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181.
182.
Natalia?StammEmail authorView authors OrcID profile Max?W.?Schmidt Dawid?Szymanowski Albrecht?von?Quadt Thabang?Mohapi Andre?Fourie 《Contributions to Mineralogy and Petrology》2018,173(9):76
The Let?eng-la-Terae kimberlite (Lesotho), famous for its large high-value diamonds, has five distinct phases that are mined in a Main and a Satellite pipe. These diatreme phases are heavily altered but parts of a directly adjacent kimberlite blow are exceptionally fresh. The blow groundmass consists of preserved primary olivine with Fo86?88, chromite, magnesio-ulvöspinel and magnetite, perovskite, monticellite, occasional Sr-rich carbonate, phlogopite, apatite, calcite and serpentine. The bulk composition of the groundmass, extracted by micro-drilling, yields 24–26 wt% SiO2, 20–21 wt% MgO, 16–19 wt% CaO and 1.9–2.1 wt% K2O, the latter being retained in phlogopite. Without a proper mineral host, groundmass Na2O is only 0.09–0.16 wt%. However, Na-rich K-richterite observed in orthopyroxene coronae allows to reconstruct a parent melt Na2O content of 3.5–5 wt%, an amount similar to that of highly undersaturated primitive ocean island basanites. The groundmass contains 10–12 wt% CO2, H2O is estimated to 4–5 wt%, but volatiles and alkalis were considerably reduced by degassing. Mg# of 77.9 and 530 ppm Ni are in equilibrium with olivine phenocrysts, characterize the parent melt and are not due to olivine fractionation. 87Sr/86Sr(i)?=?0.703602–0.703656, 143Nd/144Nd(i)?=?0.512660 and 176Hf/177Hf(i)?=?0.282677–0.282679 indicate that the Let?eng kimberlite originates from the convective upper mantle. U–Pb dating of groundmass perovskite reveals an emplacement age of 85.5?±?0.3 (2σ) Ma, which is significantly younger than previously proposed for the Let?eng kimberlite. 相似文献
183.
Recharge,geochemical processes and water quality in karst aquifers: Central West Bank,Palestine 总被引:1,自引:0,他引:1
Hassan Jebreen Stefan Wohnlich Andre Banning Frank Wisotzky Andrea Niedermayr Marwan Ghanem 《Environmental Earth Sciences》2018,77(6):261
The Central West Bank aquifer (CWB) is one of the most important resources of fresh groundwater of Palestine. The geology of the area consists mainly of karstic and permeable limestones and dolomites interbedded with argillaceous beds of late Albian–Turonian age. Exploitation of the CWB aquifer, combined with lack of information required to understand the groundwater pattern, represents a challenge for reservoir management. The present work reports hydrogeochemistry, microbiology and environmental isotope data from spring water samples, which were utilized to understand recharge mechanisms, geochemical evolution and renewability of groundwater in CWB aquifer. Besides the major chemical compositions, ionic ratios were used to delineate mineral-solution reactions and weathering processes. Interpretation of chemical data suggests that the chemical evolution of groundwater is primarily controlled by (1) water–rock interactions, involving dissolution of carbonate minerals (calcite and dolomite), and (2) cation exchange processes. The measured equation of the local meteoric water line is δD?=?5.8 δ18O?+?9.9. Stable isotopes show that precipitation is the source of recharge to the groundwater system. The evaporation line has a linear increasing trend from south to north direction in the study area. All analyzed spring waters are suitable for irrigation, but not for drinking purposes. The results from this study can serve as a basis for decision-makers and stakeholders, with the intention to increase the understanding of sustainable management of the CWBs. 相似文献
184.
Uranium and As in deep groundwater of the volcano-sedimentary Villa de Reyes Graben around the city of San Luis Potosí in semi-arid North-Central Mexico (mean U: 7.6 μg L−1, max. 138 μg L−1; mean As: 11.4 μg L−1, max. 25.8 μg L−1) partly exhibit concentrations in excess of the WHO guideline values and thus endanger the quality of the most important drinking water source. To unravel the mechanisms for their enrichment in groundwater, the potential trace element sources, volcanic rocks and basin fill sediments, were characterized. A total of 131 solid and liquid samples were analyzed for major and trace element composition. The As/U hydrogeochemical signatures, their behavior during rock alteration and evidence from other major and trace element distributions, especially rare earth elements, strongly argue for dissolution of acid volcanic glass to be the dominating process of U and As release into groundwater. This natural baseline quality representing water–acid volcanic rock interaction is modified by additional trace element (preferentially As) mobilization from the sedimentary basin fill, representing a secondary source, in the course of decarbonatization of playa lake sediments and desorption from Fe-(hydr)oxide coated clastic material. The common behavior of both elements during magmatic differentiation and growing drift apart in sedimentary environments are important findings of this work. Comparison with recent findings in a similar environment suggests a common primary trace element source identification but significant differences in the evolution of As and U distribution. Geological and climatic similarity to numerous volcano-sedimentary basins makes the findings useful for water management purposes and transferable to other semi-arid regions facing challenges of geogenically impacted drinking water quality. 相似文献
185.
Geochemistry and Cr stable isotopes of Cr-contaminated groundwater in León valley,Guanajuato, México
Alejandro Villalobos-Aragón Andre S. Ellis María A. Armienta Ofelia Morton-Bermea Thomas M. Johnson 《Applied Geochemistry》2012
León valley, located in the Mexican state of Guanajuato, has a long history (35+ a) of Cr contamination of groundwater and surface water. Here data are presented for Cr, major ion and trace element concentrations and Cr stable isotope measurements of groundwater in a heavily contaminated aquifer in Buenavista, where Cr ore processing residue piles (COPRPs) located in a chromate production factory are the main source of Cr. The aquifer directly beneath the factory still retains very high Cr(VI) concentrations (∼121 mg/L). Ongoing pump and treat remediation is keeping the high concentration plume confined to the factory area and immediate vicinity, though Cr is also detected at some distance away. Chromium isotope data of the aquifer directly under the factory show only a small increase in δ53Cr (+0.33‰ to +0.81‰) and indicates minimal reduction of Cr(VI) to Cr(III). Very high Cr(VI) concentrations have possibly overwhelmed natural reductants and furthermore fresh Cr(VI) was being leached into the groundwater from the COPRP. From just one year of Cr isotope data it is clear that more aggressive remediation techniques will be necessary to reduce or eliminate the contamination. The fringes of the Cr plume have substantially lower concentrations and can be partially explained by transport of the main plume or mixing between waters from the nearby landfill and highly contaminated waters from QC. While the source of Cr at the fringes of the plume could be attributed to a source from the nearby landfill instead of the main plume from the factory, the Cr stable isotope data show enrichment in the heavier isotopes and point to varying amounts of reduction. Isotopic enrichment seen between 2007 and 2008 along the fringe may indicate either reduction or less unreacted Cr(VI) is being transported to the fringes. In either case some potential for natural attenuation of Cr(VI) exists at the western margin of the plume with the landfill playing a role. 相似文献
186.
Cleivison Souza de Jesus Andre Luis Batista Ribeiro Christine Cordula Dantas 《Astronomische Nachrichten》2024,345(1):e220081
In this work, we study how to improve well-known techniques for detecting progenitors/descendants of galaxies, such as the NDpredict program, when applied to galaxies in clusters. The improvement of this particular method is based on the use of the red sequence of galaxies in those environments. Objects close to the red sequence in the color and magnitude diagram are more likely to belong to the cluster. This defines a probability scale which is then combined with the one generated by NDpredict. This procedure is optimized for the study of galaxies in clusters over different epochs. Our main result is that, for a sample composed of clusters, with masses greater than , selected from the IllustrisTNG simulations (namely, the TNG100 runs). In of the cases (i.e., systems), we obtain better performance with the red sequence method in comparison to the original NDpredict, and the average gain obtained is in the identification of descendants for this sample of cluster galaxies. 相似文献