Chemical and isotopic signatures of the basement rocks from the Campi Flegrei geothermal field (Naples, southern Italy): inferences about the origin and evolution of its hydrothermal fluids     

Graziella Caprarelli  Makoto Tsutsumi  Bruno Turi 《Journal of Volcanology and Geothermal Research》1997,76(1-2)

The Campi Flegrei (Naples, Campanian Plain, southern Italy) geothermal system is hosted by Quaternary volcanic rocks erupted before, during and after the formation of the caldera that represents one of the major structural features in the Neapolitan area. The volcanic products rest on a Mesozoic carbonate basement, cropping out north, east and south of the area. Chemical (major, minor and trace elements) and stable isotope (C, H, O) analyses were conducted on drill-core samples recovered from geothermal wells MF-1, MF-5, SV-1 and SV-3, at depths of ˜ 1100 to 2900 m. The study was complemented by petrographic and SEM examination of thin sections. The water which feeds the system is both marine and meteoric in origin. Mineral zonation typical of a high-temperature geothermal system exists in all the geothermal wells; measured temperatures in wells are as high as ˜ 400 °C. The chemical composition of the waters suggests the existence of two reservoirs: a shallow reservoir (depth < 2000 m) fed by seawater that boiled at 320 °C and became progressively diluted by steam-heated local meteoric water during its ascent; and a deeper reservoir (depth > 2000 m) of hypersaline water. The drill-cores are mainly hydrothermally altered volcanics of trachy-latitic affinity, but some altered pelites and limestones are also present. Published Na, Mg and K concentrations of selected geothermal waters indicate that the hydrothermal fluids are in equilibrium with their host rocks, with respect to K-feldspar, albite, sericite and chlorite. The measured δ¹⁸O_(SMOW) values of rocks range from +4.3 to + 16.5%. The measured δD_(SMOW) values range from − 79 to − 46%. The calculated isotopic composition of the fluids at equilibrium with the samples vary from + 1 to + 8.3%. δ¹⁸O and from − 52 to + 1%. δD. The estimated isotopic composition of the waters at equilibrium with the studied samples confirmed the existence of two distinct fluid types circulating in the geothermal system. The shallower has a marine water signature, while the deeper water has a signature consistent both with magmatic and meteoric origins. In the latter case, the recharge of this aquifer likely occurs at the outcrop of the Mesozoic Limestones surrounding the Campanian Plain; after infiltration, the water percolates through evaporitic layers, becoming hypersaline and D-depleted.  相似文献   

Theoretical variability of s1 in the tide generating potential     

J. J. Alonso  M. Bruno  R. Mañanes 《Ocean Dynamics》1997,49(4):457-466

Summary The S₁ tidal wave arising from the second order tidal potential occurs in any geophysical data record. Since the frequency of S₁ is the same as that of earth’s rotation, many distortions are observed in real data sets. To isolate S₁ from its powerful neighbours,K ₁ and P₁ at least one-year hourly data series are required. Studies onS ₁ on an experimental basis, have been aimed mainly at a precise determination of its origin and mechanisms of variability. There are many hypotheses on its variability. In physical oceanography it is commonly accepted that the variability of S₁ is due to air-sea interaction processes. The authors review most existing hypotheses on the variability of S₁ They also show that the distortions of real data must be expected due to additional contributions from the second and third-order lunar potentials. An analysis is made to detect the sources of the additional contributions to the S₁ frequency.

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Theoretische schwankung der s 1 im gezeitenerzeugenden potential TIPAB-95

Zusammenfassung Die Gezeitenwelle (Partialtide) S₁ ist in jedem Datensatz gegenw?rtig, der unter dem Einfluβ der Gezei tenkr?fte aufgezeichnet wurde. Ihre Quelle ist das sonnent?gliche Gezeitenpotential zweiter Ordnung. Die Frequenz S₁ stimmt mit der der Erdrotation überein. In den beobachteten Datens?tzen treten aber viele St? rungen auf. Wenigstens ein Jahr stündlicher Beobachtungen ist erforderlich, um die S₁ von ihren beiden m?chtigen Nachbarn, n?mlich derK ₁ und P₁ ,trennen zu k?nnen. In l?ngeren Beobachtungsreihen tritt sie klar in Erscheinung. Viele Arbeiten über die S₁ haben sich damit besch?ftigt, ihren Ursprung und die Quelle ihrer Ver?nde rung genau zu bestimmen. Es wurden aber auch viele Hypothesen hinsichtlich der in den Beobachtungen vorgefundenen St?rungen aufgestellt. In dieser Arbeit wird eine neue Hypothese, die Ver?nderlichkeit der S₁ betreffend, aufgezeigt, deren Grundlage die theoretische Entwicklung “TIPAB-95” des gezeitenerzeugenden Potentials ist.

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Magnetostratigraphy of the Toarcian stratotype sections at Thouars and Airvault (Deux-Sèvres, France)     

Bruno Galbrun  Jean Gabilly  Lopold Rasplus 《Earth and Planetary Science Letters》1988,87(4)

Magnetostratigraphic study of the Toarcian type sections of Thouars and Airvault (Deux-Sèvres, France) has yielded two reliable magnetic polarity sequences. Most samples were treated by mixed cleaning: thermal demagnetization (250°, 300° or 350°C) and subsequent alternating field demagnetization. Polarity intervals are easily identified and correlate well between the two sections using the biostratigraphic data provided by the detailed standard ammonite zonation of the Toarcian stage. The polarity sequence extends from ammonite horizon V (Pseudoserpentinum horizon,Serpentinus zone) to horizon XXV (Subcompta horizon,Aalensis zone); it shows 5 reversed and 5 normal polarity magnetozones.  相似文献   

Experimental transport of Si,Al and Mg in hydrothermal solutions: an application to vein mineralization during high-pressure,low-temperature metamorphism in the French Alps     

Bruno Goffé  William M. Murphy  Martine Lagache 《Contributions to Mineralogy and Petrology》1987,97(4):438-450

A study of hydrothermal vein mineralization in meta-argillites subjected to high-pressure, low-temperature metamorphism reveals that ferromagnesian (e.g., chlorite) and pure aluminosilicate (e.g., pyrophyllite) mineralization can be correlated with regimes of increasing and decreasing temperature, respectively. An experimental study of the transport of silica, aluminum and magnesium in hydrothermal solutions has been undertaken to simulate variations in the physical conditions during metamorphism and the accompanying mass transport in a closed system. Thermodynamic and kinetic analysis of the experimental results indicates that local equilibrium among aqueous and mineral phases controls the distribution and composition of hydrothermal vein mineralization and that vein mineralogy can be used to infer the sense of variation of pressure and temperature during metamorphism.  相似文献   

Average structure and M2 site configurations in C2/c clinopyroxenes along the Di-En join     

M. Tribaudino  P. Benna  E. Bruno 《Contributions to Mineralogy and Petrology》1989,103(4):452-456

In order to clarify the structural configurations observed in Di_ss in the Ca-rich region of the Di-En join (in which TEM observations show neither exsolution microstructures nor evidence of spinodal decomposition) single crystals large enough for X-ray diffraction analyses, with composition (Ca_0.66Mg_0.34)MgSi₂O₆, have been equilibrated close to the solvus atT=1350° C for 317 h, and quenched at room temperature. The refinement in C2/c space group shows that in the M2 site Ca and Mg are fully ordered in two split positions (M2_occ: 0.66 Ca; M2_occ: 0.34 Mg). Since the average structure shows a relevant elongation of anisotropic thermal ellipsoids of the O2 and O3 oxygen atoms, the refinement has been carried out according to a split model for O2 and O3 atoms: Ca appears 8-coordinated (as in diopside) and Mg shows a sixfold coordination similar to that of high-pigeonite. This coordination for Mg is significantly different from the fourfold coordination (Zn-like in Zn-cpx) proposed previously and it is a more probable coordination for Mg from a crystalchemical point of view. The same results were obtained refining a Di₈₀En₂₀ cpx, equilibrated atT=1230° C, according to the same O-split model. The data support the coexistence of a Di-like configuration for Ca and of a highPig-like configuration for Mg away from the solvus also. AtT very near toT _solidus the different configurations, observed at room temperature in the quenched samples, should converge and Ca and Mg should retain a single disordered configuration in the M2 site.  相似文献   

Precise lead isotope measurements by the double spike technique: A reconsideration   总被引：1，自引：0，他引：1  

Bruno Hamelin  Gérard Manhes  Francis Albarede  Claude J. Allègre 《Geochimica et cosmochimica acta》1985,49(1):173-182

A reappraisal of the “Double Spike Method” for correction of the mass discrimination in lead isotope analysis is presented in view of the possible efficiency of this method, especially as related to the improved performance of the new multi-collector mass spectrometers.First, the effects of mass discrimination during lead isotope analysis, using the silica-gel phosphoric acid method, are discussed in order to verify the validity of the linear discrimination law. In this discussion, we give evidence of a slight bias of the isotopic composition of the SRM 981 NBS lead standard, commonly used for mass discrimination calibrations.A rigorous way to deal with the propagation of the within-run statistical errors on the precision of the double spike correction is then presented. This allows the optimization of the parameters of the method (spike isotopic composition and precision, spiking proportion) and the calculation of the respective error associated with each corrected isotopic ratio. The perturbation of the double spike correction due to analytical contamination, which has caused previous failure in the application of the method, is avoided by preparation of the mixture between the spike and the sample at the very end of the chemical separation procedure.Using a single collector mass spectrometer, examples of application on lead standards and on a set of samples suggest a possible improvement in the precision by a factor of 3 compared to the usual method of fractionation normalization and confirm the usefulness of the method with the new generation of mass spectrometers.  相似文献   

Modelling seasonal variations in nitrate and sulphate concentrations in a vulnerable alluvial aquifer     

Luk Peeters  Bruno Haerens  Jan Van der Sluys  Alain Dassargues 《Environmental Geology》2004,46(6-7):951-961

The Eisden–Meeswijk region in Belgium has been affected by mining subsidence due to the deep coal mining activities. Groundwater levels in the alluvial plain of the Meuse River are maintained below the ground surface by drainage installations and municipal well fields. A correlation between the water level in the Meuse River and the variation in nitrate and sulphate concentrations in the aquifer has been observed. A transient groundwater model is developed for the period May 1998–May 2002 and advective transport simulations have been carried out using this model. During dry periods, the major groundwater flow is directed towards the Meuse River, thereby feeding the river. During wet periods, however, groundwater flows in the opposite direction. Due to these variations in groundwater flow direction and to the extraction of groundwater, zones of higher solute concentration exist of which the position and extension vary both spatially and temporally.  相似文献   

Local erosion rates versus active tectonics: cosmic ray exposure modelling in Provence (south-east France)     

Lionel Siame  Olivier Bellier  Rgis Braucher  Michel Sbrier  Marc Cushing  Didier Bourls  Bruno Hamelin  Emmanuel Baroux  Beatrice de Voogd  Grant Raisbeck  Franoise Yiou 《Earth and Planetary Science Letters》2004,220(3-4):345-364

Over the past decade, in situ-produced cosmogenic nuclides have revolutionised the study of landscape evolution. In particular, numerous studies have demonstrated that, in active tectonic settings, cosmic ray exposure dating of deformed or displaced geomorphic features makes it possible to quantify long-term deformation rates. In western European countries, erosion due to climatically driven processes and human activities is probably the factor that most limits the accuracy of exposure ages and landscape modification rates. In this study, we present the results of a depth-profiling technique applied to alluvial terraces located along the Rhône and the Moyenne Durance rivers. The expected decrease with depth of the measured ¹⁰Be concentrations has been modelled using a χ² inversion method in order to constrain the exposure history of the alluvial sediments. The results suggest that: (1) over the Quaternary, the local surface erosion rates including both regional uplift and climatically driven processes acting on landforms are on the order of 30 m/Myr in southeastern France, and (2) providing a fairly good bracketing of the exposure age, the modelled abandonment age of alluvial terraces affected by the Moyenne Durance Fault allows estimating incision rates, comparing the alluvial terrace elevations with topographic river profiles, and a minimum vertical slip rate value of roughly 0.02 mm/yr for the southern segment of the Moyenne Durance Fault.  相似文献   

Early diagenetic processes in coastal marine sediments disturbed by a catastrophic sedimentation event     

Bruno DeflandreAlfonso Mucci  Jean-Pierre GagnéConstance Guignard  B.jørn Sundby 《Geochimica et cosmochimica acta》2002,66(14):2547-2558

Following a catastrophic flash flood in July 1996, as much as 50 cm of post-glacial clays were deposited in less than 2 days in the upper reaches of the Saguenay Fjord (Quebec, Canada), disrupting the normal sedimentation and diagenetic regimes. We report detailed geochemical analyses of sediments (porosity, Eh, organic and inorganic carbon, Fe and Mn reactive solid phases, and acid volatile sulfide) and porewaters (salinity, dissolved organic carbon (DOC), Fe(II), Mn(II), nitrate, ammonium, and sulfate) for seven stations located in the Saguenay Fjord. Three of these (SAG-05, SAG-09, and SAG-30) were visited in 1996 and once per year thereafter to document the chemical evolution of the sediment toward a new steady state. The flood deposits contain less organic carbon and more inorganic carbon than the indigenous fjord sediments. The flood deposit modified the distribution patterns of reactive Mn and Fe as a result of the reduction of Mn and Fe oxides delivered with the deposit and those concentrated at the now buried former sediment-water interface. Most of the Mn(II) migrated to the new sediment-water interface, where a Mn-rich layer was formed. In contrast, much of the Fe(II) was precipitated as sulfides and remained trapped at or close to the old interface. A nitrate peak developed in the porewater at the old sediment-water interface, possibly because of the oxidation of ammonia by Mn oxides. The distributions of porewater DOC within the flood deposit correlate with the distributions of dissolved Mn(II) and Fe(II), suggesting that adsorbed DOC was released when metal oxides were reduced.  相似文献   

Municipal initiatives for managing dunes in coastal residential areas: a case study of Avalon, New Jersey, USA     

Karl F. Nordstrom  Nancy L. Jackson  Michael S. Bruno  Harry A. de Butts 《Geomorphology》2002,47(2-4)

The characteristics of foredunes created in a municipal management program on a developed barrier island are evaluated to identify how landforms used as protection structures can be natural in appearance and function yet compatible with human values. Shoreline management zones include a naturally evolving, undeveloped segment; a noneroding, developed segment; eroding and noneroding segments of an “improved beach” where dunes have been built by artificial nourishment; and a privately built, artificially nourished dune on the shoreline of an inlet.A disastrous storm in 1962 resulted in an aggressive program for building dunes using sand fences, vegetation plantings, purchase of undeveloped lots, and sediment backpassing to maintain beach widths and dune elevations. The present nourished and shaped foredune in the improved beach is higher, wider, and closer to the berm crest than the natural dune. Restricted inputs of aeolian sand keep the surface flat and poorly vegetated. A stable section of this engineered shore has a wider beach, and sand fences have created a higher foredune with greater topographic diversity. The cross shore zonation of vegetation here is more typical of natural dunes, but the environmental gradient is much narrower. The privately built dune is low, narrow, and located where it could not be created naturally. Foreshore and aeolian sediments in the undeveloped segment and the improved beach are similar in mean grain size (0.16–0.21 mm) and sorting (0.31–0.39φ), but sediment on the surface of the nourished dune is coarser (28.1% gravel) with a more poorly sorted sand fraction (1.30φ) representing lag elements on the deflation surface.Willingness to enhance beaches and dunes for protection has reduced insurance premiums and allowed the municipality to qualify for funds from the Federal Emergency Management Agency (FEMA) to replace lost sediment, thus placing an economic value on dunes. Success of the management program is attributed to: (i) timing property-purchase and dune-building programs to periods immediately after storms (causing residents to accept high dunes that restrict access or views); (ii) instituting a vigorous education program (reminding residents of hazards during nonstorm periods); (iii) maintaining control over local sediment supplies (to keep pace with erosion and create new shoreline environments); (iv) investing private and municipal economic resources in landforms (qualifying them for external funds for replacement); and (v) maintaining, augmenting, or simply tolerating biodiversity and natural processes (retaining a natural heritage).  相似文献