Sub-micron scale distributions of trace elements in zircon   总被引：2，自引：1，他引：1  

Amy E. Hofmann  John W. Valley  E. Bruce Watson  Aaron J. Cavosie  John M. Eiler 《Contributions to Mineralogy and Petrology》2009,158(3):317-335

Sub-micron scale zoning of Ti concentrations and correlations between concentrations of Ti and other trace elements (P, Ce, and Y) and cathodoluminescent (CL) banding is observed in natural zircons. Ion images were made using the Caltech Microanalysis Center’s CAMECA NanoSIMS 50L with an O⁻ primary beam focused to ~300 nm on the sample surface. The high spatial resolution of this technique allows for interrogation of chemical variations at or below the scale of CL banding in natural zircons. Images produced in this manner display two types of correlations among Ti, P, Ce, and Y (which appears to be a proxy for CL intensity): strong (correlation coefficients >0.8) and subtle (correlation coefficients ~0.15–0.4). Strongly correlated images, which display Ti variations of ca. a factor of 3 between adjacent CL bands and overall elevated trace element concentrations in CL-dark bands, were found within an oscillatory-zoned, trace element enriched sector of a CL sector-zoned zircon. Three possible causes for such correlations include: temperature-dependent equilibrium partitioning, trace element partitioning limited by diffusion in the host melt and surface-controlled, non-equilibrium growth. Comparison of our data with the expected results of these processes suggests that: (1) Ti partitioning in zircon is dependent upon non-equilibrium effects in addition to temperature and/or (2) the incorporation of elements that co-vary with Ti in zircon (e.g., Y, P and Ce) is also temperature-dependent. Sub-micron scale, high-Ti regions are also found within Proterozoic Adirondack and >4 Ga Jack Hills zircons as well as trace element enrichments (including Ti) along cracks within Jack Hills zircons.  相似文献   

Aerial electromagnetic sounding of the lithosphere of Venus     

Robert E. Grimm  Amy C. Barr  Keith P. Harrison  David E. Stillman  Kerry L. Neal  Michael A. Vincent  Gregory T. Delory 《Icarus》2012,217(2):462-473

Electromagnetic (EM) investigation depths are larger on Venus than Earth due to the dearth of water in rocks, in spite of higher temperatures. Whistlers detected by Venus Express proved that lightning is present, so the Schumann resonances ～10–40 Hz may provide a global source of electromagnetic energy that penetrates ～10–100 km. Electrical conductivity will be sensitive at these depths to temperature structure and hence thermal lithospheric thickness. Using 1D analytic and 2D numerical models, we demonstrate that the Schumann resonances—transverse EM waves in the ground-ionosphere waveguide—remain sensitive at all altitudes to the properties of the boundaries. This is in marked contrast to other EM methods in which sensitivity to the ground falls off sharply with altitude. We develop a 1D analytical model for aerial EM sounding that treats the electrical properties of the subsurface (thermal gradient, water content, and presence of conductive crust) and ionosphere, and the effects of both random errors and biases that can influence the measurements. We initially consider specified 1D lithospheric thicknesses 100–500 km, but we turn to 2D convection models with Newtonian temperature-dependent viscosity to provide representative vertical and lateral temperature variations. We invert for the conductivity-depth structure and then temperature gradient. For a dry Venus, we find that the error on temperature gradient obtained from any single local measurement is ～100%—perhaps enough to distinguish “thick” vs. “thin” lithospheres. When averaging over thousands of kilometers, however, the standard deviation of the recovered thermal gradient is within the natural variability of the convection models, <25%. A “wet” interior (hundreds of ppm H₂O) limits EM sounding depths using the Schumann resonances to <20 km, and errors are too large to estimate lithospheric properties. A 30-km conductive crust has little influence on the dry-interior models because the Schumann penetration depths are significantly larger. We conclude that EM sounding of the interior of Venus is feasible from a 55-km high balloon. Lithospheric thickness can be measured if the upper-mantle water content is low. If H₂O at hundreds of ppm is present, the deeper, temperature-sensitive structure is screened, but the “wet” nature of the upper mantle, as well as structure of the upper crust, is revealed.  相似文献   

Ice grain size and the rheology of the martian polar deposits     

Amy C. Barr  Sarah M. Milkovich 《Icarus》2008,194(2):513-518

The history and dynamics of the martian polar deposits (MPD), the largest known water reservoirs on Mars, are of great interest, but estimates of ice grain size are required before detailed modeling can be performed. We clarify the microphysical processes that may control grain size in the MPD. If the MPD are ∼2% dust by mass, the maximum ice grain size is ∼1 mm due to grain boundary pinning by silicate microparticles. Relatively dusty layers in the MPD will have smaller grain sizes. If MPD ice has a very low impurity content and has experienced a significant amount of strain, grains may reach a steady state size of ∼1.5 to 3 mm due to dynamic recrystallization, wherein a steady state grain size is maintained due to the balance of grain growth and destruction during flow. If the near-bed ice in the MPD is warmed close to its melting point and has been extensively sheared, grain sizes at its base may be between 10 and 40 mm, by analogy with warm, dirty, near-bed ice in terrestrial ice sheets.  相似文献   

Global travertine deposition modulated by oscillations in climate   总被引：1，自引：0，他引：1  

Jason W. Ricketts  Lin Ma  Amy E. Wagler  Victor H. Garcia 《第四纪科学杂志》2019,34(7):558-568

Travertine deposits are important records of past fluid flow in the Earth's crust, and document fluid migration through both tectonic activity and changes in climate. While many studies hint at possible relationships between travertine formation and global climate, none have investigated these connections on a global scale. Here we compile 1649 published travertine ages from six continents to test the hypothesis that global and/or regional changes in climate regulate travertine deposition. Peaks in bedded travertine ages occur with main frequencies that correspond to 100‐kyr changes in global climate, where most peaks occur during glacial terminations or interglacial periods, including a large peak that coincides with the Early Holocene climatic optimum. Time–series analysis also suggests a possible connection with 41‐kyr obliquity cycles. At regional scales, many peaks also correspond with local times of high precipitation or wet conditions. This can be attributed to higher groundwater recharge rates, providing the necessary water to form travertine. Many bedded travertine‐depositing systems may therefore be water‐limiting and sufficient CO₂ may be present even during times of no travertine deposition. Exceptions to this conclusion are banded vein travertine deposits, which typically form during times of dry climate when water tables are low. Copyright © 2019 John Wiley & Sons, Ltd.  相似文献   

Hydrogen fluence in Genesis collectors: Implications for acceleration of solar wind and for solar metallicity     

Gary R. Huss  Elizabeth Koeman‐Shields  Amy J. G. Jurewicz  Donald S. Burnett  Kazuhide Nagashima  Ryan Ogliore  Chad T. Olinger 《Meteoritics & planetary science》2020,55(2):326-351

NASA's Genesis mission was flown to capture samples of the solar wind and return them to the Earth for measurement. The purpose of the mission was to determine the chemical and isotopic composition of the Sun with significantly better precision than known before. Abundance data are now available for noble gases, magnesium, sodium, calcium, potassium, aluminum, chromium, iron, and other elements. Here, we report abundance data for hydrogen in four solar wind regimes collected by the Genesis mission (bulk solar wind, interstream low‐energy wind, coronal hole high‐energy wind, and coronal mass ejections). The mission was not designed to collect hydrogen, and in order to measure it, we had to overcome a variety of technical problems, as described herein. The relative hydrogen fluences among the four regimes should be accurate to better than ±5–6%, and the absolute fluences should be accurate to ±10%. We use the data to investigate elemental fractionations due to the first ionization potential during acceleration of the solar wind. We also use our data, combined with regime data for neon and argon, to estimate the solar neon and argon abundances, elements that cannot be measured spectroscopically in the solar photosphere.  相似文献   

Prograded coastal barriers provide paleoenvironmental records of storms and sea level during late Quaternary highstands          下载免费PDF全文

Amy J. Dougherty 《第四纪科学杂志》2018,33(5):501-517

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Verification of tropical cyclone deposits with oxygen isotope analyses of coeval ostracod valves     

Chad S. Lane  Brooklyn Hildebrandt  Lisa M. Kennedy  Allison LeBlanc  Kam-Biu Liu  Amy J. Wagner  Andrea D. Hawkes 《Journal of Paleolimnology》2017,57(3):245-255

Reconstruction of prehistoric tropical cyclone (TC) activity often relies on the identification of distinctive overwash deposits (tempestites) in coastal lagoon sediments. Similar sediment deposits, however, can result from high-energy events other than TCs. In this study we assessed the utility of using the geochemistry of ostracod valves, specifically their stable oxygen isotope composition (δ¹⁸O), as a potential validation variable that could reduce the chances of misidentifying an overwash deposit as having been generated by a TC, when in fact it formed from another high-energy depositional process (type 1 error). We applied this technique to a sediment core recovered from Laguna Alejandro, Dominican Republic, which had already been analyzed for other sedimentary TC proxies. Negative δ¹⁸O anomalies identified in the ostracod valve stable isotope record are associated with TC deposits and are most easily explained by large influxes of ¹⁸O-depleted meteoric waters typical of intense tropical storms. There is potential for this technique to be used to identify TC landfalls that are not represented by overwash deposits. We, however, propose a more conservative approach and suggest this technique be used to validate the origin of a storm deposit and reduce the odds of a type 1 error.  相似文献   

A regime shift in sediment export from a coastal watershed during a record wet winter,California: Implications for landscape response to hydroclimatic extremes          下载免费PDF全文

Amy E. East  Andrew W. Stevens  Andrew C. Ritchie  Patrick L. Barnard  Pamela Campbell‐Swarzenski  Brian D. Collins  Christopher H. Conaway 《地球表面变化过程与地形》2018,43(12):2562-2577

Small, steep watersheds are prolific sediment sources from which sediment flux is highly sensitive to climatic changes. Storm intensity and frequency are widely expected to increase during the 21st century, and so assessing the response of small, steep watersheds to extreme rainfall is essential to understanding landscape response to climate change. During record winter rainfall in 2016–2017, the San Lorenzo River, coastal California, had nine flow peaks representing 2–10‐year flood magnitudes. By the third flood, fluvial suspended sediment showed a regime shift to greater and coarser sediment supply, coincident with numerous landslides in the watershed. Even with no singular catastrophic flood, these flows exported more than half as much sediment as had a 100‐year flood 35 years earlier, substantially enlarging the nearshore delta. Annual sediment load in 2017 was an order of magnitude greater than during an average‐rainfall year, and 500‐fold greater than in a recent drought. These anomalous sediment inputs are critical to the coastal littoral system, delivering enough sediment, sometimes over only a few days, to maintain beaches for several years. Future projections of megadroughts punctuated by major atmospheric‐river storm activity suggest that interannual sediment‐yield variations will become more extreme than today in the western USA, with potential consequences for coastal management, ecosystems, and water‐storage capacity. The occurrence of two years with major sediment export over the past 35 years that were not associated with extremes of the El Niño Southern Oscillation or Pacific Decadal Oscillation suggests caution in interpreting climatic signals from marine sedimentary deposits derived from small, steep, coastal watersheds, to avoid misinterpreting the frequencies of those cycles. Published 2018. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   

Reply to ‘Wolf‐triggered trophic cascades and stream channel dynamics in Olympic National Park: a comment on East et al. (2017)’ by Robert Beschta and William Ripple          下载免费PDF全文

Amy E. East  Kurt J. Jenkins  Patricia J. Happe  Jennifer A. Bountry  Timothy J. Beechie  Mark C. Mastin  Joel B. Sankey  Timothy J. Randle 《地球表面变化过程与地形》2018,43(4):936-939

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Bayesian posterior predictive return levels for environmental extremes     

Lee?FawcettEmail author  Amy?C.?Green 《Stochastic Environmental Research and Risk Assessment (SERRA)》2018,32(8):2233-2252

A key aim of most extreme value analyses is the estimation of the r-year return level; the wind speed, or sea-surge, or rainfall level (for example), we might expect to see once (on average) every r years. There are compelling arguments for working within the Bayesian setting here, not least the natural extension to prediction via the posterior predictive distribution. Indeed, for practitioners the posterior predictive return level has been cited as perhaps the most useful point summary from a Bayesian analysis of extremes, and yet little is known of the properties of this statistic. In this paper, we attempt to assess the performance of predictive return levels relative to their estimative counterparts obtained directly from the return level posterior distribution; in particular, we make comparisons with the return level posterior mean, mode and 95% credible upper bound. Differences between the predictive return level and standard summaries from the return level posterior distribution, for wind speed extremes observed in the UK, motivates this work. A large scale simulation study then reveals the superiority of the predictive return level over the other posterior summaries in many cases of practical interest.  相似文献