A major element,PGE and Re–Os isotope study of Middle Atlas (Morocco) peridotite xenoliths: Evidence for coupled introduction of metasomatic sulphides and clinopyroxene     

Nadine Wittig  D. Graham Pearson  Joel A. Baker  Svend Duggen  Kaj Hoernle 《Lithos》2010,115(1-4):15-26

We present major element and PGE (platinum-group-element) abundances in addition to Re–Os isotope data for 11 spinel-facies whole rock peridotites from a single maar from the Middle Atlas Mountains, Morocco.Major element systematics of these xenoliths are generally correlated with indices of depletion. FeO–MgO systematics appear to suggest spinel-facies melting in the range of 5 to 25%. However, Al₂O₃ abundances in these xenoliths appear elevated relative to primitive mantle (Prima). The Al₂O₃ abundances in conjunction with other major elements require distinct re-enrichment of the Middle Atlas continental mantle root due to melt/rock reaction and precipitation of amphibole and/or clinopyroxene from passing silicate melts akin to MORB or OIB that evolved in reverse direction along the melting curves in e.g. FeO–MgO space. Sc and V confirm the range of apparent depletion and also indicate that the currently preserved fO₂ in these peridotites is distinctly different from fO₂ conditions observed in subduction zones.The majority of these xenoliths have low Os and Ir (I-PGEs) concentrations relative to Prima and modelled sulphide- and clinopyroxene-depleted residues of mantle melting under low fO₂, mid-ocean ridge-like conditions. Moreover, Pt and Pd (P-PGE) abundances are elevated when compared to their expected abundances after substantial melt extraction. Importantly, the systematically low Ir abundances in the majority of samples show well-correlated trends with Al₂O₃, MgO and Cu that are inconsistent with established melting trends. Os isotopes in the Middle Atlas xenoliths range from ¹⁸⁷Os/¹⁸⁸Os = 0.11604 to 0.12664 although most samples are close to chondritic. The Os isotope ratios are decoupled from ¹⁸⁷Re/¹⁸⁸Os but, together with Re abundances, also exhibit a good correlation with Al₂O₃, MgO and Cu.The major element, I-PGE and Os isotope correlations suggest that the initial melt depletion led to the exhaustion of sulphide and clinopyroxene (20 to 30%) without significant stabilization of I-PGE-rich alloys. During later modal metasomatism of the refractory Middle Atlas continental mantle root with silicate melts akin to MORB or OIB the introduction of clinopyroxene/amphibole reduced the volume of the melt inducing sulphur saturation in these melts causing precipitation of secondary sulphides. This coupled crystallization of pyroxenes and sulphides (chalcopyrite) resulted in the two-component mixing systematics exhibited by I-PGEs, Os isotopes with major elements and Cu preserved in the Middle Atlas continental mantle root.  相似文献   

Patterns of Irrigated Agricultural Land Conversion in a Western U.S. Watershed: Implications for Landscape-Level Water Management and Land-Use Planning     

J. Mark Baker  Yvonne Everett  Lora Liegel  Rob Van Kirk 《社会与自然资源》2014,27(11):1145-1160

In irrigated agricultural landscapes, land-use conversion may have landscape-level social, hydrological, and ecological effects. We used geographic information systems (GIS) and interviews to analyze development effects on irrigation in the Henry's Fork Watershed, Idaho. Farmers developed irrigation there in the 19th century, and incidental recharge from canal seepage and flood irrigation raised groundwater levels and expanded wetlands. Cohesive culture in agricultural communities sustained irrigation systems until amenity-driven demographic shifts beginning in the 1970s led to development approved by local governments with land-use planning but no water-management authority. Although only 5% of irrigated land has been converted, development has fragmented irrigated landscapes and made canal-system operation more difficult, potentially reducing groundwater levels, wetland extent, and return flows critical to downstream irrigators and fish and wildlife. We discuss future scenarios, highlighting the need for increased communication among local and state governments regarding land use and water management in irrigated landscapes across the West.  相似文献   

Encyclopedia of caves D. C. Culver and W. B. White (eds) Publisher Elsevier Academic Press, 2004 (654 pp) ISBN 0 12 198651 9 (hardback)     

Andy Baker 《第四纪科学杂志》2005,20(5):509-510

  相似文献   

The chemical evolution of the Universe – I. High column density absorbers     

G. P. Mathlin  A. C. Baker  D. K. Churches  M. G. Edmunds 《Monthly notices of the Royal Astronomical Society》2001,321(4):743-758

We construct a simple, robust model of the chemical evolution of galaxies from high to low redshift, and apply it to published observations of damped Lyman α quasar absorption line systems (DLAs). The elementary model assumes quiescent star formation and isolated galaxies (no interactions, mergers or gas flows). We consider the influence of dust and chemical gradients in the galaxies, and hence explore the selection effects in quasar surveys. We fit individual DLA systems to predict some observable properties of the absorbing galaxies, and also indicate the expected redshift behaviour of chemical element ratios involving nucleosynthetic time delays.
Despite its simplicity, our 'monolithic collapse' model gives a good account of the distribution and evolution of the metallicity and column density of DLAs, and of the evolution of the global star formation rate and gas density below redshifts z ∼3. However, from the comparison of DLA observations with our model, it is clear that star formation rates at higher redshifts ( z >3) are enhanced. Galaxy interactions and mergers, and gas flows very probably play a major role.  相似文献   

Continuous fluorescence assessment of organic matter variability on the Bournbrook River,Birmingham, UK     

Elfrida M. Carstea  Andy Baker  Gabriela Pavelescu  Ian Boomer 《水文研究》2009,23(13):1937-1946

Continuous monitoring of dissolved organic matter (DOM) character and concentration at hourly resolution is rare, despite the importance of analysing organic matter variability at high‐temporal resolution to evaluate river carbon budgeting, river water health by detecting episodic pollution and to determine short‐term variations in chemical and ecological function. The authors report a 2‐week experiment performed on DOM sampled from Bournbrook, Birmingham, UK, an urban river for which spectrophotometric (fluorescence, absorbance), physiochemical (dissolved organic carbon [DOC], electrical conductivity, pH) and isotopic (D/H) parameters have been measured at hourly frequency. Our results show that the river had sub‐daily variations in both organic matter concentration and characteristics. In particular, after relatively high‐magnitude precipitation events, organic carbon concentration increased, with an associated increase in intensity of both humic‐like and tryptophan‐like fluorescence. D/H isotopic ratio demonstrates different hydrological responses to different rainfall events, and organic matter character reflects this difference. Events with precipitation < 2 mm typically yielded isotopically heavy water with relatively hydrophilic DOM and relatively low specific absorbance. Events with precipitation > 2 mm had isotopically lighter water with higher specific absorbance and a decrease in the proportion of microbially derived to humic‐like fluorescence. In our heavily urbanized catchment, we interpret these signals as one where riverine DOM is dominated by storm sewer‐derived ‘old’ organic matter at low‐rainfall amounts and a mixed signal at high‐precipitation amounts where ‘event’ surface runoff‐derived organic matter dominate during storm sewer and combined sewer overflow routed DOM. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Liquidus Equilibria in the System K2O-Na2O-Al2O3-SiO2-F2O-1-H2O to 100 MPa: II. Differentiation Paths of Fluorosilicic Magmas in Hydrous Systems     

Dolejs  David; Baker  Don R. 《Journal of Petrology》2007,48(4):807-828

We investigated phase equilibria in the six-component systemNa₂O–K₂O–Al₂O₃–SiO₂–F₂O_–1–H₂Oat 100 MPa to characterize differentiation paths of naturalfluorine-bearing granitic and rhyolitic magmas. Topaz and cryoliteare stable saturating solid phases in calcium-poor systems.At 100 MPa the maximum solidus depression and fluorine solubilityin evolving silicic melts are controlled by the eutectics haplogranite–cryolite–H₂Oat 640°C and 4 wt % F, and haplogranite–topaz–H₂Oat 640°C and 2 wt % F. Topaz and cryolite form a binaryperalkaline eutectic at 660°C, 100 MPa and fluid saturation.The low-temperature nature of this invariant point causes displacementof multiphase eutectics with quartz and alkali feldspar towardsthe topaz–cryolite join and enables the silicate liquidusand cotectic surfaces to extend to very high fluorine concentrations(more than 30 wt % F) for weakly peraluminous and subaluminouscompositions. The differentiation of fluorine-bearing magmasfollows two distinct paths of fluorine behavior, depending onwhether additional minerals buffer the alkali/alumina ratioin the melt. In systems with micas or aluminosilicates thatbuffer the activity of alumina, magmatic crystallization willreach either topaz or cryolite saturation and the system solidifiesat low fluorine concentration. In leucogranitic suites precipitatingquartz and feldspar only, the liquid line of descent will reachtopaz or cryolite but fluorine will continue to increase untilthe quaternary eutectic with two fluorine-bearing solid phasesis reached at 540°C, 100 MPa and aqueous-fluid saturation.The maximum water solubility in the haplogranitic melts increaseswith the fluorine content and reaches 12· 5 ±0· 5 wt % H₂O at the quartz–cryolite–topazeutectic composition. A continuous transition between hydrousfluorosilicate melts and solute-rich aqueous fluids is not documentedby this study. Our experimental results are applicable to leucocraticfluorosilicic magmas. In multicomponent systems, however, thepresence of calcium may severely limit enrichment of fluorineby crystallization of fluorite. KEY WORDS: granite; rhyolite; topaz; cryolite; magmatic differentiation  相似文献   

Persistent Near-Surface Flow Structures from Local Helioseismology     

Rachel Howe  R. W. Komm  D. Baker  L. Harra  L. van Driel-Gesztelyi  R. S. Bogart 《Solar physics》2015,290(11):3137-3149

  相似文献   

Tracking Solar Active Region Outflow Plasma from Its Source to the Near-Earth Environment     

J. L. Culhane  D. H. Brooks  L. van Driel-Gesztelyi  P. Démoulin  D. Baker  M. L. DeRosa  C. H. Mandrini  L. Zhao  T. H. Zurbuchen 《Solar physics》2014,289(10):3799-3816

Seeking to establish whether active-region upflow material contributes to the slow solar wind, we examine in detail the plasma upflows from Active Region (AR) 10978, which crossed the Sun’s disc in the interval 8 to 16 December 2007 during Carrington rotation (CR) 2064. In previous work, using data from the Hinode/EUV Imaging Spectrometer, upflow velocity evolution was extensively studied as the region crossed the disc, while a linear force-free-field magnetic extrapolation was used to confirm aspects of the velocity evolution and to establish the presence of quasi-separatrix layers at the upflow source areas. The plasma properties, temperature, density, and first ionisation potential bias [FIP-bias] were measured with the spectrometer during the disc passage of the active region. Global potential-field source-surface (PFSS) models showed that AR 10978 was completely covered by the closed field of a helmet streamer that is part of the streamer belt. Therefore it is not clear how any of the upflowing AR-associated plasma could reach the source surface at 2.5 R_⊙ and contribute to the slow solar wind. However, a detailed examination of solar-wind in-situ data obtained by the Advanced Composition Explorer (ACE) spacecraft at the L₁ point shows that increases in O⁷⁺/O⁶⁺, C⁶⁺/C⁵⁺, and Fe/O – a FIP-bias proxy – are present before the heliospheric current-sheet crossing. These increases, along with an accompanying reduction in proton velocity and an increase in density are characteristic of both AR and slow-solar-wind plasma. Finally, we describe a two-step reconnection process by which some of the upflowing plasma from the AR might reach the heliosphere.  相似文献   

Polar wander on Mars: Evidence in the geoid     

Kenneth F. Sprenke  Leslie L. Baker  Adele F. Williams 《Icarus》2005,174(2):486-489

The geoid of Mars is dominated by its equilibrium figure and by the effect of the Tharsis rise. To investigate the rotational stability of Mars prior to the rise of Tharsis, we produced a residual non-hydrostatic geoid without Tharsis. First the hydrostatic component of the present-day flattening was removed. This procedure was performed using a 6% non-hydrostatic component of flattening, a value set by the spin axis precession rate of Mars. Then zonal spherical harmonics up to degree 6 centered on Tharsis were removed. Finally, the resultant residual geoid was evaluated for rotational stability by comparing polar and equatorial moments at 4050 trial pole positions. If the spin axis of ancient Mars was secularly stable, our analysis indicates that substantial polar wander has occurred with the rise of Tharsis. Stable spin axis positions on the non-hydrostatic residual figure of Mars are 15° to 90° from the present-day poles. This result is consistent with previously proposed paleopoles based on magnetic anomalies, geomorphology, and grazing impacts.  相似文献   

AN AUTOMATIC PROCEDURE FOR ESTIMATING SPRING SMALL GRAINS ACREAGE FROM LANDSAT DATA     

Robert R. J. Mohler  Wesley F. Palmer  Thomas C. Baker  Robert M. Bizzell 《The Professional geographer》1986,38(4):375-382

The development and testing of a computerized technique for utilizing multitemporal Landsat multispectral scanner data to estimate spring small grains acreage are described. The Kauth-Thomas green number transformation is applied to the data prior to application of the pixel-level standardized logic. Four years of data from the U.S. and Canada are used in testing. A comparison of the test results to those of the analyst-intensive procedures indicates a potential for increase in near-harvest estimation efficiency with little sacrifice in accuracy.  相似文献