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51.
Laboratory powder XRD patterns of the perovskite-group mineral lueshite from the type locality (Lueshe, Kivu, DRC) and pure NaNbO3 demonstrate that lueshite does not adopt the same space group (Pbma; #57) as the synthetic compound. The crystal structures of lueshite (2 samples) from Lueshe, Mont Saint-Hilaire (Quebec, Canada) and Sallanlatvi (Kola, Russia) have been determined by single-crystal CCD X-ray diffraction. These room temperature X-ray data for all single-crystal samples can be satisfactorily refined in the orthorhombic space group Pbnm (#62). Cell dimensions, atomic coordinates of the atoms, bond lengths and octahedron tilt angles are given for four crystals. Conventional neutron diffraction patterns for Lueshe lueshite recorded over the temperature range 11–1,000 K confirm that lueshite does not adopt space group Pbma within these temperatures. Neutron diffraction indicates no phase changes on cooling from room temperature to 11 K. None of these neutron diffraction data give satisfactorily refinements but suggest that this is the space group Pbnm. Time-of-flight neutron diffraction patterns for Lueshe lueshite recorded from room temperature to 700 °C demonstrate phase transitions above 550 °C from Cmcm through P4/mbm to \(Pm\overline{3} m\) above 650 °C. Cell dimensions and atomic coordinates of the atoms are given for the three high-temperature phases. The room temperature to 400 °C structures cannot be satisfactorily resolved, and it is suggested that the lueshite at room temperature consists of domains of pinned metastable phases with orthorhombic and/or monoclinic structures. However, the sequence of high-temperature phase transitions observed is similar to those determined for synthetic NaTaO3, suggesting that the equilibrated room temperature structure of lueshite is orthorhombic Pbnm.  相似文献   
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This study investigated contributory factors to flood hazard around Scotland. There is a need to develop preliminary assessments of areas potentially vulnerable to flooding for compliance with the European Union Directive on the Assessment and Management of Flood Risks (2007/60/EC). Historical accounts of coastal flood events in Scotland, notably in a storm in January 2005, had shown that estimates of risk based on still water levels required further information to identify sites at which waves and surges could combine. Additionally, it was important to add the effect of future sea-level rise and other drivers from published sources. Analysis of multiple years’ tidal data at seven sites, including estuaries, compared recorded water levels at high-return periods to those derived from a spatially interpolated numerical model contained within a publicly available flood risk map. For gauges with the longest records, increases were seen over time that reflected rises in mean sea level. Exposure to wave energy was computed from prevailing wind strength and direction at 36 stations, related to wave fetch and incident wind direction. Although the highest wave exposure was at open coast locations exposed to the long Atlantic fetch, GIS analysis of coastal rasters identified other areas in or close to estuaries that also had high exposure. Projected sea-level change, when added to the surge and wave analyses, gives a spatially extensive structured variable flood risk assessment for future coastal flood hazard to complement the public flood risk map. Such tools can help fulfil the requirements of the EC Directive and may be a useful approach in other regions with high spatial variability in coastal flood risk related to exposure to waves and wind.  相似文献   
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Over the last years, geospatial web platforms, social media, and volunteered geographic information (VGI) have opened a window of opportunity for traditional Public Participatory GIS (PPGIS) to usher in a new era. Taking advantage of these technological achievements, this paper presents a new approach for a citizen-orientated framework of spatial planning that aims at integrating participatory community work into existing decision-making structures. One major cornerstone of the presented approach is the application of a social geoweb platform (the GeoCitizen platform) that combines geo-web technologies and social media in one single tool allowing citizens to collaboratively report observations, discuss ideas, solve, and monitor problems in their living environment at a local level. This paper gives an account of an ongoing participatory land-zoning process in the Capital District of Quito, Ecuador, where the GeoCitizen platform is applied in a long-term study.  相似文献   
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The popularization of tracking devices, such as GPS, accelerometers and smartphones, have made it possible to detect, record, and analyze new patterns of human movement and behavior. However, employing GPS alone for indoor localization is not always possible due to the system's inability to determine location inside buildings or in places of signal occlusion. In this context, the application of local wireless networks for determining position is a promising alternative solution, although they still suffer from a number of limitations due to energy and IT‐resources. Our research outlines the potential for employing indoor wireless network positioning and sensor‐based systems to improve the collection of tracking data indoors. By applying various methods of GIScience we developed a methodology that can be applicable for diverse human indoor mobility analysis. To show the advantage of the proposed method, we present the result of an experiment that included mobility analysis of 37 participants. We tracked their movements on a university campus over the course of 41 days and demonstrated that their movement behavior can be successfully studied with our proposed method.  相似文献   
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Seismic scattering and shallow structure of the moon in oceanus procellarum   总被引:1,自引:0,他引:1  
Long, reverberating trains of seismic waves produced by impacts and moonquakes may be interpreted in terms of scattering in a surface layer overlying a non-scattering elastic medium. Model seismic experiments are used to qualitatively demonstrate the correctness of the interpretation. Three types of seismograms are found, near impact, far impact and moonquake. Only near impact and moonquake seismograms contain independent information. Details are given in the paper of the modelling of the scattering processes by the theory of diffusion.Interpretation of moonquake and artificial impact seismograms in two frequency bands from the Apollo 12 site indicates that the scattering layer is 25 km thick, with a Q of 5000. The mean distance between scatterers is approximately 5 km at 25 km depth and approximately 2 km at 14 km depth; the density of scatterers appears to be high near the surface, decreasing with depth. This may indicate that the scatterers are associated with cratering, or are cracks that anneal with depth. Most of the scattered energy is in the form of scattered surface waves.Communication presented at the Lunar Science Institute Conference on Geophysical and Geochemical Exploration of the Moon and Planets, January 10–12, 1973.  相似文献   
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This paper addresses global oxygenation and establishment of a marine sulphate reservoir in the Palaeoproterozoic. We report syn-depositional, marine, anhydrite-containing pseudomorphs after Ca-sulphates as widespread throughout the Tulomozero Formation in the SE Fennoscandian Shield, implying that surface waters were oxidized and a large SO marine reservoir was developed as early as 2100 Ma. The Ca-sulphates and associated magnesite and halite precipitated syn-depositionally from oxidized, evolved and modified seawater in coastal playa, sabkha and intertidal flat settings. 87Sr/86Sr and δ13C of associated 13C-rich stromatolitic dolostones were environmentally controlled with the highest ratios occurring in playa and sabkha carbonates. The results imply that the Palaeoproterozoic δ13Ccarb excursion was amplified by 8‰ by local environmental factors and calls into question many observations of putative δ13C global signals reported previously from similar Palaeoproterozoic, evaporitic, dolostones. The local environmental amplification can explain a large regional and intercontinental δ13C discrepancy observed in synchronous carbonates.  相似文献   
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