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Exsolution and shock microstructures of igneous pyroxene clasts in the Northwest Africa 7533 Martian meteorite 
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下载免费PDF全文 Hugues Leroux Damien Jacob Maya Marinova Roger H. Hewins Brigitte Zanda Sylvain Pont Jean‐Pierre Lorand Munir Humayun 《Meteoritics & planetary science》2016,51(5):932-945
Northwest Africa (NWA) 7533 is a Martian regolith breccia. This meteorite (and its pairings) offers a good opportunity to study (near‐) surface processes that occurred on early Mars. Here, we have conducted a transmission electron microscope study of medium‐ and coarse‐grained (a few tens to hundreds of micrometers) Ca‐rich pyroxene clasts in order to define their thermal and shock histories. The pyroxene grains have a high‐temperature (magmatic) origin as revealed by the well‐developed pigeonite–augite exsolution microstructure. Exsolution lamella characteristics (composition, thickness, and spacing) indicate a moderately slow cooling. Some of the pyroxene clasts display evidence for local decomposition into magnetite and silica at the submicron scale. This phase decomposition may have occurred at high temperature and occurred at high oxygen fugacity at least 2–3 log units above the QFM buffer, after the formation of the exsolution lamellae. This corresponds to oxidizing conditions well above typical Martian magmatic conditions. These oxidizing conditions seem to have prevailed early and throughout most of the history of NWA 7533. The shock microstructure consists of (100) mechanical twins which have accommodated plastic deformation. Other pyroxene shock indicators are absent. Compared with SNC meteorites that all suffered significant shock metamorphism, NWA 7533 appears only mildly shocked. The twin microstructure is similar from one clast to another, suggesting that the impact which generated the (100) twins involved the compacted breccia and that the pyroxene clasts were unshocked when they were incorporated into the NWA 7533 breccia. 相似文献
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Uta Passow Megan A. French Maya Robert 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(12):1147-1157
The majority of opal produced by diatoms dissolves during their sedimentation to the seafloor, but spatial and temporal variability of dissolution rates are large. Controlled laboratory experiments using live phytoplankton or phyto-detritus may help identify the different processes, including those that are biologically mediated or physico-chemically driven, that impact the dissolution of frustules and the aforementioned variability. Results of eight bSiO2 dissolution experiments, seven of which were conducted at low temperatures (<6 °C) are presented within the context of earlier similar studies, and different phases of dissolution dynamics characterized. TEP concentration, aggregation and the physiological status of the diatoms determined the period during which diatoms may maintain the protective membrane that surrounds their frustule and effectively reduces or completely inhibits (lag period) dissolution for some time. Once diatoms loose the capability to maintain their protective membrane, bacterial activity compromises it. Physico-chemical dissolution, which depends on frustule structure and abiotic environmental conditions, begins once the protective membrane is damaged. The ability of diatoms to maintain their membrane, the bacterial composition and activity governing its degradation, and the physico-chemical dissolution dynamics of exposed frustules are all impacted by temperature. In our experiments instantaneous dissolution rates were not dependant on bSiO2 concentration at low temperatures, although such a relationship was observed under otherwise identical conditions at 15 °C, implying that biotic factors rather than physico-chemical processes initially dominated dissolution at polar temperatures. Since inhibition of bSiO2 dissolution at low temperatures was inhibited to a greater extent than organic matter degradation, we postulate that it was not reduced bacterial activity but the enhanced ability of diatoms to maintain their membrane and thus withstand microbial attack that caused the low initial dissolution rates at <6 °C. In situ, interactions between the different biotic and abiotic processes impacting dissolution combined with differences in sinking velocity of diatom aggregates and grazing effects could easily explain high spatial and temporal variability in the accumulation of diatoms on the seafloor. Simple calculations based on our experimental results suggest that Fragilariopsis kerguelensis, for example, would be appreciably more likely to reach the seafloor than Chaetoceros debilis if both grow at low growth rates, e.g. under growth limiting conditions. However, dissolution behavior of Chaetoceros debilis during sedimentation may differ under conditions where this species forms large blooms. 相似文献
3.
Jean-Robert Disnar Maya Stefanova Jean-Gabriel Bréhéret Jean-Jacques Macaire 《Organic Geochemistry》2011,42(9):1089-1098
The Sarliève marsh in the Limagne plain, in the heart of the French Massif Central, functioned as an endorheic lake during the Late Glacial and the Early and Middle Holocene. During the Late Boreal and the Atlantic it experienced drastic lowering of the water level as a result of dry and warm climatic episodes. Then, pre-evaporitic conditions triggered the deposition of sediment rich in organic matter (OM) and in carbonates including dolomite. Fifty-one samples from a ca. 1.8 m sediment core section covering the period were analysed using Rock–Eval pyrolysis and gas chromatography–mass spectrometry (GC–MS). Throughout the interval, the OM content remained notable to high [up to 13.35% total organic carbon (TOC)] and of good quality as indicated by low oxygen index (OI) values (<200 mg CO2 g−1 TOC) and high hydrogen index (HI) values (160–660 mg HC g−1) which, as a rule, increased with increasing TOC content.In contrast to the acid fractions, which sometimes contained notable proportions of n-C16 or n-C18 fatty acids (FAs; analysed as the methyl esters, FAMEs), the neutral fractions were almost devoid of low molecular weight compounds. The latter were probably biodegraded during early diagenesis. Conversely, high molecular weight compounds were abundant in both fractions and were dominated by n-alkanols, n-alkanes, steroids and hopanoids in the neutrals and even numbered FAs and hopanoids in the acid fractions. The hopanoids were dominated by regular bishomohopanoids, accompanied by 2-methylated bishomohopanoids, as well as by unidentified bishomohopanoids with methylation in either the D or E ring. These distributions, typical for bacteria, provide support for previous hypotheses on the contribution of microorganisms to the studied record and for providing conditions for the precipitation and growth of dolomite and other pristine carbonate minerals [Bréheret, J.G., Fourmont, A., Macaire, J.J., Négrel, Ph., 2008. Microbially mediated carbonates in the Holocene lacustrine deposits of the Marais de Sarliève (French Massif Central) testify to the evolution of a restricted environment. Sedimentology 55, 557–578]. The preservation of the compounds was probably ensured by persistent reducing conditions during diagenesis, despite variable climatic conditions and related changes in lake level and sedimentation rate. Comparable distributions of hopanoic acids and hopanols, as well as roughly parallel variation with depth in the corresponding components in both fractions, strongly suggest that all the hopanoids derive from the same microbial precursors, slight shifts in the acid/alcohol ratio being governed by limited changes in redox conditions during early diagenesis. 相似文献
4.
Mineral inclusions in fibrous diamonds: constraints on cratonic mantle refertilization and diamond formation 总被引：1，自引：0，他引：1
We analyzed mineral microinclusions in fibrous diamonds from the Wawa metaconglomerate (Superior craton) and Diavik kimberlites (Slave craton) and compared them with published compositions of large mineral inclusions in non-fibrous diamonds from these localities. The comparison, together with similar datasets available for Ekati and Koffiefontein kimberlites, suggest a general pattern of metasomatic alteration imposed on the ambient mantle by formation of fibrous diamond. Calcium and Fe enrichment of peridotitic garnet and pyroxenes and Fe enrichment of olivine associated with fibrous diamond-forming fluids contributes to refertilization of the cratonic mantle. Saline—carbonatitic—silicic fluid trapped by fibrous diamonds may represent one of the elusive agents of mantle refertilization. Calcium enrichment of peridotitic garnet and pyroxenes is expected in local mantle segments during fibrous diamond production, as Ca in the carbonatitic fluids is deposited into the surrounding mantle when oxidized carbon is reduced to diamond. Harzburgitic garnet evolves towards Ca-rich compositions even when it interacts with Ca-poor saline fluids. An unusual trend of Mg enrichment to Fo95–98 is observed in some olivine inclusions in Wawa fibrous diamonds. The trend may result from the carbonatitic composition of the fluid that promotes crystallization of magnesian olivine and preferentially oxidizes the fayalite component. We propose a generic model of fibrous and non-fibrous diamond formation from carbonatitic fluids that explains enrichment of the mantle in mafic magmaphile and incompatible elements and accounts for locally metasomatized compositions of diamond inclusions. 相似文献
5.
Maya P. Bhatt William H. McDowell Kevin H. Gardner Jens Hartmann 《Environmental Earth Sciences》2014,71(2):911-922
Water quality in less-developed countries is often subject to substantial degradation, but is rarely studied in a systematic way. The concentration and flux of major ions, carbon, nitrogen, silicon, and trace metals in the heavily urbanized Bagmati River within Kathmandu Valley, Nepal, are reported. The concentrations of all chemical species increased with distance downstream with the exceptions of protons and nitrate, and showed strong relationships with population density adjacent to the river. Total dissolved nitrogen (TDN), dominated by NH4, was found in high concentrations along the Bagmati drainage system. The export of dissolved organic carbon (DOC) and TDN were 23 and 33 tons km?2 year?1, respectively, at the outlet point of the Kathmandu Valley, much higher than in relatively undeveloped watersheds. The cationic and silica fluxes were 106 and 18 tons km?2 year?1 at the outlet of the Bagmati within Kathmandu Valley, and 36 and 32 tons km?2 year?1 from the relatively pristine headwater area. The difference between headwaters and the urban site suggests that the apparent weathering flux is three times higher than the actual weathering rate in the heavily urbanized Bagmati basin. Fluxes of cations and silica are above the world average, as well as fluxes from densely populated North American and European watersheds. End-member composition of anthropogenic sources like sewage or agricultural runoff is needed to understand the drivers of this high rate of apparent weathering. 相似文献
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Natural Hazards - Collapse of residential buildings is the major cause of death during earthquakes. Seismic retrofitting of residential buildings is a cost-effective way to reduce injury and death.... 相似文献
8.
Axelle Bouiges Amir Yassin Maya Ikogou Clément Lelarge Axelle-Rolande Sikoa Stefano Mona Michel Veuille 《Comptes Rendus Geoscience》2013,345(7-8):297-305
Previous genetic studies showing evidence of past demographic changes in African drosophilids suggested that these populations had strongly responded to Quaternary climate changes. We surveyed nine species of Zaprionus, a drosophilid genus mostly present in Africa, in forests located between southern Senegal and Gabon. The mitochondrial COI gene showed contrasted levels of sequence variation across species. Populations of the only cosmopolitan species of the genus, Z. indianus, and of its closely related sibling species, Z. africanus, are highly polymorphic and appear to have undergone a continuous population expansion beginning about 130,000 years ago. Five less variable species probably underwent a population expansion beginning only about 20,000–30,000 years ago. One of them, Z. taronus, was significantly structured between forest blocks. The last two species were nearly monomorphic, probably due to infection by Wolbachia. These results are similar to those obtained in three species from the melanogaster subgroup, and may be typical of the responses of African drosophilid populations to glacial cycles. 相似文献
9.
Cesar Villanoy Laura David Olivia Cabrera Michael Atrigenio Fernando Siringan Porfirio Aliño Maya Villaluz 《Climatic change》2012,112(2):493-505
Coral reefs and other coastal ecosystems such as seagrasses and mangroves are widely recognized to provide protection against
the devastating effects of strong waves associated with tsunamis and storms. The predicted warming climate brings to fore
the role of these ecosystems in providing protection against stronger typhoons that can result in more devastating waves of
greater amplitude. We performed a model simulation of storm generated waves on a Philippine reef, which is located along the
path of tropical storms, i.e., at least 10 typhoons on the average pass through the study site yearly. A model to simulate
wave propagation was developed using Simulating Waves Nearshore (SWAN) and DELFT3D-WAVE computer simulation software. Scenarios
involving local monsoonal wind forcing and storm conditions were simulated. In addition, as climate change may also result
to increased relative sea level, a 0.3 m and 1 m rise in sea level scenarios were also used in the wave model simulations.
Results showed that the extensive reef system in the site helped dissipate wave energy that in turn reduced wave run-up on
land. A significant reduction in wave energy was observed in both climate change, i.e., stronger wind and higher sea level,
and non-climate change scenarios. This present study was conducted in a reef whose coral cover is in excellent condition (i.e.,
50 to 80% coral cover). Estimates of coral reef growth are in the same order of magnitude as estimates of relative sea level
rise based on tide gauge and satellite altimeter data, thus it is possible that the role of reefs in attenuating wave energy
may be maintained if coral reef growth can keep up with the change in sea level. Nonetheless, to maintain reef growth, it
is imperative to manage coral reef ecosystems sustainably and to eliminate the stressors that are within human control. Minimizing
activities such as illegal and destructive blast and poison fishing methods, pollution and siltation, is crucial to minimize
the impacts of high-energy waves that may increase with climate change. 相似文献
10.
Variation in DOC and trace metal concentration along the heavily urbanized basin in Kathmandu Valley,Nepal 总被引：1，自引：0，他引：1
Water samples were analyzed for DOC and trace metals from Bagmati River within Kathmandu valley, Nepal, to understand the
variation trends of DOC and trace metals and their relationship along the drainage network. The variability in organic matter
and wastewater input within the Bagmati drainage basin appeared to control DOC and most of the trace metal concentration.
The large input of organic matter and wastewater creates anoxic condition by consuming dissolved oxygen and releasing higher
concentrations of DOC, trace elements such as nickel, arsenic, barium, cadmium, and copper with downstream distance. Concentrations
of DOC and trace metals like barium and zinc showed strong relationships with human population density and suggest that human
activities have strong control on these parameters along the drainage network. The DOC and most of the trace metal concentration
increased with downstream distance and appeared to be directly associated with human activities. The variation trends of most
of the trace metals appeared to be the same; however, concentration varied widely. Inputs of organic matter and wastewater
due to human activities appeared directly to be associated for the variation of DOC and trace metals along the Bagmati drainage
network within Kathmandu valley. 相似文献