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21.
The transport mechanisms of As from contaminated soil or irrigation water into roots and subsequently into grain, and the As species distribution—a toxicity determinant, is critical for assessing health risks imposed by As. However, the commonly-employed extraction of plant material with trifluoroacetic acid (TFA) has not proven successful in preserving inorganic As species. Synchrotron-based spectroscopic techniques are useful for discerning elemental distributions and chemical speciation of elements in situ. Here, we both characterize the mineral phases of Fe coatings on rice roots, and quantify plant nutrients and As species in situ on roots and grain samples. Arsenic in rice grains was present in bran layers as oxidized As (69-88% as As(V)i and 12-31% as DMA) and in the germ as a mixture of As(V)i and As(III)i, but was non-detected from the endosperm, which is consistent with previous findings. The extent of Fe coatings on rice roots was variable and, when present, consisted of lepidocrocite (γ-FeOOH), goethite (α-FeOOH) and ferrihydrite (Fe(OH)3·nH2O). Arsenic was co-located with root Fe coatings, but our findings indicate that Fe is not a direct interceptor of As uptake, and is rather a bulk scavenger mostly near the air-water interface. On whole root mounts with Fe plaque, arsenic was present as mixed species of As(V)i (44-66%) and As(III)i (34-56%). Within a root cross-section, oxidized As species were dominant in the xylem (86% as As(V)i and 14% as DMA) whereas mostly reduced species (71% as As(III)i, 29% as AsGlu3) resided within a vacuole adjacent to the xylem. This finding contrasts the prevailing view that As(V)i is rapidly reduced in roots and transported to shoots as As(III)i, and points to the importance of interspecies differences in As-uptake dynamics.  相似文献   
22.
Geochemical, mineralogical and biological indicators preserved in sediments are widely used to reconstruct past climate change, but proxies differ in the degree to which their utility as climate indicators has been validated via laboratory experiments, modern spatial calibrations, or down‐core comparisons with instrumental climate data. Multi‐proxy studies provide another means of evaluating interpretations of proxies. This paper presents a multi‐proxy assessment comparing 19 sub‐centennially resolved late Holocene proxy records, covering the period 300–1900 AD, from seven Icelandic marine and lacustrine core sites. We employ simple statistical comparisons between proxy reconstructions to evaluate their correlations over time and, ultimately, their utility as proxies for regional climate. Proxies examined include oxygen isotopic composition of benthic and planktonic foraminifera, abundance of the sea‐ice biomarker IP25, allochthonous quartz in marine sediments (a proxy for drift ice around Iceland), marine carbonate abundance, total organic carbon concentration, chironomid assemblages, lacustrine biogenic silica and carbon/nitrogen ratios in lake sediments. Most of the examined proxy records, including temperature and sea‐ice proxies, correlate strongly with each other over multi‐centennial timescales, and thus do appear to record changes in regional climate. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
23.
In November 2010, students from a Palmerston North intermediate school embarked on a 2‐week excursion to India. Qualitative research was carried out before, during and after the trip. Results discussed in this article focus primarily on the students' account of their trip, especially their perceived cultural competence and their explanation for it. Accounts of their competence are also offered by the parents and teachers, for example, they especially valued the students' extensive school‐based preparation. Insights gained from the experiences of this trip may be applied to other, including older, cohorts of students embarking on overseas school field trips.  相似文献   
24.
We reconstruct palaeoclimate and palaeoceanography of the Ísafjarðardjúp fjord system from two cores – one from the inner fjord and one near the fjord mouth – while separating the potential overprinting of relative sea‐level (RSL) and local fjord hydrographic changes on these records. The inner fjord core (B997‐339) reflects local fjord hydrography; the outer fjord core (MD99‐2266) reflects the regional oceanic signal. Glacial marine conditions ended at ca. 10 200 cal. a BP, indicated by both ice‐rafted debris records. The other proxy records show spatial and temporal variability within the fjord system. At the inner fjord site (B997‐339) foraminiferal assemblages and the δ18O record indicate lowered RSL between ca. 10 600 and 8900 cal. a BP and document the onset of fjord water overturning at ca. 8900 cal. a BP, which obscured the climate record. At the fjord mouth (MD99‐2266) mass accumulation rates suggest lowered RSL between ca. 10 200 and 5500 cal. a BP and local freshwater and/or reduced salinities of the Irminger Current water masses affected the δ18O signal between ca. 10 200 and 7900 cal. a BP. At MD99‐2266, foraminiferal fauna record the Holocene Thermal Maximum between ca. 8000 and 5700 cal. a BP and the onset of modern oceanic circulation at ca. 7000 cal. a BP. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
25.
We present a detailed review of the calibration of the LASCO C3 coronagraph on the SOHO satellite. Most of the calibration has been in place since early in the mission and has been utilized to varying degrees as required by specific analysis efforts. However, using observational data from the nearly decade-long database of LASCO images, we have re-evaluated and improved many aspects of the calibration. This includes the photometric calibration, vignetting function, geometric distortion, stray light, and exposure and observation times. Using this comprehensive set of corrections we have generated and made available a set of calibrated coronal images along with a set of periodic background images to ease the accessibility and use of the LASCO database. Deceased  相似文献   
26.
27.
Andrews  M.D. 《Solar physics》2001,204(1-2):179-196
The period of 10–14 July 2000 saw a large number of energetic solar events ending with a very energetic flare that was associated with a large solar energetic particle event and a fast halo coronal mass ejection (CME) that produced the largest geomagnetic disturbance since 1989. This paper tries to summarize the complex coronal activity observed during this period, in order to establish a background for a number of papers in this topical issue. The GOES X-ray data are presented. Data animations of observations from EIT and LASCO C2 and C3 are presented on the accompanying CD-ROM. The observations around the time of the three X-class flares are considered. EIT observations of the Bastille Day flare show coronal brightening followed by dimming. LASCO had good data coverage for all three events. For one of the flares, no coronal response was seen. The other two flares are associated with halo CMEs. The timing suggests that the start of the flares and CMEs are simultaneous to approximately 30 min. Analysis of the LASCO and EIT images following the Bastille Day flare show the arrival of energetic particles at SOHO at approximately 10:41 UT on 14 July. Individual features of these CMEs have been tracked and the height–time plots used to estimate the dynamics of the CMEs. The initial speed and deceleration of the halo CMEs estimated from the fitting of height–time plots are compared with the in-situ observations at L1. The three flares are identified as the solar sources of three shocks observed at 1 AU. Finally, it is stressed that global heliospheric effects during periods of exceptional activity should consider a cumulative scenario rather than events in isolation.  相似文献   
28.
A useful index of the status of women should be mappable, in order to allow global and regional comparisons. Ideally, such an index should include political, economic, and social components. In actuality, data that measure political and economic equality are available only in Western societies. An index that measures the general well-being of women, however, can be mapped and used crossculturally. An index is proposed that includes indicators from the areas of health, education and fertility.  相似文献   
29.
Wave-like features in range seen on the range/time/intensity (RTI) records of VHF backscatter radars operating in the South of New Zealand are interpreted as being the signature of gravity waves propagating in an ionospheric sporadic-E layer. The data show that, during midsummer in particular, sporadic-E ionisation which has been modified by the passage of a gravity wave can produce two distinct echo types : backscatter from field-aligned irregularities within the sporadic-E layer, probably generated by plasma waves, and a second type of echo resulting from energy backscattered from the surface of the sea after specular reflection in the ionosphere. The backscattering and reflecting region can exist at latitudes at least as low as 49° geographic (57° geomagnetic) latitude during quiet magnetic conditions. We confirm the patchiness of dense sporadic-E, and conclude that gravity waves at sporadic-E heights have amplitudes of the order of several tenths of a kilometre.  相似文献   
30.
A rigorous solution is developed from first principles to guide the preliminary design of cutoff walls installed to contain the migration of contaminants from source zones. The full analytic solution is used to develop a criterion for determining the configuration and hydraulics of optimal wall designs. The solution is used to demonstrate the interaction between the properties of the wall, the Darcy flux, and the concentration of contaminants at the outside face of the well. For a particular wall design, the containment criterion can be used to estimate the long-term concentration that will develop at the outside face of the wall. Alternatively, for a given concentration on the outside face of the cutoff wall, the containment criterion can be used to estimate the Darcy flux required to balance the outward diffusion of contaminants. The results of numerical simulations are presented to evaluate the analytic approach. The numerical results confirm that for a wall with known transport properties, a specified Darcy flux is associated with a unique outside contaminant concentration.  相似文献   
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