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101.
Geochemical data obtained from X-ray fluorescence, physical properties, total organic and inorganic carbon content (TOC/TIC), and diatom analysis from a 6.61-m-long sedimentary sequence near the modern northern shore of Lake Zirahuen (101° 44′ W, 19° 26′ N, 2000 m asl) provide a reconstruction of lacustrine sedimentation during the last approximately 17 cal kyr BP. A time scale is based on ten AMS 14C dates and by tephra layers from Jorullo (AD 1759-1764) and Paricutin (AD 1943-1952) volcanoes. The multiproxy analyses presented in this study reveal abrupt changes in environmental and climatic conditions. The results are compared to the paleo-record from nearby Lake Patzcuaro. Dry conditions and low lake level are inferred in the late Pleistocene until ca. 15 cal kyr BP, followed by a slight but sustained increase in lake level, as well as a higher productivity, peaking at ca. 12.1 cal kyr BP. This interpretation is consistent with several regional climatic reconstructions in central Mexico, but it is in opposition to record from Lake Patzcuaro. A sediment hiatus bracketed between 12.1 and 7.2 cal kyr BP suggests a drop in lake level in response to a dry early Holocene. A deeper, more eutrophic and turbid lake is recorded after 7.2 cal kyr BP. Lake level at the coring site during the mid Holocene is considered the highest for the past 17 cal kyr BP. The emplacement of the La Magueyera lava flows (LMLF), dated by thermoluminiscence at 6560 ± 950 year, may have reduced basin volume and contributed to the relative deepening of the lake after 7.2 cal kyr BP. The late Holocene (after 3.9 cal kyr BP) climate is characterized by high instability. Extensive erosion, lower lake levels, dry conditions and pulses of high sediment influx due to high rainfall are inferred for this time. Further decrease in lake level and increased erosion are recorded after ca. AD 1050, at the peak of Purepechas occupation (AD 1300–1521), and until the eighteenth century. Few lacustrine records extend back to the late Pleistocene—early Holocene in central Mexico; this paper contributes to the understanding of late Pleistocene-Holocene paleoclimates in this region.  相似文献   
102.
Paleoenvironmental studies have documented the late Pleistocene to Holocene evolution of the lakes in the central and southern parts of the basin of Mexico (Texcoco and Chalco). No information was available, however, for the lakes in the north-eastern part of this basin. The north-eastern and the central and southern areas represent, at present, different environmental conditions: an important gradient exists between the dry north and the moister south. To investigate the late Pleistocene to Holocene characteristics of the north-eastern lakes in the basin of Mexico two parallel cores (TA and TB) were drilled at the SE shore of Lake Tecocomulco. Stratigraphy, magnetic properties, granulometry, diatom and pollen analyses performed on these sediments indicate that the lake experienced a series of changes between ca. > 42,000 yr BP and present. Chronological control is given by five radiocarbon determinations. The base of the record is represented by a thick, rhyolitic air-fall tephra that could be older than ca. 50,000 yr BP. After this Plininan event, and until ca. 42,000 yr BP, Lake Tecocomulco was a moderately deep, freshwater lake surrounded by extended pine forests that suggest the presence of cooler and moister conditions than present. Between ca. 42,000 and 37,000 yr BP, the lake became shallower but with important fluctuations and pollen suggests slightly warmer conditions. Between ca. 37,000 and 30,000 yr BP the lake experienced two relatively deep phases separated by a dry interval. A second Plinian eruption, represented in the sequence by a dacitic an air-fall tephra layer dated at 31,000 yr BP, occurred in the area by the end of this dry episode. Between ca. 30,000 and 25,7000 yr BP Tecocomulco was a fresh to slightly alkaline lake with a trend towards lower level. After ca. 25,700 yr BP very low lake levels are inferred, and after ca. 16,000 yr BP the data indicate the presence of a very dry environment that was persistent until the middle Holocene. After 3,500 yr BP lacustrine conditions were re-established and the vegetation cover shows a change towards higher percentages of herbaceous taxa.  相似文献   
103.
We measured the extensional‐mode attenuation and Young's modulus in a porous sample made of sintered borosilicate glass at microseismic to seismic frequencies (0.05–50 Hz) using the forced oscillation method. Partial saturation was achieved by water imbibition, varying the water saturation from an initial dry state up to ~99%, and by gas exsolution from an initially fully water‐saturated state down to ~99%. During forced oscillations of the sample effective stresses up to 10 MPa were applied. We observe frequency‐dependent attenuation, with a peak at 1–5 Hz, for ~99% water saturation achieved both by imbibition and by gas exsolution. The magnitude of this attenuation peak is consistently reduced with increasing fluid pressure and is largely insensitive to changes in effective stress. Similar observations have recently been attributed to wave‐induced gas exsolution–dissolution. At full water saturation, the left‐hand side of an attenuation curve, with a peak beyond the highest measured frequency, is observed at 3 MPa effective stress, while at 10 MPa effective stress the measured attenuation is negligible. This observation is consistent with wave‐induced fluid flow associated with mesoscopic compressibility contrasts in the sample's frame. These variations in compressibility could be due to fractures and/or compaction bands that formed between separate sets of forced‐oscillation experiments in response to the applied stresses. The agreement of the measured frequency‐dependent attenuation and Young's modulus with the Kramers–Kronig relations and additional data analyses indicate the good quality of the measurements. Our observations point to the complex interplay between structural and fluid heterogeneities on the measured seismic attenuation and they illustrate how these heterogeneities can facilitate the dominance of one attenuation mechanism over another.  相似文献   
104.
In interconnected microcracks, or in microcracks connected to spherical pores, the deformation associated with the passage of mechanical waves can induce fluid flow parallel to the crack walls, which is known as squirt flow. This phenomenon can also occur at larger scales in hydraulically interconnected mesoscopic cracks or fractures. The associated viscous friction causes the waves to experience attenuation and velocity dispersion. We present a simple hydromechanical numerical scheme, based on the interface-coupled Lamé–Navier and Navier–Stokes equations, to simulate squirt flow in the frequency domain. The linearized, quasi-static Navier–Stokes equations describe the laminar flow of a compressible viscous fluid in conduits embedded in a linear elastic solid background described by the quasi-static Lamé–Navier equations. Assuming that the heterogeneous model behaves effectively like a homogeneous viscoelastic medium at a larger spatial scale, the resulting attenuation and stiffness modulus dispersion are computed from spatial averages of the complex-valued, frequency-dependent stress and strain fields. An energy-based approach is implemented to calculate the local contributions to attenuation that, when integrated over the entire model, yield results that are identical to those based on the viscoelastic assumption. In addition to thus validating this assumption, the energy-based approach allows for analyses of the spatial dissipation patterns in squirt flow models. We perform simulations for a series of numerical models to illustrate the viability and versatility of the proposed method. For a 3D model consisting of a spherical crack embedded in a solid background, the characteristic frequency of the resulting P-wave attenuation agrees with that of a corresponding analytical solution, indicating that the dissipative viscous flow problem is appropriately handled in our numerical solution of the linearized, quasi-static Navier–Stokes equations. For 2D models containing either interconnected cracks or cracks connected to a circular pore, the results are compared with those based on Biot's poroelastic equations of consolidation, which are solved through an equivalent approach. Overall, our numerical simulations and the associated analyses demonstrate the suitability of the coupled Lamé–Navier and Navier–Stokes equations and of Biot's equations for quantifying attenuation and dispersion for a range of squirt flow scenarios. These analyses also allow for delineating numerical and physical limitations associated with each set of equations.  相似文献   
105.
This paper presents a high-resolution operational forecast system for providing support to oil spill response in Belfast Lough. The system comprises an operational oceanographic module coupled to an oil spill forecast module that is integrated in a user-friendly web application. The oceanographic module is based on Delft3D model which uses daily boundary conditions and meteorological forcing obtained from COPERNICUS and from the UK Meteorological Office. Downscaled currents and meteorological forecasts are used to provide short-term oil spill fate and trajectory predictions at local scales. Both components of the system are calibrated and validated with observational data, including ADCP data, sea level, temperature and salinity measurements and drifting buoys released in the study area. The transport model is calibrated using a novel methodology to obtain the model coefficients that optimize the numerical simulations. The results obtained show the good performance of the system and its capability for oil spill forecast.  相似文献   
106.
A complete first order orthogonal plan was used to optimize the growth and the production of yessotoxin (YTX) by the dinoflagellate Protoceratium reticulatum in culture by controlling salinity, temperature and irradiance. Initially, an approach to the kinetic data of cellular density and YTX production for each one of the experimental design conditions was performed. The P. reticulatum growth and YTX production were fitted to logistical equations and to a first-order kinetic model, respectively. The parameters obtained from this adjustment were used as dependent variables for the formulation of the empirical equations of the factorial design tested. The results showed that in practically all the cases for both, P. reticulatum growth and YTX production, irradiance is the primary independent variable and has a positive effect in the range 50-90 micromol photons m(-2) s(-1). Additionally, in certain specific cases, temperature reveals significant positive effects when maintained between 15 and 23 degrees C and salinity in the range of 20-34 displays negative effects. Despite the narrow ranges used in the work, results showed the suitability of factorial analysis to evaluate the optimal conditions for growth and yessotoxin production by the dinoflagellate P. reticulatum.  相似文献   
107.
Environmental dating tracers (3H, 3He, 4He, CFC-12, CFC-11, and SF6) and the natural spring response (hydrochemistry, water temperature, and hydrodynamics) were jointly used to assess mixing processes and to characterize groundwater flow in a relatively small carbonate aquifer with complex geology in southern Spain. Results evidence a marked karst behaviour of some temporary outlets, with sharp and rapid responses to precipitation events, while some perennial springs show buffer and delayed variations with respect to recharge periods. The general geochemical evolution shows a pattern, from higher to lower altitudes, in which mineralization and the Mg/Ca ratio rise, evidencing longer water–rock interaction. The large SF6 concentrations in groundwater suggest terrigenic production, whereas CFC-11 values are affected by sorption or degradation. The groundwater age in the perennial springs—as deduced from CFC-12 and 3H/3He—points to mean residence times of several decades, although the large amount of radiogenic 4He in samples indicate a contribution of old groundwater (free of 3H and CFC-12). Lumped parameter models and shape-free models were created based on 3H, tritiogenic 3He, CFC-12, and radiogenic 4He data in order to interpret the age distribution of the samples. Results evidence the existence of two mixing components, with an old fraction ranging between 160 and 220 years in age. The correlation of physicochemical parameters with some dating parameters, derived from the mixing models, serves to explain the hydrogeochemical processes occurring within the system. Altogether, long residence times are shown to be possible in small alpine systems with a clearly karst behaviour if the geological setting features highly tectonized media including units with diverse hydrogeological characteristics. These findings highlight the importance of applying different approaches, including groundwater dating techniques, when studying such groundwater flow regimes.  相似文献   
108.
Harnessing the radiometric information provided by photogrammetric flights could be useful in increasing the thematic applications of aerial images. The aim of this paper is to improve relative and absolute homogenization in aerial images by applying atmospheric correction and treatment of bidirectional effects. We propose combining remote sensing methodologies based on radiative transfer models and photogrammetry models, taking into account the three-dimensional geometry of the images (external orientation and Digital Elevation Model). The photogrammetric flight was done with a Z/I Digital Mapping Camera (DMC) with a Ground Sample Distance (GSD) of 45 cm. Spectral field data were acquired by defining radiometric control points in order to apply atmospheric correction models, obtaining calibration parameters from the camera and surface reflectance images. Kernel-driven models were applied to correct the anisotropy caused by the bidirectional reflectance distribution function (BRDF) of surfaces viewed under large observation angles with constant illumination, using the overlapping area between images and the establishment of radiometric tie points. Two case studies were used: 8-bit images with applied Lookup Tables (LUTs) resulting from the conventional photogrammetric workflow for BRDF studies and original 12-bit images (Low Resolution Color, LRC) for the correction of atmospheric and bidirectional effects. The proposed methodology shows promising results in the different phases of the process. The geometric kernel that shows the best performance is the Lidense kernel. The homogenization factor in 8-bit images ranged from 6% to 25% relative to the range of digital numbers (0–255), and from 18% to 35% relative to levels of reflectance (0–100) in the 12-bit images, representing a relative improvement of approximately 1–30%, depending on the band analyzed.  相似文献   
109.
A multivariate biochronological analysis of the Plio‐Pleistocene Iberian rodent fossil record is presented. Among more than 300 fossil sites, 49 sites have been selected. The ordination of the fossil sites selected from the Iberian Peninsula has been achieved by the appearance event ordination method. After calibration of this ordination with geochronological dates at some of the localities, numerical dates are proposed for all the localities studied. Hence, mammal fossil sites non‐datable by other means (palaeomagnetism, radiometric dating, etc.) have been dated with a relatively high degree of confidence. Final results allow dating of boundaries between the Plio‐Pleistocene European Land Mammal Ages (ELMAS) or the Mammal Neogene (MN) units. These boundaries agree with previous studies using magnetostratigraphical calibration of these scales. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
110.
Twenty-one surficial sand samples from the Altar Desert coastal and desert dune systems were analysed for rare earth elements (REE) content. This was done to observe the provenance signatures for four strategic dune localities near the Colorado River Delta, the El Pinacate dune fields, and the beaches of the north of the Gulf of California in the state of Sonora, Mexico. Our goals are to show which mechanisms (i.e., aeolian, marine) exert more influence on the composition of the Altar Desert dune sands. This study also shows the usefulness of REE spatial distribution to determine the relative mobility of the sand. Some sand samples from the dune systems in San Luis Río Colorado (SLRC), Golfo de Santa Clara (GSC), and Puerto Peñasco (PP) displayed dissimilar REE concentrations with respect to the rest of the sand samples from the same sites. These differences can be related to short aeolian transport distance in the sands with high REE concentrations and long aeolian transport distance in the sands with low REE concentrations. Besides, high REE concentration in the sands might be due to their closeness to the Colorado River Delta sediments and to recycled sands derived from granitic rocks. In contrast, all the sand samples from the El Pinacate (EP) site have similar REE concentration values, suggesting that the El Pinacate dune sands are influenced by more selective aeolian processes and less diverse heavy mineral content. The Altar Desert dune sands are derived from granitic sources eroded by the Colorado River. Our results also indicate that the Altar Desert dune sands are low in heavy mineral content (with the exception of Fe and Ti bearing minerals) and enriched in carbonates with phosphates (especially at the PP site) yielding poor correlations between REE and major element concentrations. The REE geographical distribution values in the Altar Desert dune sands indicate that light and heavy REE concentration values are related to aeolian transport, maturity of the sands, their low weathering rates, proximity of the source rocks, and the biogenic debris input from beach sands into the dune.  相似文献   
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