Anthropogenic contributions to atmospheric Hg, Pb and As accumulation recorded by peat cores from southern Greenland and Denmark dated using the C “bomb pulse curve”     

W. Shotyk  M.E. Goodsite  F. Roos-Barraclough  R. Frei  G. Asmund  T.S. Hansen 《Geochimica et cosmochimica acta》2003,67(21):3991-4011

Mercury concentrations are clearly elevated in the surface and sub-surface layers of peat cores collected from a minerotrophic (“groundwater-fed”) fen in southern Greenland (GL) and an ombrotrophic (“rainwater-fed”) bog in Denmark (DK). Using ¹⁴C to precisely date samples since ca. AD 1950 using the “atmospheric bomb pulse,” the chronology of Hg accumulation in GL is remarkably similar to the bog in DK where Hg was supplied only by atmospheric deposition: this suggests not only that Hg has been supplied to the surface layers of the minerotrophic core (GL) primarily by atmospheric inputs, but also that the peat cores have preserved a consistent record of the changing rates of atmospheric Hg accumulation. The lowest Hg fluxes in the GL core (0.3 to 0.5 μg/m²/yr) were found in peats dating from AD 550 to AD 975, compared to the maximum of 164 μg/m²/yr in AD 1953. Atmospheric Hg accumulation rates have since declined, with the value for 1995 (14 μg/m²/yr) comparable to the value for 1995 obtained by published studies of atmospheric transport modelling (12 μg/m²/yr).The greatest rates of atmospheric Hg accumulation in the DK core are also found in the sample dating from AD 1953 and are comparable in magnitude (184 μg/m²/yr) to the GL core; again, the fluxes have since gone into strong decline. The accumulation rates recorded by the peat core for AD 1994 (14 μg/m²/yr) are also comparable to the value for 1995 obtained by atmospheric transport modelling (18 μg/m²/yr). Comparing the Pb/Ti and As/Ti ratios of the DK samples with the corresponding crustal ratios (or “natural background values” for preanthropogenic peat) shows that the samples dating from 1953 also contain the maximum concentration of “excess” Pb and As. The synchroneity of the enrichments of all three elements (Hg, Pb, and As) suggests a common source, with coal-burning the most likely candidate. Independent support for this interpretation was obtained from the Pb isotope data (²⁰⁶Pb/²⁰⁷Pb = 1.1481 ± 0.0002 in the leached fraction and 1.1505 ± 0.0002 in the residual fraction) which is too radiogenic to be explained in terms of gasoline lead alone, but compares well with values for U.K. coals. In contrast, the lowest values for ²⁰⁶Pb/²⁰⁷Pb in the DK profile (1.1370 ± 0.0003 in the leached fraction and 1.1408 ± 0.0003 in the residual fraction) are found in the sample dating from AD 1979: this shows that the maximum contribution of leaded gasoline occurred approximately 25 yr after the zenith in total anthropogenic Pb deposition.  相似文献   

Adaptive Multiscale Permeability Estimation     

Alv-Arne Grimstad  Trond Mannseth  Geir Nævdal  Hege Urkedal 《Computational Geosciences》2003,7(1):1-25

With multiscale permeability estimation one does not select parameterization prior to the estimation. Instead, one performs a hierarchical search for the right parameterization while solving a sequence of estimation problems with an increasing parameterization dimension. In some previous works on the subject, the same refinement is applied all over the porous medium. This may lead to over-parameterization, and subsequently, to unrealistic permeability estimates and excessive computational work. With adaptive multiscale permeability estimation, the new parameterization at an arbitrary stage in the estimation sequence is such that new degrees of freedom are not necessarily introduced all over the porous medium. The aim is to introduce new degrees of freedom only where it is warranted by the data. In this paper, we introduce a novel adaptive multiscale estimation. The approach is used to estimate absolute permeability from two-phase pressure data in several numerical examples.  相似文献   

An Assessment of Conventional In Situ Air Sparging Pilot Tests     

Paul C. Johnson  Richard L. Johnson  Christopher Neaville  Erik E. Hansen  Steve M. Stearns  Ira J. Dortch 《Ground water》1997,35(5):765-774

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Gravity reduction with three-dimensional atmospheric pressure data for precise ground gravity measurements     

Juergen Neumeyer  Jan Hagedoorn  Jens Leitloff  Torsten Schmidt 《Journal of Geodynamics》2004,38(3-5):437

The redistribution of air masses induces gravity variations (atmospheric pressure effect) up to about 20 μgal. These variations are disturbing signals in gravity records and they must be removed very carefully for detecting weak gravity signals. In the past, different methods have been developed for modelling of the atmospheric pressure effect. These methods use local or two-dimensional (2D) surface atmospheric pressure data and a standard height-dependent air density distribution. The atmospheric pressure effect is consisting of the elastic deformation and attraction term. The deformation term can be well modelled with 2D surface atmospheric pressure data, for instance with the Green's function method. For modelling of the attraction term, three-dimensional (3D) data are required. Results with 2D data are insufficient.From European Centre for Medium-Range Weather Forecasts (ECMWF) 3D atmospheric pressure data are now available. The ECMWF data used here are characterised by a spacing of Δ and Δλ = 0.5°, 60 pressure levels up to a height of 60 km and an interval of 6 h. These data are used for modelling of the atmospheric attraction term. Two attraction models have been developed based on the point mass attraction of air segments and the gravity potential of the air masses. The modelling shows a surface pressure-independent part of gravity variations induced by mass redistribution of the atmosphere in the order of some μgal. This part can only be determined by using 3D atmospheric pressure data. It has been calculated for the Vienna Superconducting Gravimeter site.From this follows that the gravity reduction can be improved by applying the 3D atmospheric attraction model for analysing long-periodic tidal waves including the polar tide. The same improvement is expected for reduction of long-term absolute gravity measurements or comparison of gravity measurements at different seasonal times. By using 3D atmospheric pressure data, the gravity correction can be improved up to some μgal.  相似文献   

Chemical and isotopic equilibrium between CO₂ and CH₄ in fumarolic gas discharges: Generation of CH₄ in arc magmatic-hydrothermal systems     

Jens Fiebig  Giovanni Chiodini  Andrea Rizzo  Johannes C. Hunziker 《Geochimica et cosmochimica acta》2004,68(10):2321-2334

The chemical and isotopic composition of fumarolic gases emitted from Nisyros Volcano, Greece, and of a single gas sample from Vesuvio, Italy, was investigated in order to determine the origin of methane (CH₄) within two subduction-related magmatic-hydrothermal environments.Apparent temperatures derived from carbon isotope partitioning between CH₄ and CO₂ of around 340°C for Nisyros and 470°C for Vesuvio correlate well with aquifer temperatures as measured directly and/or inferred from compositional data using the H₂O-H₂-CO₂-CO-CH₄ geothermometer. Thermodynamic modeling reveals chemical equilibrium between CH₄, CO₂ and H₂O implying that carbon isotope partitioning between CO₂ and CH₄ in both systems is controlled by aquifer temperature.N₂/³He and CH₄/³He ratios of Nisyros fumarolic gases are unusually low for subduction zone gases and correspond to those of midoceanic ridge environments. Accordingly, CH₄ may have been primarily generated through the reduction of CO₂ by H₂ in the absence of any organic matter following a Fischer-Tropsch-type reaction. However, primary occurrence of minor amounts of thermogenic CH₄ and subsequent re-equilibration with co-existing CO₂ cannot be ruled out entirely. CO₂/³He ratios and δ¹³C_CO2 values imply that the evolved CO₂ either derives from a metasomatized mantle or is a mixture between two components, one outgassing from an unaltered mantle and the other released by thermal breakdown of marine carbonates. The latter may contain traces of organic matter possibly decomposing to CH₄ during thermometamorphism.  相似文献   

Upper-mantle reflectors: modelling of seismic wavefield characteristics and tectonic implications     

T. M. Hansen  N. Balling 《Geophysical Journal International》2004,157(2):664-682

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Land uplift near Vatnajökull, Iceland, as observed by GPS in 1992, 1996 and 1999     

Lars E. Sjöberg  Ming Pan  Sigurdur Erlingsson  Erick Asenjo  Kolbeinn Arnason 《Geophysical Journal International》2004,159(3):943-948

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Late Glacial to Holocene coastal changes of SE Rügen Island (Baltic Sea, NE Germany)     

Gösta Hoffmann  Jens Barnasch 《Aquatic Sciences - Research Across Boundaries》2005,67(2):132-141

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Induced seismicity around the Tous New Dam (Spain)   总被引：2，自引：0，他引：2  

Federico Torcal  Inmaculada Serrano  Jens Havskov  José Luis Utrillas  José Valero 《Geophysical Journal International》2005,160(1):144-160

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Difference information criterion for the analysis of a seismotectonic influence on a radon time-series at the KSM site, Japan   总被引：3，自引：0，他引：3  

Jens Hartmann 《Geophysical Journal International》2005,160(3):891-900

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