Lake Sediment Core Records of Sulphur Accumulation and Sulphur Isotopic Composition in Central Ontario, Canada Lakes     

M. Catherine Eimers  Andrew M. Paterson  Peter J. Dillon  Sherry L. Schiff  Brian F. Cumming  Roland I. Hall 《Journal of Paleolimnology》2006,35(1):99-109

Stable isotopic compositions and concentrations of total sedimentary sulphur (S) were determined in cores from 6 lakes in the acid-sensitive Muskoka-Haliburton region of south-central Ontario. The isotopic composition of S in deep sediment (> ~ 20 cm) was approximately constant in all lakes, and indicated a pre-industrial δ ³⁴S value between +4.0 and +5.3‰, which is similar to current bulk deposition. Similarly, total S concentrations in deep sediment were relatively low (1.9–5 mg S g⁻¹ dwt) and approximately constant with depth within cores. All lakes exhibited up-core increases in total S and decreases in δ ³⁴S at a depth corresponding to the beginning of industrialization in the Great Lakes region ( ~ 1900), resulting in a generally reciprocal depth pattern between total S concentration and δ ³⁴S ratios. While initial shifts in total S and δ ³⁴S were likely due to enhanced SO₄ reduction of newly available anthropogenic SO₄, both the magnitude and pattern of up-core S enrichment and shifts in δ ³⁴S varied greatly among lakes, and did not match changes in S deposition post 1900. Differences between lakes in total S and δ ³⁴S were not related to any single hydrologic (e.g., residence time) or physical (e.g., catchment-area-to-lake area ratio) lake characteristic. This work indicates that sediment cores do not provide consistent records of changes in post-industrial S deposition in this region, likely due to redox-related mobility of S in upper sediment.  相似文献   

Verification of the motion fields over Southeast Asia by the Florida State University (FSU) superensemble forecast     

Mastura Mahmud  Robert S. Ross 《Singapore journal of tropical geography》2006,27(2):176-190

The Florida State University (FSU) multimodel superensemble forecast is evaluated against several other operational weather models for the Southeast Asia region. The superensemble technique has demonstrated its exceptional skills in forecasting precipitation, motion and mass fields compared to either individual global operational or ensemble mean forecasts. The motion field investigation for the season of 2001 reveals that the superensemble forecasts are closer to the observed data compared to the other global member operational models through its low systematic errors at the 850 hPa level. The FSU multimodel superensemble forecasts exhibit the lowest root mean square errors (RSMEs), the highest correlation against the best observed data and the lowest systematic errors compared to the other operational model members. These forecasts have the potential to provide better daily weather predictions over the Southeast Asia region, particularly during the early northeast monsoon that often causes heavy rainfall in the equatorial part of the Southeast Asia region.  相似文献   

Origin of the Nchanga copper–cobalt deposits of the Zambian Copperbelt     

Ross R. McGowan  Stephen Roberts  Adrian J. Boyce 《Mineralium Deposita》2006,40(6-7):617-638

The Zambian Copperbelt forms the southeastern part of the 900-km-long Neoproterozoic Lufilian Arc and contains one of the world’s largest accumulations of sediment-hosted stratiform copper mineralization. The Nchanga deposit is one of the most significant ore systems in the Zambian Copperbelt and contains two major economic concentrations of copper and cobalt, hosted within the Lower Roan Group of the Katangan Supergroup. A Lower Orebody (copper only) and Upper Orebody (copper and cobalt) occur towards the top of arkosic units and within the base of overlying shales. The sulfide mineralogy includes pyrite, bornite, chalcopyrite, and chalcocite, although in the Lower Orebody, sulfide phases are partially or completely replaced by malachite and copper oxides. Carrollite is the major cobalt-bearing phase and is restricted to fault-propagation fold zones within a feldspathic arenite. Hydrothermal alteration minerals include dolomite, phlogophite, sericite, rutile, quartz, tourmaline, and chlorite. Quartz veins from the mine sequence show halite-saturated fluid inclusions, ranging from ~31 to 38 wt% equivalent NaCl, with homogenisation temperatures (Th_TOT) ranging between 140 and 180°C. Diagenetic pyrites in the lower orebody show distinct, relatively low δ ³⁴S, ranging from −1 to −17‰ whereas arenite- and shale-hosted copper and cobalt sulfides reveal distinctly different δ ³⁴S from −1 to +12‰ for the Lower Orebody and +5 to +18‰ for the Upper Orebody. There is also a clear distinction between the δ ³⁴S mean of +12.1±3.3‰ (n=65) for the Upper Orebody compared with +5.2±3.6‰ (n=23) for the Lower Orebody. The δ ¹³C of dolomites from units above the Upper Orebody give δ ¹³C values of +1.4 to +2.5‰ consistent with marine carbon. However, dolomite from the shear-zones and the alteration assemblages within the Upper Orebody show more negative δ ¹³C values: −2.9 to −4.0‰ and −5.6 to −8.3‰, respectively. Similarly, shear zone and Upper Orebody dolomites give a δ ¹⁸O of +11.7 to +16.9‰ compared to Lower Roan Dolomites, which show δ ¹⁸O of +22.4 to +23.0‰_. Two distinct structural regimes are recognized in the Nchanga area: a weakly deformed zone consisting of basement and overlying footwall siliciclastics, and a moderate to tightly folded zone of meta-sediments of the Katangan succession. The fold geometry of the Lower Roan package is controlled by internal thrust fault-propagation folds, which detach at the top of the lowermost arkose or within the base of the overlying stratigraphy and show vergence towards the NE. Faulting and folding are considered to be synchronous, as folding predominantly occurred at the tips of propagating thrust faults, with local thrust breakthrough. The data from Nchanga suggests a strong link between ore formation and the development of structures during basin inversion as part of the Lufilian Orogeny. Sulfides tend to be concentrated within arenites or coarser-grained layers within shale units, suggesting that host-rock porosity and possibly permeability played a role in ore formation. However, sulfides are also commonly orientated along, but not deformed by, a tectonic fabric or hosted within small fractures that suggest a significant role for deformation in the development of the mineralization. The ore mineralogy, hydrothermal alteration, and stable isotope data lend support to models consistent with the thermochemical reduction of a sulfate- (and metal) enriched hydrothermal fluid, at the site of mineralization. There is no evidence at Nchanga for a contribution of bacteriogenic sulfide, produced during sedimentation or early diagenesis, to the ores.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.Editorial handling: H. Frimmel  相似文献   

3D numerical modelling of fluid flow in the Val-d’Or orogenic gold district: major crustal shear zones drain fluids from overpressured vein fields     

Georges Beaudoin  René Therrien  Catherine Savard 《Mineralium Deposita》2006,41(1):82-98

Fluid flow patterns have been determined using oxygen isotope isopleths in the Val-d’Or orogenic gold district. 3D numerical modelling of fluid flow and oxygen isotope exchange in the vein field shows that the fluid flow patterns can be reproduced if the lower boundary of the model is permeable, which represents middle or lower crustal rocks that are infiltrated by a metamorphic fluid generated at deeper levels. This boundary condition implies that the major crustal faults so conspicuous in vein fields do not act as the only major channel for upward fluid flow. The upper model boundary is impermeable except along the trace of major crustal faults where fluids are allowed to drain out of the vein field. This upper impermeable boundary condition represents a low-permeability layer in the crust that separates the overpressured fluid from the overlying hydrostatic fluid pressure regime. We propose that the role of major crustal faults in overpressured vein fields, independent of tectonic setting, is to drain hydrothermal fluids out of the vein field along a breach across an impermeable layer higher in the crust and above the vein field. This breach is crucial to allow flow out of the vein field and accumulation of metals in the fractures, and this breach has major implications for exploration for mineral resources. We propose that tectonic events that cause episodic metamorphic dehydration create a short-lived pulse of metamorphic fluid to rise along zones of transient permeability. This results in a fluid wave that propagates upward carrying metals to the mineralized area. Earthquakes along crustal shear zones cause dilation near jogs that draw fluids and deposit metals in an interconnected network of subsidiary shear zones. Fluid flow is arrested by an impermeable barrier separating the hydrostatic and lithostatic fluid pressure regimes. Fluids flow through the evolving and interconnected network of shear zones and by advection through the rock matrix. Episodic breaches in the impermeable barrier along the crustal shear zones allow fluid flow out of the vein field.  相似文献   

Earth-moon relationships, edited by C. Barbieri and F. Rampazzi. Kluwer Academic Publishers, Dordrecht (Netherlands), 2001, 575 pp. Eur 229, GBP 140, US $199 (ISBN 0-7923-7089-9)     

Stuart Ross Taylor 《Geochimica et cosmochimica acta》2002,66(8):1495

  相似文献   

Celestite formation, bacterial sulphate reduction and carbonate cementation of Eocene reefs and basinal sediments (Igualada, NE Spain)   总被引：5，自引：0，他引：5  

Conxita Taberner  James D. Marshall†  James P. Hendry‡  Catherine Pierre§  & M. F. Thirlwall¶ 《Sedimentology》2002,49(1):171-190

Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO₄) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr²⁺ and SO₄^2? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO₄^2? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, ⁸⁷Sr/⁸⁶Sr data also suggest that Sr²⁺ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in ¹⁸O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits.  相似文献   

Explosion seismic reflections from the Earth’s core     

H Thybo  A.R Ross 《Earth and Planetary Science Letters》2003,216(4):693-702

Recent seismological studies have presented evidence for the existence of a layer with ultra-low seismic velocities at the core-mantle boundary at ca. 2900 km depth. We report high-amplitude, high-frequency, and laterally coherent seismic arrivals from three nuclear explosions in Siberia. With recording station intervals of 15 km, the seismic phases are readily correlated and show the presence of a thin, ultra-low velocity zone in a region where it was not previously reported. The duration and complexity of the arrivals are inconsistent with a simple core-mantle boundary and require a hitherto unidentified, kilometre-scale, fine structure in the ultra-low velocity zone. The observations may be explained by a ca. 7 km thick, two-layer, ultra-low velocity zone with exceptional low velocities, which indicate the presence of high percentages of melt (>15%), in particular in the lower part of the zone. Waveform variation implies lateral change in the thickness and physical properties of the ultra-low velocity zone with a wavelength of less than 100 km.  相似文献   

Raman scattering and X-ray diffraction study of the thermal decomposition of an ettringite-group crystal     

S. K. Deb  M. H. Manghnani  K. Ross  R. A. Livingston  P. J. M. Monteiro 《Physics and Chemistry of Minerals》2003,30(1):31-38

 A Raman scattering and X-ray diffraction study of the thermal decomposition of a naturally occurring, ettringite-group crystal is presented. Raman spectra, recorded with increasing temperature, indicate that the thermal decomposition begins at ≈55 °C, accompanied by dehydration of water molecules from the mineral. This is in contrast to previous studies that reported higher temperature breakdown of ettringite. The dehydration is completed by 175 °C and this results in total collapse of the crystalline structure and the material becomes amorphous. The Raman scattering results are supported by X-ray diffraction results obtained at increasing temperatures. Received: 9 July 2001 / Accepted: 14 August 2002  相似文献   

Toxic Cyanobacteria in Greek Freshwaters, 1987—2000: Occurrence,Toxicity, and Impacts in the Mediterranean Region     

Catherine M. Cook  Elisabeth Vardaka  Tom Lanaras 《洁净——土壤、空气、水》2004,32(2):107-124

In a survey in Greece from 1987 to 2000 hepatotoxic cyanobacterial blooms were observed in 9 out of 33 freshwaters. Microcystins (MCYSTs) were detected by HPLC in 7 of these lakes, and the total MCYST concentration per scum dry weight ranged from 50.3 to 1638 ± 464 μg g^—1. Cyanobacterial genera (Microcystis, Anabaena, Anabaenopsis, Aphanizomenon, Cylindrospermopsis) with known toxin producing taxa were present in 31 freshwaters. From our data and a review of the literature, it would appear that Mediterranean countries are more likely 1) to have toxic cyanobacterial blooms consisting of Microcystis spp. and 2) to have higher intracellular MCYST concentrations. A case study in Lake Kastoria is used to highlight seasonal patterns of cyanobacterial and MCYST‐LR occurrence and to assess cyanotoxin risk. Cyanobacterial biovolume was high (> 11 μL L^—1) throughout the year and was in excess of Guidance Level 2 (10 μL L^—1) proposed by WHO for recreational waters and Alert Level 2 for drinking water. Further, surface water samples from April to November exceeded Guidance Level 3, with the potential for acute cyanobacterial poisoning. Intracellular MCYST‐LR concentrations (max 3186 μg L^—1) exceeded the WHO guideline for drinking water (1 μg L^—1) from September to November with a high risk of adverse health effects. Preliminary evidence indicates that in 3 lakes microcystins are accumulated in some aquatic organisms. Generally, a high risk level can be deduced from the data for the Mediterranean region.  相似文献   

Temnospondyls from the Beaufort Group (Karoo Basin) of South Africa and Their Biostratigraphy     

Ross J. Damiani   《Gondwana Research》2004,7(1):165-173

The Permo-Triassic Beaufort Group (Karoo Basin) of South Africa is biostratigraphically subdivided into eight, temporally successive assemblage zones based on therapsids (‘mammal-like reptiles’). The Temnospondyli, fossil tetrapods usually regarded as extinct amphibians, are second only to therapsids in terms of diversity and abundance in these strata, with nine higher-level taxa (‘families’) known. Temnospondyls are also playing an increasingly important role in biostratigraphy and correlation of the Beaufort strata. The lower Beaufort Group (Late Permian) contains six of the eight biozones, but only one temnospondyl ‘family’, the Rhinesuchidae, whose record in the Karoo is the richest in the world. However, rhinesuchid taxonomy remains in flux and the group is thus of limited biostratigraphic utility. The Early Triassic Lystrosaurus Assemblage Zone (middle Beaufort Group) contains the Rhinesuchidae, Amphibamidae, Lydekkerinidae, Tupilakosauridae, Rhytidosteidae, Mastodonsauridae and Trematosauridae, although the biostratigraphy of temnospondyls within this biozone is poorly constrained. The uppermost reaches of the Lystrosaurus biozone contain a paucity of fossils but includes ‘Kestrosaurus’ (Mastodonsauridae) and ?Trematosuchus (Trematosauridae), taxa previously thought to pertain to the lower part of the overlying Cynognathus biozone. The late Early to Middle Triassic Cynognathus Assemblage Zone (upper Beaufort Group) hosts the Mastodonsauridae, Trematosauridae, Brachyopidae, Laidleriidae and, possibly, the Rhytidosteidae. Based largely on the spatial and temporal distribution of mastodonsaurids, this biozone has been biostratigraphically subdivided into a lower A, middle B and upper C subzones, characterised by differing ages and faunas.  相似文献