Used Motor Oil as a Source of MTBE, TAME, and BTEX to Ground Water     

Ronald J. Baker  Eric W. Best  Arthur L Baehr 《Ground Water Monitoring & Remediation》2002,22(4):46-51

Methyl tert-butyl ether (MTBE), the widely used gasoline oxygenate, has been identified as a common ground water contaminant, and BTEX compounds (benzene, toluene, ethylbenzene, and xylenes) have long been associated with gasoline spills. Because not all instances of ground water contamination by MTBE and BTEX can be attributed to spills or leaking storage tanks, other potential sources need to be considered. In this study, used motor oil was investigated as a potential source of these contaminants. MTBE in oil was measured directly by methanol extraction and gas chromatography using a flame ionization detector (GC/FID). Water was equilibrated with oil samples and analyzed for MTBE, BTEX, and the oxygenate tert-amyl methyl ether (TAME) by purge- and-trap concentration followed by GC/FID analysis. Raoult's law was used to calculate oil-phase concentrations of MTBE, BTEX, and TAME from aqueous-phase concentrations. MTBE, TAME, and BTEX were not detected in any of five new motor oil samples, whereas these compounds were found at significant concentrations in all six samples of the used motor oil tested for MTBE and all four samples tested for TAME and BTEX. MTBE concentrations in used motor oil were on the order of 100 mg/L. TAME concentrations ranged from 2.2 to 87 mg/L. Concentrations of benzene were 29 to 66 mg/L, but those of other BTEX compounds were higher, typically 500 to 2000 mg/L.  相似文献   

A faecal sterol survey in the Clyde Estuary     

R. M. Goodfellow  J. Cardoso  G. Eglinton  J. P. Dawson  G. A. Best 《Marine pollution bulletin》1977,8(12):272-276

5β-Stanols, and in particular coprostanol, which is one of the principal sterols of human sewage, show promise as chemical tracers of faecal pollution in estuaries. In the present survey, coprostanol has been measured gas chromatographically in the waters and sediments of the Clyde Estuary. Thus, the bottom sediments contained 0.1–14 ppm of coprostanol (5β-cholestan-3β-ol) together with the corresponding 24-methyl- and 24-ethyl-5β-stanols, while in the seawater samples, the coprostanol concentrations closely paralled the faecal coliform counts. Overall, the amounts of coprostanol correlate well with the location and amounts of the known inputs of sewage from outfalls and dumping.  相似文献   

Corals as speaking stones     

Borel Best  Maya 《Geologie en Mijnbouw》1999,78(2):141-145

Corals are animals living in shallow seas (where they may form coral reefs) or in the deep sea. Because they fossilize well, these stones inform us in detail about the geological past; not only about the history of the Earth as a whole (rotation, tectonics, sea-level changes), but also about past local environmental conditions in the sea. Joint research of marine biology and marine geology can therefore solve many questions about our changing world, and can be used to discover what factors cause deterioration of living coral reefs.  相似文献   

Editorial     

Jim  Best  Chris  Fielding  Ian  Jarvis  Peter  Mozley 《Sedimentology》2002,49(4):643-643

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Case study of compaction grouting for foundation support in karst terrain: Earth and Marine Sciences Building,University of California at Santa Cruz     

Gularte  F. B.  Griffis  R. A.  Kasunich  J. E.  Best  T. C. 《Environmental Geology》1993,22(4):291-295

Sinkholes were discovered during initial construction of a new science building at the University of California, Santa Cruz campus. The occurrence of such classic karst features in California is typically uncommon, although sinkholes have frequently been encountered at the campus during previous construction projects. Subsequent to the sinkhole collapse, geologic and engineering investigations were conducted to determine the size and extent of the collapsed sinkholes and assess the potential for further failure. An exploratory compaction grouting program was developed and implemented in order to locate, fill, and plug voids and to densify loose soils beneath the structure. Eighty-one injection locations were drilled, totaling 1350 m (4429 ft), and 248.2 m³ (324.4 yd³) of low-slump grout was placed. Grout volumes and pressures were carefully monitored, and these data correlated well with lithology determined during grout pipe drilling. Permitted movement on the structure was kept well within the allowable 0.64 cm (0.25 in) using a combination of manometers and laser levels.  相似文献   

Bemerkungen zur Hypothese zweier Sturmzeitringströme     

Armin Grafe  Adolf Best 《Pure and Applied Geophysics》1966,64(1):59-77

Summary For several years the theory of the main phase of geomagnetic storms takes into account the existence of two storm time ring currents which are thought to exist in different altitudes. This hypothesis is supported less by satellite data than by the analysis of recovery effects observed in the geomagnetic records, according to that the recovery phase should exist of two seperate single phases. In our opinion however the observational material seems not convincing enough, especially because material of one station only was used for the hitherto made investigations and no elimination of theSq-part was executed. A critical analysis of the observational material is by all means necessary, especially for the reason that already in literature extensive inferences of theDR2 ring current for the formation and the energy behaviour of theDP part were drawn. For the investigation of recovery effects it is necessary to use additionally to records of equatorial stations those of observatories in higher latitudes. TheSq-part has to be eliminated in the analysis. It is referred that new disturbances after the beginning of the recovery phase can feign two separated ring current effects. Some examples of the recovery phase will be discussed. They show that the observational material gives no necessity for the supposition of two separate strom time ring currents. Furthermore some theoretical considerations are opposite to this hypothesis. The charge exchange with thermical atoms of hydrogen is discussed to be a possible loss process. It is taken into account also the possibility to suppose a wide proton energy spectrum for explaining the recovery phase.

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Mitteilung aus dem Geomagnetischen Institut Potsdam, Nr. 226.  相似文献   

How special are brightest group and cluster galaxies?     

Anja von der Linden  Philip N. Best  Guinevere Kauffmann  Simon D. M. White 《Monthly notices of the Royal Astronomical Society》2007,379(3):867-893

We use the Sloan Digital Sky Survey (SDSS) to construct a sample of 625 brightest group and cluster galaxies (BCGs) together with control samples of non-BCGs matched in stellar mass, redshift and colour. We investigate how the systematic properties of BCGs depend on stellar mass and on their privileged location near the cluster centre. The groups and clusters that we study are drawn from the C4 catalogue of Miller et al. but we have developed improved algorithms for identifying the BCG and for measuring the cluster velocity dispersion. Since the SDSS photometric pipeline tends to underestimate the luminosities of large galaxies in dense environments, we have developed a correction for this effect which can be readily applied to the published catalogue data. We find that BCGs are larger and have higher velocity dispersions than non-BCGs of the same stellar mass, which implies that BCGs contain a larger fraction of dark matter. In contrast to non-BCGs, the dynamical mass-to-light ratio of BCGs does not vary as a function of galaxy luminosity. Hence BCGs lie on a different Fundamental Plane than ordinary elliptical galaxies. BCGs also follow a steeper Faber–Jackson relation than non-BCGs, as suggested by models in which BCGs assemble via dissipationless mergers along preferentially radial orbits. We find tentative evidence that this steepening is stronger in more massive clusters. BCGs have similar mean stellar ages and metallicities to non-BCGs of the same mass, but they have somewhat higher α/Fe ratios, indicating that star formation may have occurred over a shorter time-scale in the BCGs. Finally, we find that BCGs are more likely to host radio-loud active galactic nuclei than other galaxies of the same mass, but are less likely to host an optical active galactic nucleus (AGN). The differences we find are more pronounced for the less massive BCGs, i.e. they are stronger at the galaxy group level.  相似文献   

Deep spectroscopy of distant 3CR radio galaxies: the data     

P. N. Best  H. J. A. Röttgering  M. S. Longair 《Monthly notices of the Royal Astronomical Society》2000,311(1):1-22

Deep long-slit spectroscopic data are presented for a sample of 14 3CR radio galaxies at redshift z ∼1, previously studied in detail using the Hubble Space Telescope , the Very Large Array, and the UK Infrared Telescope (UKIRT). Analysis of the [O  ii ] 3727 emission-line structures at ∼5 Å spectral resolution is carried out to derive the kinematic properties of the emission-line gas. In line with previous lower resolution studies, a wide variety of kinematics are seen, from gas consistent with a mean rotational motion through to complex structures with velocity dispersions exceeding 1000 km s ⁻¹. The data confirm the presence of a high-velocity gas component in 3C 265 and detached emission-line systems in 3C 356 and 3C 441, and show for the first time that the emission-line gas in the central regions of 3C 324 is composed of two kinematically distinct components. Emission-line fluxes and the colour of the continuum emission are determined down to unprecedentedly low observed wavelengths, λ <3500 Å, sufficiently short that any contribution of an evolved stellar population is negligible. An accompanying paper investigates the variation in the emission-line ratios and velocity structures within the sample, and draws conclusions as to the origin of the ionization and kinematics of these galaxies.  相似文献   

Suspended sediment transport and deposition over a dune: Río Paraná, Argentina     

Ray Kostaschuk  Dan Shugar  Jim Best  Dan Parsons  Stuart Lane  Rich Hardy  Oscar Orfeo 《地球表面变化过程与地形》2009,34(12):1605-1611

Field data from the Rio Paraná, Argentina, are used to examine patterns of suspended sediment transport over a sand dune. Measurements of three‐dimensional velocity are made with an acoustic Doppler current profiler whilst suspended sediment concentration and particle size have been quantified using a laser in situ sediment scattering transmissometer. Suspended sediment concentration and streamwise and vertical sediment flux are highest close to the bed, with an upward vertical flux over the stoss side of the dune and downward flux over the lee side. Suspended sediment concentrations are higher over the crest compared with the trough and suspended sediment is coarsest near the bed. About 17% of the suspended‐load transported over the crest is deposited in the lee side before it reaches the trough. Most of this deposited sand is coarser sediment that originates close to the bed over the crest, a result consistent with simulations based on the model of Mohrig and Smith (Water Resources Research 1996; 32: 3207–3217) for the excursion lengths of sediment dispersed in the lee side of a dune. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Experimental verification of the fracture density and shear‐wave splitting relationship using synthetic silica cemented sandstones with a controlled fracture geometry     

Philip Tillotson  Jeremy Sothcott  Angus Ian Best  Mark Chapman  Xiang‐Yang Li 《Geophysical Prospecting》2012,60(3):516-525

We present laboratory ultrasonic measurements of shear‐wave splitting from two synthetic silica cemented sandstones. The manufacturing process, which enabled silica cementation of quartz sand grains, was found to produce realistic sandstones of average porosity 29.7 ± 0.5% and average permeability 29.4 ± 11.3 mD. One sample was made with a regular distribution of aligned, penny‐shaped voids to simulate meso‐scale fractures in reservoir rocks, while the other was left blank. Ultrasonic shear waves were measured with a propagation direction of 90° to the coincident bedding plane and fracture normal. In the water saturated blank sample, shear‐wave splitting, the percentage velocity difference between the fast and slow shear waves, of <0.5% was measured due to the bedding planes (or layering) introduced during sample preparation. In the fractured sample, shear‐wave splitting (corrected for layering anisotropy) of 2.72 ± 0.58% for water, 2.80 ± 0.58% for air and 3.21 ± 0.58% for glycerin saturation at a net pressure of 40 MPa was measured. Analysis of X‐ray CT scan images was used to determine a fracture density of 0.0298 ± 0.077 in the fractured sample. This supports theoretical predictions that shear‐wave splitting (SWS) can be used as a good estimate for fracture density in porous rocks (i.e., SWS = 100ε_f, where ε_f is fracture density) regardless of pore fluid type, for wave propagation at 90° to the fracture normal.  相似文献