Root‐related rhodochrosite and concretionary siderite formation in oxygen‐deficient conditions induced by a ground‐water table rise          下载免费PDF全文

Maciej J. Bojanowski  Elżbieta Jaroszewicz  Adrijan Košir  Maciej Łoziński  Leszek Marynowski  Anna Wysocka  Arkadiusz Derkowski 《Sedimentology》2016,63(3):523-551

Sedimentological, mineralogical, stable carbon and oxygen isotope determinations and biomarker analyses were performed on siderite concretions occurring in terrestrial silts to understand their formation and to characterize the sedimentary and diagenetic conditions favouring their growth. High δ¹³C values (6·4‰ on average) indicate that siderite precipitated in an anoxic environment where bacterial methanogenesis operated. The development of anoxic conditions during shallow burial was induced by a change in sedimentary environment from flood plain to swamp, related to a rise of the ground‐water table. Large amounts of decaying plant debris led to efficient oxygen consumption within the pore‐water in the peat. Oxygen depletion, in combination with a decrease in sedimentation rate, promoted anoxic diagenetic conditions under the swamp and favoured abundant siderite precipitation. This shows how a change in sedimentary conditions can have a profound impact on the early‐diagenetic environment and carbonate authigenesis. The concretions contain numerous rhizoliths; they are cemented with calcium‐rhodochrosite, a feature which has not been reported before. The rhodochrosite cement has negative δ¹³C values (?16·5‰ on average) and precipitated in suboxic conditions due to microbial degradation of roots coupled to manganese reduction. The exceptional preservation of the epidermis/exodermis and xylem vessels of former root tissues indicates that the rhodochrosite formed shortly after the death of a root in water‐logged sediments. Rhodochrosite precipitated during the initial stages of concretionary growth in suboxic microenvironments within roots, while siderite cementation occurred simultaneously around them in anoxic conditions. These suboxic microenvironments developed because oxygen was transported from the overlying oxygenated soil into sediments saturated with anoxic water via roots acting as permeable conduits. This model explains how separate generations of carbonate cements having different mineralogy and isotopic compositions, which would conventionally be regarded as cements precipitated sequentially in different diagenetic zones during gradual burial, can form simultaneously in shallow burial settings where strong redox gradients exist around vertically oriented permeable root structures.  相似文献   

Late‐glacial to Holocene depositional architecture of the Ombrone palaeovalley system (Southern Tuscany,Italy): Sea‐level,climate and local control in valley‐fill variability          下载免费PDF全文

Anna Breda  Alessandro Amorosi  Veronica Rossi  Fabio Fusco 《Sedimentology》2016,63(5):1124-1148

The Ombrone palaeovalley was incised during the last glacial sea‐level fall and was infilled during the subsequent Late‐glacial to Holocene transgression. A detailed sedimentological and stratigraphic study of two cores along the palaeovalley axis led to reconstruction of the post‐Last Glacial Maximum valley‐fill history. Stratigraphic correlations show remarkable similarity in the Late‐glacial to early‐Holocene succession, but discrepancy in the Holocene portion of the valley fill. Above the palaeovalley floor, about 60 m below sea‐level, Late‐glacial sedimentation is recorded by an unusually thick alluvial succession dated back to ca 18 cal kyr bp . The Holocene onset was followed by the retrogradational shift from alluvial to coastal facies. In seaward core OM1, the transition from inner to outer estuarine environments marks the maximum deepening of the system. By comparison, in landward core OM2, the emplacement of estuarine conditions was interrupted by renewed continental sedimentation. Swamp to lacustrine facies, stratigraphically equivalent to the fully estuarine facies of core OM1, represent the proximal expression of the maximum flooding zone. This succession reflects location in a confined segment of the valley, just landward of the confluence with a tributary valley. It is likely that sudden sediment input from the tributary produced a topographic threshold, damming the main valley course and isolating its landward segment from the sea. The seaward portion of the Ombrone palaeovalley presents the typical estuarine backfilling succession of allogenically controlled incised valleys. In contrast, in the landward portion of the system, local dynamics completely overwhelmed the sea‐level signal, following marine ingression. This study highlights the complexity of palaeovalley systems, where local morphologies, changes in catchment areas, drainage systems and tributary valleys may produce facies patterns significantly different from the general stratigraphic organization depicted by traditional sequence‐stratigraphic models.  相似文献   

In situ high-temperature X-ray diffraction and spectroscopic study of fibroferrite,FeOH(SO<Subscript>4</Subscript>)·5H<Subscript>2</Subscript>O     

Gennaro Ventruti  Giancarlo Della Ventura  Nicola Corriero  Daniele Malferrari  Alessandro F. Gualtieri  Umberto Susta  Maria Lacalamita  Emanuela Schingaro 《Physics and Chemistry of Minerals》2016,43(8):587-595

The thermal dehydration process of fibroferrite, FeOH(SO₄)·5H₂O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO₄)·4H₂O, appearing at about 80 °C due to release of one interstitial H₂O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.  相似文献   

Some Open Issues on Rockfall Hazard Analysis in Fractured Rock Mass: Problems and Prospects     

Anna Maria Ferrero  Maria Rita Migliazza  Marina Pirulli  Gessica Umili 《Rock Mechanics and Rock Engineering》2016,49(9):3615-3629

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Modeling of Shales in Salt-Hydrocarbon Systems     

Maria A. Nikolinakou  Peter B. Flemings  Michael R. Hudec 《Rock Mechanics and Rock Engineering》2016,49(2):699-705

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Analysis of extreme rainfall in the Ebre Observatory (Spain)     

Núria Pérez-Zanón  M. Carmen Casas-Castillo  Raúl Rodríguez-Solà  Juan Carlos Peña  Anna Rius  J. Germán Solé  Ángel Redaño 《Theoretical and Applied Climatology》2016,124(3-4):935-944

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Situational Adaptation of Spatial Data in On-Board Geographic Information Systems     

Vladislav Alexandrovich Androsov  Konstantin Vadimovich Malynkin  Dmitry Vladimirovich Sukhomlinov  Anna Nikolaevna Tikhomirova 《Journal of the Indian Society of Remote Sensing》2016,44(3):427-433

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Compromise not consensus: designing a participatory process for landslide risk mitigation     

Anna Scolobig  Michael Thompson  JoAnne Linnerooth-Bayer 《Natural Hazards》2016,81(1):45-68

With the escalating costs of landslides, the challenge for local authorities is to develop institutional arrangements for landslide risk management that are viewed as efficient, feasible and fair by those affected. For this purpose, the participation of stakeholders in the decision-making process is mandated by the European Union as a way of improving its perceived legitimacy and transparency. This paper reports on an analytical-deliberative process for selecting landslide risk mitigation measures in the town of Nocera Inferiore in southern Italy. The process was structured as a series of meetings with a group of selected residents and several parallel activities open to the public. The preparatory work included a literature/media review, semi-structured interviews carried out with key local stakeholders and a survey eliciting residents’ views on landslide risk management. The main point of departure in the design of this process was the explicit elicitation and structuring of multiple worldviews (or perspectives) among the participants with respect to the nature of the problem and its solution. Rather than eliciting preferences using decision analytical methods (e.g. utility theory or multi-criteria evaluation), this process built on a body of research—based on the theory of plural rationality—that has teased out the limited number of contending and socially constructed definitions of problem-and-solution that are able to achieve viability. This framing proved effective in structuring participants’ views and arriving at a compromise recommendation (not, as is often aimed for, a consensus) on measures for reducing landslide risk. Experts played a unique role in this process by providing a range of policy options that corresponded to the different perspectives held by the participants.  相似文献   

Life after death: shallow‐water Mediterranean invertebrate communities associated with mammal bones          下载免费PDF全文

Sergi Taboada  Maria Bas  Carlos Leiva  Mariona Garriga  Rafael Sardá  Conxita Avila 《Marine Ecology》2016,37(1):164-178

Invertebrate and microbial marine communities associated with mammal bones are interesting and poorly understood habitats, mainly known from studies on deep‐water whale remains. In order to characterize these communities in the shallow‐water Mediterranean, we present here the results of a pioneering experiment using mammal bones. Minke whale, pig and cow bones were experimentally deployed on three different background communities: rocky substrate, soft‐bottom and a Posidonia oceanica meadow. Bones were deployed for a year at about 20 m depth and collected every 3 months, and the invertebrate fauna colonizing the bones was identified to the lowest possible taxonomic level. As expected, mammal bones showed remarkable differences when compared with background communities. Within bones, four different clusters could be identified, primarily on the basis of the polychaete fauna, the most abundant and diverse group in the survey. Clusters A1–A3 corresponded to high to moderately altered successional stages composed by a fauna closer to that of anthropogenically enriched shallow‐water environments. These clusters were characterized by the occurrence of the opportunist polychaetes Ophryotrocha puerilis, Neanthes caudata (Cluster A1), Protodorvillea kefersteini (Cluster A2) and Ophryotrocha alborana (Cluster A3). Cluster B was characterized by the presence of the polychaete Oxydromus pallidus together with typical invertebrate background fauna, which suggests that this community, after a year of deployment, was closer to that found in natural conditions. As opposed to similar shallow‐water studies in other geographic areas, no occurrence of the polychaete Osedax (commonly known as bone‐eating worms) was reported from our experiments. Apart from the study on the invertebrate communities, insights about the population dynamics of three of the most abundant species (O. puerilis, O. alborana, N. caudata) are given as well as remarks on a hypothetical trophic network based on fecal pellet analysis.  相似文献   

The influence of physical and biological processes on the ichthyoplankton communities in the Gulf of Sirte (Southern Mediterranean Sea)          下载免费PDF全文

Angela Cuttitta  Sergio Bonomo  Salem Zgozi  Angelo Bonanno  Bernardo Patti  Enza Maria Quinci  Marco Torri  Mohamed Hamza  Abdul Fatah  Daw Haddoud  Akram El Turki  Abdul Bari Ramadan  Simona Genovese  Salvatore Mazzola 《Marine Ecology》2016,37(4):831-844

This paper reports on the first study on the ichthyoplankton community structure in the Gulf of Sirte and its spatial distribution in relation to environmental conditions and zooplankton abundance. The results make an important contribution to the future management of fisheries in this unexplored, but much exploited, area. Biological samples were collected in July 2008 using a Bongo40 net. In total, 1914 larvae were found and 1652 of these were identified. In particular, bathypelagic taxa were the most abundant, followed by demersal, mesopelagic, pelagic and epipelagic taxa. The ichthyoplankton community had a patchwork distribution influenced by oligotrophic conditions, the bottom depth and oceanographical features. The results suggest that environmental forcings were able to transport the ichthyoplankton to productive areas. Indeed, maximum fish egg densities were found in coastal stations in correspondence with the Atlantic Tunisian Current inflow, whereas larvae were mainly concentrated in the east side of the Gulf, probably as a result of advection by the anticyclonic circulation. Additionally, the distribution patterns of the total larvae density and the different assemblages were well matched with the abundance of the zooplankton, probably determining final larval survival, growth and recruitment.  相似文献