Dissolution of calcitic marble and dolomitic rock in high iron concentrated acid mine drainage: application to anoxic limestone drains     

Thomas Genty  Bruno Bussière  Robin Potvin  Mostafa Benzaazoua  Gérald J. Zagury 《Environmental Earth Sciences》2012,66(8):2387-2401

Oxidation of sulphide mining waste can generate acid mine drainage (AMD) that has the potential to seriously affect the ecosystems. Acid mine drainage is characterised by a high acidity, high concentrations of sulphates and metals. To reduce the environmental impacts due to AMD, neutralisation using limestone drains is an option proposed in the literature and used around the world. The present study focuses on the influence of the carbonate rock mineralogy and their particle size on the neutralising capacity. The tests were performed in two different anoxic conditions: in batch reactors, and in columns having a hydraulic retention time of 15?h. The results showed that the neutralisation capacity of calcite was more important than for dolomitic rock, and smaller particle size gave higher alkalinity production (fine calcite dissolved faster in contact with AMD). A characterization of metal precipitate in sludge and in limestone coating was performed and demonstrated that gypsum, lepidocrocite and goethite were the predominant secondary minerals to be formed. Finally, this study underlines that anoxic limestone drain cannot be used alone to treat high iron concentrated AMD.  相似文献   

Combining a Detailed Building Energy Model with a Physically-Based Urban Canopy Model     

Bruno Bueno  Leslie Norford  Grégoire Pigeon  Rex Britter 《Boundary-Layer Meteorology》2011,140(3):471-489

A scheme that couples a detailed building energy model, EnergyPlus, and an urban canopy model, the Town Energy Balance (TEB), is presented. Both models are well accepted and evaluated within their individual scientific communities. The coupled scheme proposes a more realistic representation of buildings and heating, ventilation and air-conditioning (HVAC) systems, which allows a broader analysis of the two-way interactions between the energy performance of buildings and the urban climate around the buildings. The scheme can be used to evaluate the building energy models that are being developed within the urban climate community. In this study, the coupled scheme is evaluated using measurements conducted over the dense urban centre of Toulouse, France. The comparison includes electricity and natural gas energy consumption of buildings, building façade temperatures, and urban canyon air temperatures. The coupled scheme is then used to analyze the effect of different building and HVAC system configurations on building energy consumption, waste heat released from HVAC systems, and outdoor air temperatures for the case study of Toulouse. Three different energy efficiency strategies are analyzed: shading devices, economizers, and heat recovery.  相似文献   

复合火山构造的高分辨率岸上地震成像:意大利武尔卡诺岛例子     

P.P.G.Bruno  A.Castiello  邵玉平 《世界地震译丛》2011,(3)

火山口地下构造详细的地震成像对于增进这些高危险火山的构造和火山学的知识是必不可少的。然而,在火山地带,尤其是在岸上,很难获得高质量的地震数据。我们报道了拉福萨火山口(意大利武尔卡诺岛)西部地区的高分辨率地震剖面结果。利用高分辨率的振动源及交替采集和处理技术,我们能够克服由火山煤岩类型带来的大多数困难。本研究提供了火山堆积的地下分布和一些重要内部喷火山口构造的识别。我们确定了埋于拉福萨火山口下面的寄生火山口或玄武碎屑岩丘的位置,它在约1km的深度记录到地震的地方正在消散CO2。此外,在剖面最南部发现的变形模式与穹隆侵入后破火山口塌陷是一致的。结果表明,使用高分辨率振动源结合交替地震采集技术和非常规处理方法,可以帮助恢复火山地区浅层构造的详细信息。  相似文献   

Instability structures, synsedimentary faults and turbidites, witnesses of a Liassic seismotectonic activity in the Dauphiné Zone (French Alps): A case example in the Lower Pliensbachian at Saint-Michel-en-Beaumont     

Franoise Bergerat  Pierre-Yves Collin  Anne-Cline Ganzhorn  Franois Baudin  Bruno Galbrun  Isabelle Rouget  Johann Schnyder 《Journal of Geodynamics》2011,51(5):344-357

Instability structures, synsedimentary faults and turbidites have been studied in the Lower Pliensbachian succession of Saint-Michel-en-Beaumont, belonging to the Taillefer block, an ancient half-graben emplaced during the Liassic Tethyan rifting. Geometrical and mechanical analyses demonstrate that the instability structures occurred thanks to movements along spineless synsedimentary normal faults, when the turbiditic and limestone layers were already case-hardened and partly fractured by tension gashes even when the mudstones were still unlithified. Both the tension gashes and the synsedimentary faults are homogeneous in strike with the major regional faults and are in good agreement with the regional direction of extension for this period. The characters of the turbiditic beds, with erosive base, graded bedding, and incomplete Bouma sequence, are in favour of a seismic origin. Instability structures, spineless synsedimentary faults and turbiditic inflows are thus considered as seismites and interpreted as the result of high seismicity periods including some events with M > 5 in the general extensive ambiance of the Liassic Tethyan rifting. The analysis of the geometrical relationships between all these sedimentary features allows to distinguish the successive stage of occurrence of an instability structure, from the sedimentation of alternating marls and limestones, and sudden turbiditic inflows, then early case-hardening of the turbidites, until the important seismotectonic event generating the spineless normal faults, themselves triggering the fall of indurated blocks and locally the forming of breccias. The Ornon Fault, which constitutes the border of the Taillefer block, 15 km eastward, played a major role during the Liassic sedimentation and may represent the major seismic fault related to the seismites occurrence in the Beaumont basin.  相似文献   

Response of the geomagnetic activity to solar wind turbulence during solar cycle 23     

R. D’Amicis  R. Bruno  B. Bavassano 《Journal of Atmospheric and Solar》2011,73(5-6):653-657

The solar wind–magnetosphere coupled system is characterized by dynamical processes. Recent works have shown that nonlinear couplings and turbulence might play a key role in the study of solar wind–magnetosphere interaction processes.Within this framework, this study presents a statistical analysis aimed to investigate the relationship between solar wind MHD turbulence and geomagnetic activity at high and low latitudes as measured by the AE and SYM-H indices, respectively. This analysis has been performed for different phases of solar cycle 23. The state of turbulence was characterized by means of 2-D histograms of the normalized cross-helicity and the normalized residual energy. The geomagnetic response was then studied in relation to those histograms.The results found clearly show that, from a statistical point of view, solar cycle 23 is somewhat peculiar. Indeed, good Alfvénic correlations are found unexpectedly even during solar activity maximum. This fact has implications on the geomagnetic response as well since a statistical relationship is found between Alfvénic fluctuations and auroral activity. Conversely, solar wind turbulence does not seem to play a relevant role in the geomagnetic response at low latitudes.  相似文献   

Multiplatform observation of the surface circulation in the Gulf of Naples (Southern Tyrrhenian Sea)   总被引：1，自引：1，他引：0  

Marco Uttieri  Daniela Cianelli  Bruno Buongiorno Nardelli  Berardino Buonocore  Pierpaolo Falco  Simone Colella  Enrico Zambianchi 《Ocean Dynamics》2011,61(6):779-796

The Gulf of Naples (Southern Tyrrhenian Sea) is a highly urbanised area, where human activities and natural factors (e.g. river runoff, exchanges with adjacent basins) can strongly affect the water quality. In this work we show how surface transport can influence the distribution of passively drifting surface matter, and more in general if and how the circulation in the basin can promote the renovation of the surface layer. To this aim, we carried out a multiplatform analysis by putting together HF radar current fields, satellite images and modelling tools. Surface current fields and satellite images of turbidity patterns were used to initialise and run model simulations of particle transport and diffusion. Model results were then examined in relation to the corresponding satellite distributions. This integrated approach permits to investigate the concurrent effects of surface dynamics and wind forcing in determining the distribution of passive tracers over the basin of interest, identifying key mechanisms supporting or preventing the renewal of surface waters as well as possible areas of aggregation and retention.  相似文献   

Vegetated filter effects on sedimentological connectivity of agricultural catchments in erosion modelling: a review   总被引：3，自引：0，他引：3  

Silvio Jose Gumiere  Yves Le Bissonnais  Damien Raclot  Bruno Cheviron 《地球表面变化过程与地形》2011,36(1):3-19

  相似文献   

Delivery and deposition of organic matter in surface sediments of Lagoa do Caçó (Brazil)     

Abdelfettah Sifeddine  Renato Campello Cordeiro

  Ana Luiza S. Albuquerque
  Marcelo Bernardes
  Bruno Turcq
  Jorge João Abrão
《Journal of Paleolimnology》2011,45(3):385-396

Elemental and isotopic compositions of organic matter in surficial sediments from five transects across Lagoa do Caçó (Brazil) were analyzed to identify the depth-related processes that affect the production and deposition of sedimentary organic matter in this shallow tropical lake. Each of four transverse transects began at a margin dominated by aquatic macrophytes (Eleocharis), crossed the central deep part of the lake, and terminated in the opposite, macrophyte-dominated margin. In each transect, TOC concentrations, C/N ratios, and δ¹³C values decreased between 0 and 4 m, whereas δ¹⁵N values increased. The variables remained stable in sediment from 4 m water depth to the center of the lake at 10 m. The depth-related patterns reflect differences in both the delivery and the deposition of organic matter in the lake. Organic matter is produced in abundance in the marginal area by emersed and submerged macrophyte vegetation that diminishes with depth and disappears at 4 meters. After the disappearance of macrophytes, organic matter is produced at low rates principally by open-lake phytoplankton. Drawdown of dissolved oxygen is high in the lake margins, but it is low in the oligotrophic open waters of the lake. Preservation of organic matter is consequently better in sediments of the lake margins than in deep waters. The depth-related pattern of organic matter delivery and deposition in the sediments of Lagoa do Caçó, in which water levels are sensitive to groundwater fluctuations, shows that the elemental and isotopic compositions of sediment organic matter can provide a record of changes in the paleohydrology of this and other similar shallow lake systems.  相似文献   

Changes in Nutrient Biogeochemistry in Response to the Regression of Zostera noltii Meadows in the Arcachon Bay (France)     

Marie-Lise Delgard  Bruno Deflandre  Jonathan Deborde  Marion Richard  Céline Charbonnier  Pierre Anschutz 《Aquatic Geochemistry》2013,19(3):241-259

From 1989 to 2007, a severe decline in Zostera noltii meadows was reported in the Arcachon Bay, with an accelerated regression after 2005. We investigated the inter-annual variability of the biogeochemistry of the sediment in an area affected by seagrass decline. In late summer and in winter of the years 2006, 2010, and 2011, sediment cores were collected at low tide on vegetated and adjacent non-vegetated sediments located in the eastern part of the Arcachon Bay. The geochemical analyses of sediment solid-phase organic carbon, reactive P and Fe, and the pore water concentrations of Fe²⁺, DIP, and NH₄ ⁺ are presented. The changes in the chemistry of sediment and pore water between 2006 and 2010 are interpreted as a consequence of the decrease in the Z. noltii biomass between 2006 and 2010. The absence of significant seasonal variations in biomass throughout the growth period (March–September) in 2011 is most likely related to the regression of Z. noltii meadow that strongly affects the study area. In contrast to the healthy meadow in 2006, the declining meadow favored the dissolution of sedimentary particulate phosphorus in winter. In late summer, the low biomass of seagrass resulted in a net release of ammonium in the pore water of the upper 20 cm of sediment. This study clearly shows that seagrass decay may enhance nutrient release in sediments, resulting in a significant supply of phosphorus to the water column of a magnitude comparable to annual inputs to the lagoon from the rivers and the tidal pump.  相似文献   

Isotopic and geochemical characterization of salinization in the shallow aquifers of a reclaimed subsiding zone: The southern Venice Lagoon coastland   总被引：3，自引：0，他引：3  

Julie C. Gattacceca  Christine Vallet-Coulomb  Adriano Mayer  Christelle Claude  Olivier Radakovitch  Enrico Conchetto  Bruno Hamelin   《Journal of Hydrology》2009,378(1-2):46-61

The coastal plain bordering the southern Venice Lagoon is a reclaimed lowland characterized by high subsidence rate, and ground level and water-table depth below sea level. In this agricultural region, where the surface hydrologic network is entirely artificially controlled by irrigation/drainage canals, salinization problems have long been encountered in soils and groundwaters. Here we use isotopic and geochemical tracers to improve our understanding of the origin of salinization and mineralization of the semi-confined aquifer (0–40 m), and the freshwater inputs to this hydrological system. Water samples have been collected at different seasons in the coastal Adriatic Sea, lagoon, rivers and irrigation canals, as well as in the semi-confined aquifer at depths between 12 and 35 m (14 boreholes), and in the first confined aquifer (three boreholes drilled between 40 and 80 m depth). Stable isotopes (δ¹⁸O and δD) and conductivity profiles show that direct saline intrusion from the sea or the lagoon is observed only in a restricted coastal strip, while brackish groundwaters are found over the entire topographic and piezometric depression in the centre of the study area. Fresh groundwaters are found only in the most western zone. The sharp isotopic contrast between the western and central regions suggests disconnected hydrological circulations between these two parts of the shallow aquifer. The border between these two regions also corresponds to the limits of the most strongly subsiding zone.Our results can be interpreted in terms of a four end-member mixing scheme, involving (1) marine water from the lagoon or the open sea, (2) alpine and pre-alpine regional recharge waters carried either by the main rivers Adige, Bacchiglione and Brenta (irrigation waters) or by the regional groundwater circulation, (3) local precipitation, and (4) evaporated waters infiltrated from the surface. Infiltration from the surface is also revealed by the stratification of the electrical conductivity profiles, showing that the brackish groundwaters are overlain by a shallow layer of less saline water all over the central depression. In the first confined aquifer, the groundwaters have isotopic compositions similar to the deep groundwaters of the Venetian confined aquifers (40–400 m depth). The isotopic data and the Br/Cl ratio show that the origin of the salinization of the phreatic aquifer can be ascribed to seawater intrusion alone, with no indication of the involvement of deep brines (identified at 450 m depth) in the process.The chemical composition of the saline and brackish groundwaters is characterized by an excess of sodium and a deficit of calcium compared to conservative mixing between fresh groundwaters and seawater. This suggests that the phreatic aquifer is progressively freshening, as a consequence of the beneficial influence of the extensive irrigation/drainage network, including raised canals acting as a hydraulic barrier along the coast. This freshening tendency may have been lasting since the reclamation in the mid-twentieth century, and has probably been accelerated by the ban on groundwater abstraction since the 1970s.  相似文献