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31.
Laeonereis acuta was seasonally collected in an industrially polluted site (P) and in an unpolluted site (UP) at the Patos Lagoon estuary (southern Brazil). Glutathione S-transferase (GST), superoxide dismutase (SOD) and catalase (CAT) activity (U/mg protein) was determined in five groups of worms from each site. Metallothionein (MT - mol GSH/g ww) and lipid peroxides content (LPO - nmoles of cumene hydroperoxide/g ww) were also measured. Annual mean values for CAT (UP=3.7+/-0.3; P=5.7+/-0.6), GST (UP=0.034+/-0.003; P=0.045+/-0.004) and MT (UP=0.15+/-0.02; P=0.23+/-0.03) were higher (p<0.05) in worms from the P site. In autumn, CAT activity was higher (p<0.05) in worms from the P site (7.6 +/- 1.3) than in those from the UP site (3.6 +/- 0.4). In summer, MT concentration was higher in worms from the P site (0.37 +/- 0.03) than in those from the UP site (0.19 +/- 0.01). No significant difference (p>0.05) in the LPO content was observed in worms from the different sites or collected in different seasons. These results indicate that worms from the polluted site showed higher antioxidant responses than those from the unpolluted site, sufficient to prevent oxidative damage in terms of LPO.  相似文献   
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Sediment grain size and organic carbon (OC) data collected over the past 50 years, together with δ13C values of OC in recently collected samples, were analyzed to improve understanding of sediment OC distribution and abundance in Todos Santos Bay. Sediments in the submarine canyon at the mouth of the bay and in quiet-water locations along the shore are fine grained, high in OC, and have generally low δ13C values; sediments in high-energy environments are low in OC and have high δ13C values. A bivariate isotopic mixing model indicates that none of the sediments contain >50% terrigenous OC (average ~30%), and that the terrigenous OC content of the sediments is a small proportion of the OC content of local soils. Sediment OC composition is apparently controlled by energy-related sorting and deposition, oxidation of much of the original terrigenous OC, and replacement of some terrigenous OC by marine OC.  相似文献   
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Seismic hazard analysis is based on data and models, which both are imprecise and uncertain. Especially the interpretation of historical information into earthquake parameters, e.g. earthquake size and location, yields ambiguous and imprecise data. Models based on probability distributions have been developed in order to quantify and represent these uncertainties. Nevertheless, the majority of the procedures applied in seismic hazard assessment do not take into account these uncertainties, nor do they show the variance of the results. Therefore, a procedure based on Bayesian statistics was developed to estimate return periods for different ground motion intensities (MSK scale).Bayesian techniques provide a mathematical model to estimate the distribution of random variables in presence of uncertainties. The developed method estimates the probability distribution of the number of occurrences in a Poisson process described by the parameter . The input data are the historical occurrences of intensities for a particular site, represented by a discrete probability distribution for each earthquake. The calculation of these historical occurrences requires a careful preparation of all input parameters, i.e. a modelling of their uncertainties. The obtained results show that the variance of the recurrence rate is smaller in regions with higher seismic activity than in less active regions. It can also be demonstrated that long return periods cannot be estimated with confidence, because the time period of observation is too short. This indicates that the long return periods obtained by seismic source methods only reflects the delineated seismic sources and the chosen earthquake size distribution law.  相似文献   
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Dust rain belongs to the climatological conditions of the Iberian Peninsula's Mediterranean seaboard. Traditionally known as muddy' or bloody rains, red dust rain has become a topical issue as a result of more frequent rainfall of this kind in recent years. In spite of the difficulties that studying this phenomenon involves, owing to the lack of systematically kept records at meteorological observatories, details are provided of the high frequency of such phenomena within the Spanish Mediterranean area, using records from other phenological sources. The study analyzes the chemical composition of red dust rain and the atmospheric factors giving rise to such phenomena. Whether there is a relationship betwen the higher frequency of dust rain and possible changes in global atmospheric circulation is as yet unclear.  相似文献   
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The present paper deals with the specification of bed erosion flux that accounts for the effects of sediment-induced stratification in the water column. Owing to difficulties in measuring the bed shear stress b and the erosive shear strength s, we suggest a series of methods that combine laboratory and numerical experiments. A simplified turbulent transport model that includes these effects helps to quantify b and s. Focusing on soft stratified beds, the present study considers erosion rate formulas of the form =f exp {[Tb-Ts]} where is a model constant (=1 for Gularte's (1978) formula and =1/2 for Parchure's (1984) formula). First, the bed erosive strength profile s(Z) is adjusted by forcing the turbulent transport model with measured erosion rates. Second, three procedures are suggested to determine the erosion rate formula coefficients f and : a global procedure and two different layer-by-layer procedures. Each procedure is applied to an erosion experiment conducted in a rotating annular flume by Villaret and Paulic (1986). The use of the layer-by-layer procedure based on a least squares fitting technique provides a closer fit than the global procedure. The present study points out the complementarity of experimental and numerical approaches and also suggests possible improvements in laboratory test procedures.  相似文献   
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The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO2, Fe2O3, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO2 (mainly anatase, nonporous, 50 m2 g–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm–2 h–1 (>340 nm, radiant fluxca. 22 mW cm–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O2. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO2, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe2O3. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO2. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed.  相似文献   
40.
In this paper analytical expressions are derived for the temporal variations ofJ 2 andJ 22 due to the tides of the solid Earth, taking into account only the deformation of the mantle, and employing a procedure already used by the authors in their Hamiltonian theory of the Earth's rotation, which obtain the necessary parameters in a direct way by integration of those provided by a selected model of Earth interior.Numerical tables giving the periodic variation of coefficients are given, as well as a new prediction for UT1. For J 2 and J 22 the amplitudes reach such a magnitude that both two variations should not be ignored in studies involving the analysis of highly precise satellite tracking data. Moreover, the possibility of improving our knowledge of the value of those harmonic coefficients in only a more exact digit appears as to be strongly dependent on the limitations in the theoretical modeling of the variations of the inertia tensor due to solid tides.  相似文献   
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