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Microbial manganese oxidation in seawater was carried out in enrichment cultures which were obtained from the seawater supply system at the Marine Science Museum, Tokai University (Shimizu-shi, Japan). The manganese oxide formed was well-crystallized todorokite. The major element composition was within the range of marine manganese concretions and the O/Mn molar ratio was 1.8. The conditions for formation of manganese oxide minerals in marine environments are discussed on the basis of these results. 相似文献
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Metal-organic complexes of transition elements removed by Amberlite XAD-2 resin from seawater pumped up from under the ground were determined. The proportions of iron, copper and zinc retained on the resin to dissolved forms of these metals were about 70, 40 and 5%, respectively, while manganese, cobalt and nickel were not retained on the resin. These results suggest that although iron may be retained in colloidal form, a significant fraction of copper is present in some organic form(s). 相似文献
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青岛大气气溶胶的浓度分布和干沉降的观测研究 总被引：9，自引：0，他引：9
根据青岛沙尘天气历史资料和近年来的青岛地面气溶胶观测资料,分析了青岛沙尘日数的长期变化趋势、季节变化特征以及气溶胶质量浓度、谱分布和干沉降的季节变化.分析结果表明,1961～1988年青岛沙尘日数呈波动变化,且幅度较大.1999年以来沙尘日数明显增加,且以浮尘天气为主.青岛在1961～2001年扬沙日数年平均值为1.83天,是北京同期的13%;年浮尘日数为2.93天,是北京同期的75%.青岛沙尘发生日数主要集中在冬春季,春季最高,冬季次高;夏季没有沙尘天气,秋季很低.青岛气溶胶质量浓度有明显的季节变化,春季最高,冬季次之,秋季又次之,夏季最低.大流量观测的总悬浮颗粒物(TSP)年平均浓度为177μgm-3,安德森分级采样器观测的气溶胶质量浓度为123μg m-3,两者的差别与不同的观测时间和观测仪器有关.在3月和4月,粗细粒子的浓度相差很大,粗粒子分别占总浓度的80%和62%.青岛气溶胶沉降通量在0.06～0.2 g m-2d-1之间,平均值为0.13 g m-2d-1,是北京沉降通量的30%. 相似文献
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This paper introduces a GIS-based toolbox, called SAINF, for analyzing the effects of infrastructural features on the distribution of non-infrastructural features. One of the distinct characteristics of SAINF is that it can deal not only with point-like infrastructural features but also line-like (e.g. railways) and polygon-like (e.g. big parks) features. SAINF analyzes these effects with the conditional nearest neighbor distance method and the cross K-function method. First, the paper briefly refers to these methods. Second, the paper illustrates how to use SAINF with an actual example. SAINF can be downloaded via the Internet without charge for non-profit uses.We express our thanks to Exceed Co. Ltd. for helping us program SAINF, and to Miki Arimoto for making the data of high-class apartment buildings and parks in Kiba. This development was partly supported by Grant-in-aid for Scientific Research No. 10202201 (Spatial information science for human and social sciences) and No. 14350327 (Regional supporting network planning for the elderly) by the Ministry of Education, Culture, Sports, Science and Technology of Japan. 相似文献
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A Computational Method for Estimating the Demand of Retail Stores on a Street Network and its Implementation in GIS 总被引：9，自引：0，他引：9
This paper describes a computational method for estimating the demand of retail stores on a street network using GIS. First, the 'network Huff model' is formulated on a network with the shortest-path distance as an extension of the ordinary Huff model (which assumes a continuous plane with Euclidean distance). Second, using this model, a formula for estimating the demand is derived. This estimation formula is similar to that with the ordinary Huff model, but it has an advantage in that the formula exactly computes the demand on a network. Third, a practical method for computing the formula is developed. Finally, a method of implementing this computational method in a GIS environment is shown. 相似文献
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Map sheets have been often used as a basic spatial unit for managing spatial data produced from paper maps. This often results
in incompatibility between adjacent map sheets, because spatial objects do not cross the boundaries smoothly and even the
boundaries themselves do not match their neighbors exactly. To solve the problem this paper proposes a computational procedure
for joining separate map sheets to obtain seamless spatial data. Line objects digitized separately in different map sheets
are considered, which are frequently used to represent road networks, gas pipelines, and boundaries of polygon objects. The
procedure consists of three steps: (1) extraction of end nodes, (2) detection of matching nodes, and (3) transformation of
the map sheet. Each step goes interactively so that unexpected errors can be avoided by human observation. To test the validity
of the procedure, map sheets are combined containing the road network data of Tokyo 23-ku area, Japan.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy 
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下载免费PDF全文 Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample). 相似文献
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Application of Chlorite Geothermometry to Hydrothermal Alteration in Toyoha Geothermal System, Southwestern Hokkaido, Japan 总被引：1，自引：0，他引：1
In this study, we applied chemical geothermometers to the estimation of formation temperatures of chlorites from various types of hydrothermally altered rocks in the Toyoha geothermal field, using core samples from six drill holes (TH-2 to TH-7) together with wasted ore samples from Toyoha vein-type ore deposit. Based on the preliminary examination of mineral assemblages by X-ray powder diffraction and optical microscopy, hydrothermal alteration observed through the drill holes was classified into four types of alteration zones: propylitic, mixed-layer minerals, kaolin minerals, and ore mineralized zones. The mineral assemblage of the ore mineralized zone observed through TH-2, TH-4, and TH-6 is similar to those of Toyoha ore veins reported previously. The Fe3+/ΣFe ratios of chlorites were determined by X-ray photoelectron spectroscopy (XPS), in addition to the usual microprobe analyses. The ratios ranged from 0.20–0.26 for chlorites from the propylitic alteration zone and from 0.13 to 0.17 for those from the ore mineralized zone associated with sulfide minerals. After correcting the Fe3+ contents in the octahedral sites of chlorite structures, we obtained acceptable temperatures of the chlorite formation by application of geothermometers, for instance, a similar range of 150–300°C for chlorites from either the propylitic zone or the ore mineralized zone developed through TH-2, TH-4, and TH-6. Chlorites from the ore mineralized zone proximal to the Toyoha deposit are characterized by high Fe and Mn contents compared to the propylitic chlorites, which is similar to the Toyoha vein-filling chlorites; the formation temperatures were close to both the homogenization temperatures of fluid inclusions and the present subsurface temperatures measured through drill holes. Chlorites from the Toyoha ore veins, however, gave slightly higher formation temperatures (180–350°C) than those of chlorites from the ore mineralized zone in the drill cores. This suggests that several types of hydrothermal alteration occurred at different stages in the Toyoha geothermal field and the composition of product chlorite was controlled not only by the temperature but also the composition of fluid related to the formation. Reliable estimation of temperature for the chlorite formation provides basic information on evaluating correctly other physicochemical conditions prevalent at the formation. 相似文献