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11.
ABSTRACT A number of non‐marine evaporite units composed of primary gypsum were deposited in saline lakes that developed in the southern Teruel Basin (NE Spain) during the Miocene. In the basin depocentre, a continuum of lacustrine evaporite lithofacies influenced by the activity of organisms is displayed. The Libros Gypsum was deposited in a deep lake, in which water stratification became unstable with progressive shoaling. Rhythmites, composed of laminae of pelletal gypsum and laminae of very fine lenticular gypsum crystals mixed with siliceous microorganisms, formed in addition to gypsum turbidites, intraformational gypsum breccias and slump structures. The pelletal laminae originated from the faecal activity of animals (crustaceans?) ingesting gypsum crystallites in the lake water during episodes of maximum evaporation, whereas the laminae of very fine lenticular gypsum mixed with microorganisms accumulated during episodes of relative dilution. In the wide marginal zones of the basin, the Libros Gypsum unit consists of massive to thin‐bedded bioturbated gypsum and thin‐bedded clotted gypsum, which formed in intermediate to very shallow (palustrine) water depths. The bioturbated gypsum lithofacies were produced by the action of diverse organisms, presumably worms and coleopterans, and chironomid larvae to a lesser extent; the massive lithofacies precipitated in very shallow water; and the thin‐bedded lithofacies formed in shallow to deeper settings. The thin‐bedded clotted gypsum is a relatively deep facies that may have diverse origins (e.g. bioturbation, compaction, disruption of soft sediments and early diagenesis). There is a well‐developed metre‐scale cyclicity in the marginal lake sequences, which is not observed in the inner lake deposits. This suggests a depth control in the various lacustrine subenvironments to record cyclic evaporitic processes. The isotopic composition of the gypsum indicates early sulphate‐reducing bacterial activity in the bottom of the lake and suggests that the sulphate was derived from the chemical recycling of Triassic evaporites of the country rocks.  相似文献   
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A conceptual-stochastic approach to short time runoff data modelling is proposed, according to the aim of reproducing the hydrological aspects of the streamflow process and of preserving as much as possible the dynamics of the process itself. This latter task implies preservation of streamflow characteristics at higher scales of aggregation and, within a conceptual framework, involves compatibility with models proposed for the runoff process at those scales. At a daily time scale the watershed response to the effective rainfall is considered as deriving from the response of three linear reservoirs, respectively representing contributions to streamflows of large deep aquifers, with over-year response lag, of aquifers which run dry by the end of the dry season and of subsurface runoff. The surface runoff component is regarded as an uncorrelated point process. Considering the occurrences of effective rainfall events as generated by an independent Poisson process, the output of the linear system represents a conceptually-based multiple shot noise process. Model identification and parameter estimation are supported by information related to the aggregated runoff process, in agreement to the conceptual framework proposed, and this allows parameter parsimony, efficient estimation and effectiveness of the streamflow reproduction. Good performances emerged from the model application and testing made with reference to some daily runoff series from Italian basins.  相似文献   
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We present 39Ar–40Ar dating of phengite, muscovite and paragonite from a set of mafic and metasedimentary rocks sampled from the high-pressure (HP) metaophiolites of the Voltri Group (Western Alps) and from clasts in the basal layer conglomerates from the Tertiary molasse which overlie the high-pressure basement. The white mica-bearing rocks display peak eclogitic and blueschist-facies parageneses, locally showing complex greenschist-facies replacement textures. The internal discordance of age spectra is proportional to the chemical complexity of the micas. High-Si phengites from eclogite clasts record a 39Ar–40Ar age of ca. 49 Ma for the eclogite stage and ca. 43 Ma for the blueschist retrogression; phengites from a blueschist basement sample yield an age of ca. 40 Ma; low-Si muscovite from a metasediment dates the formation of the greenschist paragenesis at ca. 33 Ma. Our data indicate that the analyzed samples reached high-pressure conditions at different times over a time-span of c.a. 10 Ma. Subduction was continuing during exhumation and blueschist retrograde re-equilibration of higher-pressure, eclogite-facies rocks. This process kept the isotherms depressed, allowing the older HP-rocks to escape thermal re-equilibration. Our results, added to literature data, fit a tectonic model of a subduction–exhumation cycle, with different tectonic slices subducted at different times from Early Eocene until the Eocene–Oligocene boundary.  相似文献   
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This work focuses on developing multidisciplinary researches concerning weathering profiles related to landscape evolution of the Capo Vaticano promontory on the Calabria Tyrrhenian side (southern Italy). In this area, the tectonic uplift, occurred at least since Pleistocene, together with the Mediterranean climatic conditions, is the main cause of deep weathering and denudation processes. The latter occurred on the outcropping rocks of the crystalline-metamorphic basement, made up of weathered granitoids, in turn belonging to the Monte Poro granitoid complex (intermediate to felsic plutonic rocks covered by Cenozoic sedimentary successions). Field observations coupled to borehole explorations, geophysical surveys, and minero-petrographical analyses allowed the characterization of the granitoid outcrops typical of the studied area in terms of kind and degree of slope instability. This characterization was based on suitable correlations verified between several factors as weathering degree, elastic properties of rocks, and discontinuity features. Weathering profiles are mainly composed by rock masses varying from completely weathered rock with corestones of highly weathered rock (classes IV–V) to slightly weathered rocks (class II). The weathered rocks are involved in several landslide typologies such as debris flow (frequency 48.5%), translational slide (frequency 33.3%), and minor rock fall and rotational slide (frequency 9%). The achieved data allowed the establishment of a general correlation between weathering degree and type of slope instability. Debris flow-type instabilities are predominant on the steeper slopes, involving very poor rock masses ascribed to the shallowest portions of the weathering class IV. Translational slides are less widespread than the previous ones and often involve a mixture of soil and highly weathered rocks. Rotational slides are more frequently close to the top of the slopes, where the thicknesses of more weathered rocks increase, and involve mainly rock masses belonging to the weathering classes IV and V. Rock falls mostly occur on the vertical escarpments of the road cuts and are controlled by the characteristics of the main discontinuities. The assessment of rock mass rating and slope mass rating, based on the application of the discontinuity data, allowed respectively an evaluation of the quality of rock masses and of the susceptibility of rock slopes to failure. The comparison between the last one and the real stability conditions along the cut slopes shows a good correspondence. Finally, the geological strength index system was also applied for the estimation of rock mass properties. The achieved results give a worthy support for a better understanding of the relationship between the distribution of landslides and the geological features related to different weathering degrees. Therefore, they can provide a reliable tool to evaluate the potential stability conditions of the rock slopes in the studied area and a general reference framework for the study of weathering processes in other regions with similar geological features.  相似文献   
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The urban growth of the southern neighborhoods of Mar del Plata City provoked significant changes in the groundwater balance of the loessic sequences. These regional loessic levels with a significant portion of volcanic ash layers were reported subject to fluoride and nitrate concentrations. Residential houses pump from sands located 70 m depth and withdraw the sewages to depths less than 5 m. These effects cause significant local and seasonal (summer) increments of the water table outcropping via springs at certain unconformities of the coastal cliffs. A mathematical model was applied to analyze the water level lowering at the productive levels, while there is a decrease in the quality of the upper levels subject to waste discharges. Much of this groundwater flow is concentrated in unconformities between different types of sediments. Human activities have affected the aquifer dynamics increasing the groundwater pumping rates and the return velocity of the sewages. This should be considered in the management strategies of coastal hydric resources.  相似文献   
20.
High resolution time series of lead and zinc in sediments of Lake Constance   总被引:3,自引:0,他引:3  
Sediments in Lake Constance have been dated by radiometric methods and lamination counting. Investigations into the concentrations of lead and zinc in the sediments were carried out to get detailed information about environmental history. Maximum concentrations were found at the beginning of the 1960's. The lead maximum contamination occurred 3 years before the zinc maximum and has an unidentified source. The use of coal, leaded gasoline or the remobilization within the sediment could be excluded to result in the lead maximum. The fluctuations in zinc contamination could be explained with increasing and decreasing pollution (industry, coal burning, building of sewage plants). The greatest fluctuations of both metals occur during periods of great change in the economic history of Germany.  相似文献   
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