Determination of Lithium, Beryllium and Boron at Trace Levels by Laser Ablation-Inductively Coupled Plasma-Sector Field Mass Spectrometry   总被引：1，自引：2，他引：1  

Massimo Tiepolo  Alberto Zanetti  Riccardo Vannucci 《Geostandards and Geoanalytical Research》2005,29(2):211-224

The analytical capabilities of laser ablation (LA)-ICP-MS in determining Li, Be and B at trace levels in geological samples have been tested on a series of glass reference materials and natural samples. The LA-ICP-MS instrument used consisted of a sector-field ICP-MS coupled with a laser ablation microprobe operating at either 266 or 213 nm wavelength. Reference glasses from NIST (SRM 612, 614 and 616) and MPI-DING (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, T1-G and ATHO-G) were selected to develop the analytical method and to assess the best instrumental configuration. A series of calcic amphiboles with different Li, Be and B concentrations were also analysed using both LA-ICP-MS and SIMS to test the applicability of the method to natural minerals. Results indicated that with a spot size of 40 μm the agreement between measured and reference values of Li, Be and B is generally better than 10% for NIST SRM 612 and 20% for NIST SRM 614. Average reproducibility at the 2s level was 10% for Li, 20% for Be and 15% for B. Limits of detection were approximately 100 ng g^-1 for Be and B and 200 ng g^-1 for Li. These results were confirmed by analyses carried out on natural amphiboles and compared well in terms of precision and accuracy with those commonly achieved by SIMS.  相似文献   

Flexural and gravity modelling of the Mérida Andes and Barinas–Apure Basin, Western Venezuela     

Luis Chacín  María I. Jcome  Carlos Izarra 《Tectonophysics》2005,405(1-4):155-167

The kinematic evolution of the Barinas–Apure Basin and the southern Mérida Andes from Lower Miocene to the Present is numerically modelled using flexural isostatic theory and geophysical and geological data. Two published regional transects are used to build up a reference section, which is then used to constrain important parameters (e.g. shortenings and sedimentary thicknesses) for the flexural modelling. To control the location of the main fault system in the flexural model earthquake information is also used. The estimated flexural elastic thickness of the South American lithosphere beneath the Barinas–Apure Basin and the Mérida Andes Range is 25 km. The value for the final total shortening is 60 km. The flexural isostatic model shows that the Andean uplift has caused the South American lithosphere subsidence and the development of the Barinas–Apure Basin.In addition, gravity modelling was used to understand deep crustal features that could not be predicted by flexural theory. Consequently, the best-fit flexural model is used to build a gravity model across the Mérida Andes and the Barinas–Apure Basin preserving the best-controlled structural features from the flexural modelling (e.g. basin wavelength and depth) and slightly changing the main bodies density values and deep crustal structures. The final gravity model is intended to be representative of the major features affecting the gravity field in the study area. The predicted morphology in the lower crustal level of the final gravity model favours the hypothesis of a present delamination or megathrust of the Maracaibo crust over the South American Shield. This process would use the Conrad discontinuity as a main detachment surface within an incipient NW dipping continental subduction.  相似文献   

Soil liquefaction during the Arequipa Mw 8.4, June 23, 2001 earthquake, southern coastal Peru   总被引：1，自引：0，他引：1  

Franck A. Audemard M.  Juan Carlos Gmez  Hernando J. Tavera  Nuris Orihuela G. 《Engineering Geology》2005,78(3-4):237-255

The Arequipa June 23, 2001, earthquake with a moment magnitude of Mw 8.4 struck southern Peru, northern Chile and western Bolivia. This shallow (29 km deep) interplate event, occurring in the coupled zone of the Nazca subduction next to the southeast of the subducting Nazca ridge, triggered very localized but widely outspread soil liquefaction. Although sand blows and lateral spreading of river banks and road bridge abutments were observed 390 km away from the epicenter in the southeast direction (nearing the town of Tacna, close to the Chile border), liquefaction features were only observed in major river valleys and delta and coastal plains in the meizoseismal area. This was strongly controlled by the aridity along the coastal strip of Southern Peru. From the sand blow distribution along the coastal area, a first relationship of isolated sand blow diameter versus epicentral distance for a single event is ever proposed. The most significant outcome from this liquefaction field reconnaissance is that energy propagation during the main June 23, 2001, event is further supported by the distribution and size of the isolated sand blows in the meizoseismal area. The sand blows are larger to the southeast of the epicenter than its northwestern equivalents. This can be stated in other words as well. The area affected by liquefaction to the northwest is less spread out than to the southeast. Implications of these results in future paleoliquefaction investigations for earthquake magnitude and epicentral determinations are extremely important. In cases of highly asymmetrical distribution of liquefaction features such as this one, where rupture propagation tends to be mono-directional, it can be reliably determined an epicentral distance (between earthquake and liquefaction evidence) and an earthquake magnitude only if the largest sand blow is found. Therefore, magnitude estimation using this uneven liquefaction occurrence will surely lead to underrating if only the shortest side of the meizoseismal area is unluckily studied, which can eventually be the only part exhibiting liquefaction evidence, depending on the earthquake location and the distribution of liquefaction-prone environments.  相似文献   

Prediction of ground displacements and velocities from groundwater level changes at the Vallcebre landslide (Eastern Pyrenees, Spain)   总被引：2，自引：5，他引：2  

Jordi Corominas  José Moya  Alberto Ledesma  Antonio Lloret  Josep A. Gili 《Landslides》2005,2(2):83-96

In active landslides, the prediction of acceleration of movement is a crucial issue for the design and performance of warning systems. The landslide of Vallcebre in the Eastern Pyreenes, Spain, has been monitored since 1996 and data on rainfall, groundwater levels and ground displacements are measured on a regular basis. Displacements observed in borehole wire extensometers have shown an immediate response of the landslide to rainfall episodes. This rapid response is likely due to the presence of preferential drainage ways. The occurrence of nearly constant rates of displacement in coincidence with steady groundwater levels suggests the presence of viscous forces developed during the movement. An attempt to predict both landslide displacements and velocities was performed at Vallcebre by solving the momentum equation in which a viscous term (Bingham and power law) was added. Results show that, using similar rheological parameters for the entire landslide, computed displacements reproduce quite accurately the displacements observed at three selected wire extensometers. These results indicate that prediction of displacements from groundwater level changes is feasible.  相似文献   

Kamafugitic diatremes: their textures and field relationships with examples from the Goiás alkaline province, Brazil     

Tereza Cristina Junqueira-Brod  Jos Carlos Gaspar  Jos Affonso Brod  Camilla Vasconcelos Kafino 《Journal of South American Earth Sciences》2005,18(3-4):337-353

Kamafugitic rocks intruded the Precambrian basement and Phanerozoic sediments at the northeast border of the Paraná basin as part of the Late Cretaceous Goiás alkaline province (GAP). Plutonic complexes dominate the north of the province, whereas lavas and pyroclastic rocks prevail in the south. The central GAP is characterized by kamafugitic diatremes, which may crop out continuously for up to 850 m and consist of a central breccia body, surrounded and overlain by lava flows and crosscut by dykes. The breccias contain some special spheroidal juvenile fragments—namely, accretionary and armored lapilli, frozen droplets, spinning droplets, and wrapped fragments—whose textural and mineralogical aspects are described in detail. Irregularly shaped tuff pockets that occur within the breccias contain textures and structures similar to those of subaerial surge deposits and formed in confined, high gas to solid+liquid ratio domains in the conduit. Diatreme emplacement affected the country rock through thermal metamorphism, development of columnar jointing, and formation of peperite-like mixtures. There is no evidence of phreatomagmatic activity in the diatremes, and CO₂, rather than H₂O, seems to have been the major volatile component of the kamafugitic magmas. This finding implies that features such as accretionary lapilli and peperites are not exclusively associated with H₂O-dominated processes.  相似文献   

A hydraulic invariance‐based methodology for the implementation of storm‐water release restrictions in urban land use master plans          下载免费PDF全文

Viviana Pappalardo  Alberto Campisano  Francesco Martinico  Carlo Modica  Luca Barbarossa 《水文研究》2017,31(23):4046-4055

A hydraulic invariance (HI)‐based methodology was developed as a tool to support implementation of storm flow control measures into land use master plans (LUMPs) for urban catchments. The methodology is based on the use of simple hydrologic analysis to compare predevelopment and postdevelopment catchment flow release scenarios. Differently from previous literature examples, for which the parcel scale is usually considered for the analysis, HI was pursued assuming the LUMP areas of transformation as the basic units for assigning storm water control measures in the form of flow release restrictions. The methodology was applied to a case study catchment in the southern part of the City of Catania (Italy), for which the LUMP re‐design has been recently proposed. Simulations were run based on the use of the EPA‐Storm Water Management Model and allowed deriving flow release restrictions in order to achieve HI at the subcatchment level for design events of different return period.  相似文献   

Application of Distributed Temperature Sensing for coupled mapping of sedimentation processes and spatio‐temporal variability of groundwater discharge in soft‐bedded streams          下载免费PDF全文

Eva Sebok  Carlos Duque  Peter Engesgaard  Eva Boegh 《水文研究》2015,29(15):3408-3422

The delineation of groundwater discharge areas based on Distributed Temperature Sensing (DTS) data of the streambed can be difficult in soft‐bedded streams where sedimentation and scouring processes constantly change the position of the fibre optic cable relative to the streambed. Deposition‐induced temperature anomalies resemble the signal of groundwater discharge while scouring will cause the cable to float in the water column and measure stream water temperatures. DTS applied in a looped layout with nine fibre optic cable rows in a 70 × 5 m section of a soft‐bedded stream made it possible to detect variability in streambed temperatures between October 2011 and January 2012. Detailed monthly streambed elevation surveys were carried out to monitor the position of the fibre optic cable relative to the streambed and to quantify the effect of sedimentation processes on streambed temperatures. Based on the simultaneous interpretation of streambed temperature and elevation data, a method is proposed to delineate potential high‐groundwater discharge areas and identify deposition‐induced temperature anomalies in soft‐bedded streams. Potential high‐discharge sites were detected using as metrics the daily minimum, maximum and mean streambed temperatures as well as the daily amplitude and standard deviation of temperatures. The identified potential high‐discharge areas were mostly located near the channel banks, also showing temporal variability because of the scouring and redistribution of streambed sediments, leading to the relocation of pool‐riffle sequences. This study also shows that sediment deposits of 0.1 m thickness already resulted in an increase in daily minimum streambed temperatures and decrease in daily amplitude and standard deviation. Scouring sites showed lower daily minimum streambed temperatures and higher daily amplitude and standard deviation compared with areas without sedimentation and scouring. As a limitation of the approach, groundwater discharge occurring at depositional and scouring areas cannot be identified by the metrics applied. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Dynamics of the January 2013–June 2014 explosive-effusive episode in the eruption of Volcán de Colima,México: insights from seismic and video monitoring     

Vyacheslav M. Zobin  Raúl Arámbula  Mauricio Bretón  Gabriel Reyes  Imelda Plascencia  Carlos Navarro  Armando Téllez  Arnoldo Campos  Miguel González  Zoraida León  Alejandro Martínez  Carlos Ramírez 《Bulletin of Volcanology》2015,77(4):1-13

  相似文献   

Improved algorithms for generalized finite element simulations of three-dimensional hydraulic fracture propagation     

Nathan Shauer  Carlos Armando Duarte 《国际地质力学数值与分析法杂志》2019,43(18):2707-2742

This paper reports improvements to algorithms for the simulation of 3-D hydraulic fracturing with the Generalized Finite Element Method (GFEM). Three optimizations are presented and analyzed. First, an improved initial guess based on solving a 3-D elastic problem with the pressure from the previous step is shown to decrease the number of Newton iterations and increase robustness. Second, an improved methodology to find the time step that leads to fracture propagation is proposed and shown to decrease significantly the number of iterations. Third, reduced computational cost is observed by properly recycling the linear part of the coupled stiffness matrix. Two representative examples are used to analyze these improvements. Additionally, a methodology to include the leak-off term is presented and verified against asymptotic analytical solutions. Conservation of mass is shown to be well satisfied in all examples.  相似文献   

Coastal Occupations in Tierra del Fuego,Southernmost South America: A Late Holocene Hunter‐Gatherer Context at Marazzi 2     

Ivana L. Ozn  Charles French  Flavia Morello Repetto  Carlos A. Vsquez  Toms Luppo 《Geoarchaeology》2015,30(6):465-482

This paper focuses on the late Holocene occupation of hunter‐gatherers at the Marazzi 2 site located on the northwestern steppe of Tierra del Fuego, Chile. Our aim is to understand stratigraphy, formation processes, and pedogenesis with respect to human occupation over the last 3000 years. Based on archaeological excavations on a fluvial terrace of the Torcido River, we integrate soil micromorphology, mineralogy, geochemistry, magnetic susceptibility, and geomorphology, as well as the micro‐ and macrofrequency distributions of archaeological material. A micro‐taphonomical perspective is also applied to anthropogenic components recorded in sedimentary thin sections. We discuss various events in the interplay between soil development and human occupation through time. Marazzi 2 was witness to aggradation and pedogenesis with an episode of surface stability coincident with a phase of more intense human occupation at about 860 BC. Taphonomic analysis suggests that there are multiple occupation events mixed together, probably by biomechanical processes, resulting in a palimpsest with poor temporal resolution.  相似文献