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Chicarelli MI Hayes JM Popp BN Eckardt CB Maxwell JR 《Geochimica et cosmochimica acta》1993,57(6):1307-1311
The carbon and nitrogen isotopic compositions of seven of the most abundant alkylporphyrins from the Serpiano oil shale (marine, Triassic) were determined. For the C31 and C32 butanoporphyrins, values of delta 13CPDB and delta 15NAIR averaged -24.0% and -3.1%. In contrast, the C31 and C32 methylpropanoporphyrins, DPEP, and a C30 13-nor etioporphyrin had delta 13C and delta 15N values averaging -27.5 and -3.3%, respectively. Carbon and nitrogen isotopic values for kerogen averaged -30.8 and -0.9, whereas those for total extract averaged -31.6, and -4.0%. The butanoporphyrins apparently derive from a biological source different from that giving rise to the other porphyrins, their 13C enrichment not being related to carbon isotopic fractionation accompanying diagenetic reactions. The delta 15N values for all the porphyrins indicate that the depletion of 15N observed in the kerogen is of primary origin. Consistent with the very high abundance of hopanoids and methyl hopanoids in the aliphatic hydrocarbon fraction, it is suggested that cyanobacterial fixation of N2 may have been the main cause of 15N depletion. 相似文献
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BIOSCREEN-AT: BIOSCREEN with an exact analytical solution 总被引：1，自引：0，他引：1
BIOSCREEN is used extensively for screening-level evaluation of the transport of dissolved contaminants in ground water. The code has an effective graphical user interface that makes it ideal for use in both professional practice and as a teaching aid. BIOSCREEN implements the approximate transport solution of Domenico (1987). This note describes an enhanced version of the program, BIOSCREEN-AT, which supplements the Domenico solution with an exact analytical solution. The exact analytical solution has been integrated seamlessly within the BIOSCREEN interface and provides a simple and direct way to calculate an exact solution to the transport equation and, if desired, to assess the significance of the errors introduced by the Domenico (1987) solution for site-specific applications. The modified version of BIOSCREEN is designated BIOSCREEN-AT and can be downloaded free of charge from http://www.sspa.com/./software/BIOSCREEN.htm. 相似文献
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A large chromium plume that evolved from chromium releases in a valley near the Mojave River was studied to understand the processes controlling fate and migration of chromium in ground water and used as a tracer to study the dynamics of a basin and range ground water system. The valley that was studied is naturally arid with high evapotranspiration such that essentially no precipitation infiltrates to the water table. The dominant natural hydrogeologic processes are recharge to the ground water system from the Mojave River during the infrequent episodes when there is flow in the river, and ground water flow toward a playa lake where the ground water evaporates. Agricultural pumping in the valley from the mid-1930s to the 1970s significantly altered ground water flow conditions by decreasing water levels in the valley by more than 20 m. This pumping declined significantly as a result of dewatering of the aquifer, and water levels have since recovered modestly. The ground water system was modeled using MODFLOW, and chromium transport was simulated using MT3D. Several innovative modifications were made to these modeling programs to simulate important processes in this ground water system. Modifications to MODFLOW include developing a new well package that estimates pumping rates from irrigation wells at each time step based on available drawdown. MT3D was modified to account for mass trapped above the water table when the water table declines beneath nonirrigated areas and to redistribute mass to the system when water levels rise. 相似文献
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THE EFFECT OF LESSER HIMALAYAN CALC-SILICATES ON THE ~(87)Sr/~(86)Sr OF THE BHOTE KOSI RIVER OF NEPAL—IMPLICATIONS FOR HIMALAYAN WEATHERING, THE MARINE ~(87)Sr/~(86)Sr RECORD AND GLOBAL CLIMATE1 VeizerJ .AnnuRevEPS ,1989,17:141～ 16 8.
2 KrishnaswamiS ,etal.EPSL ,1992 ,10 9:2 43～ 2 5 3.
3 EdmondJM .Science ,1992 ,2 5 8:15 94～ 15 97.
4 DerryLA .France LanordCEPSL ,1996 ,142 :5 9～ 74.
5 QuadeJ ,eta… 相似文献
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Money C Braungardt CB Jha AN Worsfold PJ Achterberg EP 《Marine environmental research》2011,72(1-2):3-12
As part of the PREDICT Tamar Workshop, the toxicity of estuarine waters in the Tamar Estuary (southwest England) was assessed by integration of metal speciation determination with bioassays. High temporal resolution metal speciation analysis was undertaken in situ by deployment of a Voltammetric In situ Profiling (VIP) system. The VIP detects Cd (cadmium), Pb (lead) and Cu (copper) species smaller than 4?nm in size and this fraction is termed 'dynamic' and considered biologically available. Cadmium was mainly present in the dynamic form and constituted between 56% and 100% of the total dissolved concentration, which was determined subsequently in the laboratory in filtered discrete samples. In contrast, the dynamic Pb and Cu fractions were less important, with a much larger proportion of these metals associated with organic ligands and/or colloids (45-90% Pb and 46-85% Cu), which probably reduced the toxicological impact of these elements in this system. Static toxicity tests, based on the response of Crassostrea gigas larva exposed to discrete water samples showed a high level of toxicity (up to 100% abnormal development) at two stations in the Tamar, particularly during periods of the tidal cycle when the influence of more pristine coastal water was at its lowest. Competitive ligand-exchange Cu titrations showed that natural organic ligands reduced the free cupric ion concentration to levels that were unlikely to have been the sole cause of the observed toxicity. Nonetheless, it is probable that the combined effect of the metals determined in this work contributed significantly to the bioassay response. 相似文献