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Sarata K. Sahoo Masahiro Hosoda Ganesh Prasad Hiroyuki Takahashi Atsuyuki Sorimachi Tetsuo Ishikawa Shinji Tokonami Shigeo Uchida 《Acta Geophysica》2013,61(4):876-885
The activity concentrations of 226Ra and 228Ac in weathered Japanese soils from two selected prefectures have been measured using a γ-ray spectroscopy system with high purity germanium detector. The uranium, thorium, and rare earth elements (REEs) concentrations were determined from the same soil samples using inductively coupled plasma mass spectrometry (ICP-MS). For example, granitic rocks contain higher amounts of U, Th, and light REEs compared to other igneous rocks such as basalt and andesites. Therefore, it is necessary to understand the interaction between REEs and nature of soils since soils are complex heterogeneous mixture of organic and inorganic solids, water, and gases. In this paper, we will discuss about distribution pattern of 238U and 232Th along with REEs in soil samples of weathered acid rock (granite) collected from two prefectures of Japan: Hiroshima and Miyagi. 相似文献
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In the real world, there are many kinds of phenomena that are represented by points on a network, such as traffic accidents
on a street network. To analyse these phenomena, the basic point pattern methods (i.e. the nearest neighbour distance method,
the quadrat method, the K-function method and the clumping method) defined on a plane (referred to as the planar basic point pattern methods) are extended to the basic point pattern methods on a network (referred to as the network basic point pattern methods). However, like the planar basic point pattern methods, the network basic point pattern methods assume a uniform network
and this assumption is hard to accept when analysing actual phenomena. To overcome this limitation, this paper formulates
a transformation, called the uniform network transformation, that transforms a non-uniform network into a uniform network. This transformation provides a simple procedure for analysing
point patterns on non-uniform networks: first, a given non-uniform network is transformed into a uniform network; second,
the network basic point pattern methods (which assume a uniform network) are applied to this transformed uniform network.
No modification to the network basic point pattern methods is necessary. The paper also shows an actual application of this
transformation to traffic accidents in Chosei, Japan. 相似文献
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Atsuyuki Ohta Noboru Imai Shigeru Terashima Yoshiko Tachibana Ken Ikehara Takashi Okai Masumi Ujiie-Mikoshiba Ran Kubota 《Applied Geochemistry》2007,22(12):2872
A total of 49 elements have been identified in 338 coastal sea sediment samples collected from an area situated off the Ise-Tokai region of Japan for a nationwide marine geochemical mapping project. The spatial distribution patterns of the elemental concentrations in coastal seas along with the existing geochemical maps in terrestrial areas were used to define the natural geochemical background variation, mass transport, and contamination processes. The elemental concentrations of coastal sea sediments are determined primarily by particle size and regional differences. Most elemental concentrations increase with a decrease in particle size. Some elements such as Ca, Mn, and Yb are found to exist in large quantities in coarse particles containing calcareous shells, Fe–Mn oxides, and felsic volcanic sediments. Regional differences reflect the mass transfer process from terrestrial areas to coastal seas and the influence of the local marine geology. An analysis of variance (ANOVA) reveals that for many elements, the particle size effect is predominant over regional difference. The mean chemical compositions of coastal sea sediments are similar to those of stream sediments in adjacent terrestrial areas and in the upper crust of Japan. This observation supports the fact that coastal sea sediments have certainly originated from terrestrial materials. However, the spatial distributions of elemental concentrations are not always continuous between the land and coastal seas. The scale of mass movement observed in marine geochemical maps occurs at a distance of 20 km from the river mouth. A detailed examination of the spatial distribution patterns of K (K2O) and Cr concentrations suggests that terrestrial materials supplied through rivers are deposited near the shore initially, and then gravity-driven processes shift the sediments deeper into the basin. Contamination with heavy metals such as Zn, Cd and Pb was observed in coastal bays surrounded by urban and industrial areas. It is noteworthy that the areas with the highest concentration of these elements usually do not occur near the shore (not near the contamination source) but at the center of the bay. Unexpected low concentrations of Zn, Cd and Pb near shore may either be due to a decreased anthropogenic load in the most recent sediments or to dilution by unpolluted flood sediments. 相似文献
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This paper shows an explanatory tool (a FORTRAN program linked to GIS software), called VCM (Variable Clumping Method), for
detecting statistically significant `multi-level clumps' in the distribution of points. The multi-level clumps imply a set
of clumps whose clumping radius varies from a small radius to a large radius (in spirits, VCM is similar to the K-function method). Compared with the ordinary (fixed radius) clumping method, VCM can detect overall significant clumps in
the distribution of points.
Received: 8 March 1999/Accepted: 17 September 1999 相似文献
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Yoko KEBUKAWA Satoru NAKASHIMA Michio ISHIKAWA Kento AIZAWA Tsutomu INOUE Keiko NAKAMURA‐MESSENGER Michael E. ZOLENSKY 《Meteoritics & planetary science》2010,45(3):394-405
Abstract– Distributions of organic functional groups as well as inorganic features were analyzed in the Bells (CM2) carbonaceous chondrite using near‐field infrared (NFIR) spectroscopy. NFIR spectroscopy has recently been developed to enable infrared spectral mapping beyond the optical diffraction limit of conventional Fourier transform infrared microspectroscopy. NFIR spectral mapping of the Bells 300 nm thick sections on Al plates for 7.5 × 7.5 μm2 areas showed some C‐H‐rich areas which were considered to represent the organic‐rich areas. Heterogeneous distributions of organic matter as well as those of inorganic phases such as silicates (Si‐O) were observed with 1 μm spatial resolution. The NFIR mappings of aliphatic C‐H (2960 and 2930 cm?1) and structural OH (3650 cm?1) confirm that organic matter is associated with phyllosilicates as previously suggested. The NFIR mapping method can provide 1 μm spatial distribution of organic functional groups and their association with minerals. High local sensitivity of NFIR enables us to find organic‐rich areas and to characterize them by their aliphatic CH2/CH3 ratios. The aliphatic CH2/CH3 ratio of Bells is slightly higher than Murchison, similar to Orgueil, and lower than literature values of IDPs and cometary dust particles. 相似文献
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Speciation Study of Cr in a Geochemical Reference Material Sediment Series Using Sequential Extraction and XANES Spectroscopy 
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下载免费PDF全文 Atsuyuki Ohta 《Geostandards and Geoanalytical Research》2015,39(1):87-103
Speciation of Cr in geochemical reference materials was characterised by sequential extraction and X‐ray absorption near‐edge structure (XANES) spectroscopy to identify Cr(III) resulting from the reduction of pollutant Cr(VI). Sequential extraction suggested that the amount of Cr associated with an acetic acid soluble fraction was low; Cr associated with a reducible phase and an oxidisable phase was extracted at 5–10% of the total Cr concentration, and the residual phase was found to be the dominant Cr‐containing fraction. Cr speciation in soil artificially doped with Cr(VI) and sediment samples collected from highly populated and industrialised areas was different from that in naturally occurring materials. Substantial Cr was extracted as a reducible phase (15–30%) and an oxidisable phase (30–60%) for these samples. Through subsequent XANES spectroscopy analysis, the reducible phase was explained by Cr bound to Fe hydroxide, while the oxidisable phase was a mixture of Cr bound to humic substances and Cr hydroxides. That is, Cr(VI) present as a contaminant in sediments and soils was reduced to Cr(III), which then bound to Fe hydroxide and humic substances, precipitating as a hydroxide. Thus, a combination of sequential extraction and XANES spectroscopy allows for effective identification and quantification of the chemical forms of Cr in sediments and soils. 相似文献
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The SANET Toolbox: New Methods for Network Spatial Analysis 总被引：3，自引：0，他引：3
This paper describes new methods, called network spatial methods, for analyzing spatial phenomena that occur on a network or alongside a network (referred to as network spatial phenomena). First, the paper reviews network spatial phenomena discussed in the related literature. Second, the paper shows the uniform network transformation, which is used in the study of non‐uniform distributions on a network, such as the densities of traffic and population. Third, the paper outlines a class of network spatial methods, including nearest neighbor distance methods, K‐function methods, cell count methods, clumping methods, the Voronoi diagrams and spatial interpolation methods. Fourth, the paper shows three commonly used computational methods to facilitate network spatial analysis. Fifth, the paper describes the functions of a GIS‐based software package, called SANET, that perform network spatial methods. Sixth, the paper compares network spatial methods with the corresponding planar spatial methods by applying both methods to the same data set. This comparison clearly demonstrates how different conclusions can result. The conclusion summarizes the major findings. 相似文献