackson  William G. R. Miller  Marc R. St-Onge  Nicole Rayner 《Journal of Metamorphic Geology》2020,38(8):853-880

Texturally complex monazite grains contained in two granulite-facies pelitic migmatites from southern Baffin Island, Arctic Canada, were mapped by laser ablation-inductively coupled plasma-mass spectrometry (using spot sizes ≤5 µm) to quantitatively determine the spatial variation in trace element chemistry (with up to 1,883 analyses per grain). The maps highlight the chemical complexity of monazite grains that have experienced multiple episodes of growth, resorption and chemical modification by dissolution–precipitation during high-grade metamorphism. Following detailed chemical characterization of monazite compositional zones, a related U–Pb data set is re-interpreted, allowing petrologically significant ages to be extracted from a continuum of concordant data. Synthesis of these data with pseudosection modelling of prograde and peak conditions allows for the temporal evolution of monazite trace element chemistry to be placed in the context of the evolving P–T conditions and major phase assemblage. This approach enables a critical evaluation of three commonly used petrochronological indicators: linking Y to garnet abundance, the Eu anomaly to feldspar content and Th/U to anatectic processes. Europium anomalies and Th/U behave in a relatively systematic fashion, suggesting that they are reliable petrochronological witnesses. However, Y systematics are variable, both within domains interpreted to have grown in a single event, between grains interpreted to be part of the same age population, and between samples that experienced similar metamorphic conditions and mineral assemblages. These observations caution against generalized petrological interpretations on the basis of Y content, as it suggests Y concentrations in monazite are controlled by domainal equilibria. The results reveal a c. 45 Myr interval between prograde metamorphism and retrograde melt crystallization in the study area, emphasizing the long-lived nature of heat flow in high-grade metamorphic terranes. Such long timescales of metamorphism would be assisted by the growth, retention and dominance of high-Th suprasolidus monazite, as observed in this study, contributing to the radiogenic heating budget of mid- to lower-crustal environments. Careful characterization of monazite grains suggests that continuum-style U–Pb data sets can be decoded to provide insights into the duration of metamorphic processes.  相似文献   

Assessing and correcting the effects of the chemical weathering of potsherds: A case study using soft-paste porcelain wasters from the Longton Hall (Staffordshire) factory site     

J. Victor Owen  Terence E. Day 《Geoarchaeology》1998,13(3):265-286

Unglazed soft-paste porcelain wasters from the Longton Hall factory site are variably depleted (75–80 rel %) in CaO relative to comparatively insoluble components (e.g., Al₂O₃, TiO₂) due to the dissolution of wollastonite (CaSiO₃, a pyroxenoid) by subsurface water. The degree of desilicification is variable (0–45 rel % SiO₂). Petrographic data and element-abundance plots suggest that these were the principal effects of the chemical weathering process in most samples. The preferential dissolution of a single phase in the unglazed Longton Hall sherds permits the semiquantitative “reversal” of weathering phenomena. Alteration effects can be corrected using porosity–volume data to constrain the amount of wollastonite originally present in the weathered sherds. The original compositions of the unglazed wasters are bracketed by arithmetically “adding back” the missing pyroxenoid components according to two endmember assumptions concerning element mobility: (1) the total leaching of wollastonite components and (2) the preferential leaching of wollastonite-derived CaO. These calculations—particularly the latter—yield results that compare favourably with the compositions of relatively unaltered (wollastonite-bearing), glazed samples from the Longton Hall site. Given the potential susceptibility of archaeological ceramics to chemical weathering, it would seem prudent that these phenomena be carefully assessed, and corrected where possible, so that analytical data for these artifacts can be judiciously interpreted. © 1998 John Wiley & Sons, Inc.  相似文献   

Rates of rockwall slope erosion in the upper Bhagirathi catchment,Garhwal Himalaya     

Elizabeth N. Orr  Lewis A. Owen  Sourav Saha  Marc W. Caffee 《地球表面变化过程与地形》2019,44(15):3108-3127

Rockwall slope erosion is defined for the upper Bhagirathi catchment using cosmogenic Beryllium-10 (¹⁰Be) concentrations in sediment from medial moraines on Gangotri glacier. Beryllium-10 concentrations range from 1.1 ± 0.2 to 2.7 ± 0.3 × 10⁴ at/g SiO₂, yielding rockwall slope erosion rates from 2.4 ± 0.4 to 6.9 ± 1.9 mm/a. Slope erosion rates are likely to have varied over space and time and responded to shifts in climate, geomorphic and/or tectonic regime throughout the late Quaternary. Geomorphic and sedimentological analyses confirm that the moraines are predominately composed of rockfall and avalanche debris mobilized from steep relief rockwall slopes via periglacial weathering processes. The glacial rockwall slope erosion affects sediment flux and storage of snow and ice at the catchment head on diurnal to millennial timescales, and more broadly influences catchment configuration and relief, glacier dynamics and microclimates. The slope erosion rates exceed the averaged catchment-wide and exhumation rates of Bhagirathi and the Garhwal region on geomorphic timescales (10³−10⁵ years), supporting the view that erosion at the headwaters can outpace the wider catchment. The ¹⁰Be concentrations of medial moraine sediment for the upper Bhagirathi catchment and the catchments of Chhota Shigri in Lahul, northern India and Baltoro glacier in Central Karakoram, Pakistan show a tentative relationship between ¹⁰Be concentration and precipitation. As such there is more rapid glacial rockwall slope erosion in the monsoon-influenced Lesser and Greater Himalaya compared to the semi-arid interior of the orogen. Rockwall slope erosion in the three study areas, and more broadly across the northwest Himalaya is likely governed by individual catchment dynamics that vary across space and time. © 2019 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons, Ltd.  相似文献   

Modelling failure mechanisms to explain rock slope change along the Isle of Purbeck coast,UK     

Robert J. Allison  Owen G. Kimber 《地球表面变化过程与地形》1998,23(8):731-750

Results are presented of distinct element computer modelling used to examine rates and mechanisms of change in rock slopes and cliffs, where material intact properties determine process and form but the most significant controls are the joint pattern and cross-joint properties. The modelling approach does not appear to have been used before in a geomorphological context and provides an alternative approach for examining cliff development. Field and laboratory data have been collected for the Portland Limestone outcrop of the Isle of Purbeck, central southern England. The Portland Limestome is a hard, shelly, crystalline sediment of the Upper Jurassic. It has a regular discontinuity pattern throughout the outcrop in Purbeck. While joint orientation remains relatively constant, bedding changes from horizontal to vertical, a consequence of the Purbeck Monocline. There are resulting implications for spatial variations in rock slope evolution. The modelling exercise enhances previous knowledge on rock failure mechanisms and slope development along the Purbeck coast and demonstrates its potential in research where landforms are developed in lithified, jointed rock masses. © 1998 John Wiley & Sons, Ltd.  相似文献   

Very slow erosion rates and landscape preservation across the southwestern slope of the Ladakh Range,India          下载免费PDF全文

Craig Dietsch  Jason M. Dortch  Scott A. Reynhout  Lewis A. Owen  Marc W. Caffee 《地球表面变化过程与地形》2015,40(3):389-402

Erosion rates are key to quantifying the timescales over which different topographic and geomorphic domains develop in mountain landscapes. Geomorphic and terrestrial cosmogenic nuclide (TCN) methods were used to determine erosion rates of the arid, tectonically quiescent Ladakh Range, northern India. Five different geomorphic domains are identified and erosion rates are determined for three of the domains using TCN ¹⁰Be concentrations. Along the range divide between 5600 and 5700 m above sea level (asl), bedrock tors in the periglacial domain are eroding at 5.0 ± 0.5 to 13.1 ± 1.2 meters per million years (m/m.y.)., principally by frost shattering. At lower elevation in the unglaciated domain, erosion rates for tributary catchments vary between 0.8 ± 0.1 and 2.0 ± 0.3 m/m.y. Bedrock along interfluvial ridge crests between 3900 and 5100 m asl that separate these tributary catchments yield erosion rates <0.7 ± 0.1 m/m.y. and the dominant form of bedrock erosion is chemical weathering and grusification. Erosion rates are fastest where glaciers conditioned hillslopes above 5100 m asl by over‐steepening slopes and glacial debris is being evacuated by the fluvial network. For range divide tors, the long‐term duration of the erosion rate is considered to be 40–120 ky. By evaluating measured ¹⁰Be concentrations in tors along a model ¹⁰Be production curve, an average of ~24 cm is lost instantaneously every ~40 ky. Small (<4 km²) unglaciated tributary catchments and their interfluve bedrock have received very little precipitation since ~300 ka and the long‐term duration of their erosion rates is 300–750 ky and >850 ky, respectively. These results highlight the persistence of very slow erosion in different geomorphic domains across the southwestern slope of the Ladakh Range, which on the scale of the orogen records spatial changes in the locus of deformation and the development of an orogenic rain shadow north of the Greater Himalaya. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Schmidt‐hammer exposure‐age dating (SHD) of snow‐avalanche impact ramparts in southern Norway: approaches,results and implications for landform age,dynamics and development          下载免费PDF全文

John A. Matthews  Lindsey J. McEwen  Geraint Owen 《地球表面变化过程与地形》2015,40(13):1705-1718

Schmidt‐hammer exposure‐age dating (SHD) was applied to the problem of dating the diachronous surfaces of five distal river‐bank boulder ramparts deposited by snow avalanches plunging into the Jostedøla and Sprongdøla rivers in the Jostedalsbreen region of southern Norway. Approaches to local high‐precision linear age calibration, which controlled in different ways for boulder roundness, were developed. The mean age (SHD_mean) and the maximum age (SHD_max) of surface boulders were estimated for whole ramparts, crests and distal fringes. Interpretation was further assisted by reference to R‐value distributions. SHD_mean ages (with 95% confidence intervals) ranged from 520 ± 270 years to 5375 ± 965 years, whereas SHD_max ages (expected to be exceeded by <5% of surface boulders) ranged from 675 to 9065 years. SHD ages from the Jostedøla ramparts tended to be older than those associated with the Sprongdøla, rampart crests were younger than the respective distal fringes, and use of relatively rounded boulders yielded more consistent SHD ages than angular boulders. The SHD_mean ages indicate differences in recent levels of snow‐avalanche activity between ramparts and provide insights into rampart dynamics as boulders are deposited on rampart crests and, in smaller numbers, on the distal fringes. SHD_max ages provide minimum age estimates of rampart age (i.e. the time elapsed since the ramparts began to form) and suggest that at least some of the ramparts have been developing since the early Holocene. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Comparing flow regime,channel hydraulics,and biological communities to infer flow–ecology relationships in the Mara River of Kenya and Tanzania     

Michael E. McClain  Amanda L. Subalusky  Elizabeth P. Anderson  Shimelis Behailu Dessu  Assefa M. Melesse  Preksedis M. Ndomba 《水文科学杂志》2014,59(3-4):801-819

Abstract

Equatorial rivers of East Africa exhibit unusually complex seasonal and inter-annual flow regimes, and aquatic and adjacent terrestrial organisms have adapted to cope with this flow variability. This study examined the annual flow regime over the past 40 years for three gauging stations on the Mara River in Kenya and Tanzania, which is of international importance because it is the only perennial river traversing the Mara-Serengeti ecoregion. Select environmental flow components were quantified and converted to ecologically relevant hydraulic variables. Vegetation, macroinvertebrates, and fish were collected and identified at target study sites during low and high flows. The results were compared with available knowledge of the life histories and flow sensitivities of the riverine communities to infer flow–ecology relationships. Management implications are discussed, including the need to preserve a dynamic environmental flow regime to protect ecosystems in the region. The results for the Mara may serve as a useful model for river basins of the wider equatorial East Africa region.