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Tephrochronology is a powerful tool for dating sedimentary sequences, especially in Patagonia, where a large number of active volcanoes have produced frequent historical eruptions. Short lacustrine sedimentary sequences were extracted from the lakes Moreno Oeste and Ton?ek (Nahuel Huapi National Park). Seventeen volcanic ash layers were identified in both cores, 210Pb and 137Cs were used for dating techniques, and historical volcanic records were employed for correlation. White pumice and glass shards from the tephras were characterised by measuring major and trace element contents by instrumental neutron activation analysis. Two volcanic sources – the Cordón Caulle and the Calbuco volcanoes – were recognised as the prevailing systems that impacted the area in the past 800–1000 a. The Calbuco volcano was mainly responsible for the nine tephras identified in the Lake Ton?ek sequence. Four of these nine tephras also contained material from the Cordón Caulle complex, and could be interpreted as composite tephras or possible reworked ones. The Calbuco volcano showed predominant influences in the Lake Moreno Oeste sequence. Six of the eight tephras identified in such a sequence were from the Calbuco volcano, and three of these six contained material from the Cordón Caulle complex. The other two were from the Cordón Caulle complex, with contributions from the Calbuco volcano in one of them. These findings show that the high frequency of volcanic events in the study region demands an accurate characterisation of the products generated by each source, as well as an evaluation of their spatial distribution, to obtain a consistent framework for dating recent environmental changes. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
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Monitoring the temporal variation of solute concentrations in streams at high temporal frequency can play an important role in understanding the hydrological and biogeochemical behaviour of catchments. UV–visible spectrometry is a relatively inexpensive and easily used tool to infer those concentrations in streams at high temporal resolution. However, it is not yet clear which solutes can be modelled with such an in-situ sensor. Here, we installed a UV–visible spectrometer probe (200–750 nm) in a high-altitude tropical Páramo stream to record the wavelength absorbance at a 5-min temporal resolution. For calibration, we simultaneously sampled stream water at a 4-h frequency from February 2018 to March 2019 for subsequent laboratory analysis. Absorbance spectra and laboratory-determined solute concentrations were used to identify the best calibration method and to determine which solute concentrations can be effectively inferred using in situ spectrometry through the evaluation of six calibration methods of different mathematical complexity. Based on the Nash – Sutcliffe efficiency (NSE) and Akaike information criterion metrics, our results suggest that multivariate methods always outperformed simpler strategies to infer solute concentrations. Eleven out of 21 studied solutes (Al, DOC, Ca, Cu, K, Mg, N, Na, Rb, Si and Sr) were successfully calibrated (NSE >0.50) and could be inferred using UV–visible spectrometry even with a reduced daily sampling frequency. It is worth noting that most calibrated solutes were correlated with wavelengths (WLs) in the low range of the spectra (i.e., UV range) and showed relatively good correlation with DOC. The latter suggests that estimation of metal concentrations could be possible in other streams with a high organic load (e.g., peat dominated catchments). In situ operation of spectrometers to monitor water quality parameters at high temporal frequency (sub-hourly) can enhance the protection of human water supplies and aquatic ecosystems as well as providing information for assessing catchment hydrological functioning.  相似文献   
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The need to understand and simulate hydrological phenomena and their interactions, and the impact of anthropogenic and climate changes on natural environments have promoted the study of evaporation from bare soils in arid climates. In closed Altiplano basins, such as those encountered in arid and hyper arid basins in northern Chile, evaporation from shallow groundwater is the main source of aquifer depletion, and thus, its study is crucial for water resources management. The objective of this work is to understand the mechanisms of evaporation in saline soils with shallow water tables, in order to better quantify evaporation fluxes and improve our understanding of the water balance in these regions. To achieve this objective, a model that couples fluid flow with heat transfer was developed and calibrated using column experiments with saline soils from the Huasco salt flat basin, Chile. The model enables determination of both liquid and water vapour fluxes, as well as the location of the evaporation front. Experimental results showed that salt transport inside the soil profile modified the water retention curve, highlighting the importance of including salt transport when modelling the evaporation processes in these soils. Indeed, model simulations only agreed with the experimental data when the effect of salt transport on water retention curves was taken into account. Model results also showed that the evaporation front is closer to the soil surface as the water table depth reduces. Therefore, the model allows determining the groundwater level depth that results in disconnection of liquid fluxes in the vadose zone. A sensitivity analysis allowed understanding the effect of water‐flux enhancements mechanisms on soil evaporation. The results presented in this study are important as they allow quantifying the evaporation that occurs in bare soils from Altiplano basins, which is typically the main water discharge in these closed basins. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
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Different hydrological models of sediment entrainment, infiltration, overland flow production, soil loss, landslide occurrence, among others, need rainfall events data. The Minimum Inter‐event Time (MIT) used to separate rainfall events affects their properties. Therefore, it is highly important their correct definition. Various event definitions are commonly used in hydrology, and a high variety of MIT is applied. In this work, an easy method is proposed for deciding the proper MIT in a certain place when dealing with hourly rainfall data series. This new methodology is based on the scale invariance properties of rainfall, analysed with both multifractal and Self‐Organized Criticality theories. The similarity between some parameters from both analyses allows picking out the more appropriate MIT for the hourly rainfall data sets analysed, in Malaga (Southern Spain) and Bullileo (Central Chile). The method can be applied for different rainfall time resolutions according to the purpose of the model that needs the rain event information. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
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