Magmatism in the Iberian Pyrite Belt: petrological constraints on a metallogenic model     

D. Thiéblemont  E. Pascual  G. Stein 《Mineralium Deposita》1997,33(1-2):98-110

Igneous formations associated with massive sulphide deposits in the Iberian Pyrite Belt (IPB) are essentially composed of basic lavas and dolerites, and dacitic to rhyolitic volcanites; intermediate lavas are subordinate. The basic rocks show variable geochemical characteristics: lavas and dolerites comparable to recent within-plate alkaline basalts seem restricted to the western and southern parts of the IPB, whereas basic rocks comparable to continental tholeiites or arc-related basalts occur across the whole belt. The felsic rocks are classified as calc-alkaline and belong to the “low-Al₂O₃ and high-Yb type”. At given SiO₂, Al₂O₃ and TiO₂ contents, they show variable Zr, Nb, and HREE contents. Heavy-rare-earth element fractionation decreases from the dacites to the rhyolites ([Gd/Yb]_N ∼ 1), whereas the negative Eu-anomaly becomes more pronounced. The characteristics of the rhyolites are typical of sulphide-fertile volcanic packages. Trace-element modelling suggests that the felsic rocks evolved from a dacitic parent magma through fractional crystallization of hornblende and plagioclase. Partial melting of an amphibolite protolith, which appears as the most probable model for the origin of this dacitic magma, requires a high T/P gradient in the crust. The occurrence of alkaline basalts and continental tholeiites is consistent with formation of the IPB in a tensional tectonic setting. However, the associated island-arc tholeiites suggest a location in a domain of plate convergence. Emplacement in a fore-arc basin over a recently accreted crustal segment is envisaged as a possible hypothesis to account for the geological and petrological constraints. A high geothermal gradient and eruption in a submarine tensional basin could have been two key ingredients for the development of massive sulphide deposits within the IPB.

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Resumen (translated by E. Pascual) Las formaciones ígneas asociadas con los depósitos de sulfuros masivos de la Faja Pirítica Ibérica (IPB) se componen esencialmente de doleritas y lavas básicas y de rocas volcánicas dacíticas a riolíticas; las lavas intermedias son poco abundantes. Las rocas básicas muestran caracteres geoquímicos variables: lavas y doleritas comparables a basaltos alcalinos intraplaca recientes parecen hasta ahora restringidos a las partes W y S de la IPB, mientras que rocas básicas de caracteres comparables a las de toleítas continentales o basaltos relacionados con arcos aparecen en toda la zona. Las rocas ácidas se clasifican como calcoalcalinas del tipo “low-Al₂O₃, high-Yb”. Para un contenido dado en SiO₂, Al₂O₃ y TiO₂, muestran contenidos variables en Zr, Nb y REE. El contenido en tierras raras pesadas decrece de dacitas a riolitas ([Gd/Yb]_N ∼ 1), al tiempo que la anomalía de Eu se hace más pronunciada. La modelización de elementos trazas sugiere que las rocas evolucionaron a partir de un magma parental dacítico mediante cristalización fraccionada de hornblenda y plagioclasa. La fusión parcial de un protolito anfibolítico, que parece el modelo más plausible para el origen del magma dacítico, requiere un elevado gradiente T/P en la corteza. La existencia de basaltos alcalinos y de toleítas continentales es congruente con la formación de la IPB en un entorno tectónico distensivo. El emplazamiento en una cuenca “fore-arc”, en un segmento cortical de reciente acreción, se contempla como una hipótesis posible para explicar los caracteres geológicos y petrológicos. Un alto gradiente térmico, junto con la erupción en una cuenca submarina extensional, pueden haber sido los dos ingredientes clave en el desarrollo de los depósitos de sulfuros masivos en la IPB.

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Received: 3 March 1996 / Accepted: 7 April 1997  相似文献   

解算非线性Molodensky问题的高阶逼近方法   总被引：5，自引：0，他引：5  

于锦海  党诵诗 《测绘学报》1992,21(4):249-258

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玄武岩—水相互作用的溶解机理研究   总被引：11，自引：0，他引：11  

党志  侯瑛 《岩石学报》1995,11(1):9-15

在常温常压排除大气干扰的封闭体系条件下,将一定粒度的玄武岩样品浸泡在不同酸度的水溶液里,研究玄武岩－水相互作用过程中元素释放和溶液酸度的变化情况。结果发现：（１）经过一段时间后,溶液中主要元素的浓度趋向平衡;（２）溶液酸度发生明显变化,即不论反应初始溶液是碱性的还是酸性的,最终都将趋于中性,我们把此现象称为溶液的中性化效应。根据溶液中溶解组分的浓度和样品表面组成的ＸＰＳ测定结果,提出玄武岩在碱性和酸性溶液中不同的溶解机理。  相似文献   

Analysis of sediment distribution and transport for mitigation of sand deposition hazard in Tam Quan estuary,Vietnam     

Do Minh Duc  Dinh Xuan Thanh  Dinh Thi Quynh  Patrick McLaren 《Environmental Earth Sciences》2016,75(9):741

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A new continuous measurement method for gaseous ammonia by counter-current flow tube sampling and indophenol reaction     

Duong Huu Huy  To Thi Hien  Norimichi Takenaka 《Journal of Atmospheric Chemistry》2016,73(3):223-240

Ammonia (NH₃) is the most abundant alkaline gas in the atmosphere and plays a key role in atmospheric chemistry. Reliable and high-time-resolution data for gaseous ammonia are necessary to understand the sources and sinks of ammonia gas in ambient air. In the present study, a sensitive and continuous instrument for measuring gaseous ammonia was developed. Ammonia gas in ambient air was collected in an aqueous solution using a counter-current flow tube (CCFT) sampler. Then, ammonium formed in the aqueous solution was detected by the indophenol method. Based on a CCFT length of 50 cm and air flow rate of 1 L/min, the collection efficiency exceeded 98.5 % at an ammonia mixing ratio of up to 120 ppbv. The detection limit of this method was 0.062 ppbv. Interferences from several gases were investigated, and the results showed that the present method was not affected by NO_x, O₃, SO₂, HONO, methylamine, formaldehyde, hydrogen sulfide or a mixture of these gases. The most important result was that only gaseous ammonia was detected in the present method without any interference from the particulate ammonium in ambient air. Comparisons with data based on the dry denuder method indicated that the present method showed good agreement with the denuder method.  相似文献   

Verification of a VOF-based two-phase flow model for wave breaking and wave–structure interactions     

Phung Dang Hieu  Katsutoshi Tanimoto   《Ocean Engineering》2006,33(11-12):1565-1588

The objective of the present study is to develop a volume of fluid (VOF)-based two-phase flow model and to discuss the applicability of the model to the simulation of wave–structure interactions. First, an overview of the development of VOF-type models for applications in the field of coastal engineering is presented. The numerical VOF-based two-phase flow model has been developed and applied to the simulations of wave interactions with a submerged breakwater as well as of wave breaking on a slope. Numerical results are then compared with laboratory experimental data in order to verify the applicability of the numerical model to the simulations of complex interactions of waves and permeable coastal structures, including the effects of wave breaking. It is concluded that the two-phase flow model with the aid of the advanced VOF technique can provide with acceptably accurate numerical results on the route to practical purposes.  相似文献   

Detection of interstellar hydrogen sulfide in cold, dark clouds     

Minh YC  Irvine WM  Ziurys LM 《The Astrophysical journal》1989,345(1):L63-L66

We have detected interstellar hydrogen sulfide (H2S) toward the cold, dark clouds L134N and TMC 1. We derive total column densities of approximately 2.6 x 10(13) cm-2 and approximately 7.0 x 10(12) cm-2 at the SO peak of L134N and at the NH3 peak of TMC 1, respectively. Since the expected gas phase reactions leading to the formation of H2S are thought to be endothermic, grain surface reactions may play a major role in the synthesis of this species in cold, dark clouds. If the carbon abundance is high and grain surface reactions are the dominant formation route, H2CS would be expected to form instead of H2S, and the abundances of H2CS have been observed to be high where those of H2S are low in L134N and TMC 1.  相似文献   

An efficient finite–discrete element method for quasi‐static nonlinear soil–structure interaction problems     

Hoang K. Dang  Mohamed A. Meguid 《国际地质力学数值与分析法杂志》2013,37(2):130-149

An efficient finite–discrete element method applicable for the analysis of quasi‐static nonlinear soil–structure interaction problems involving large deformations in three‐dimensional space was presented in this paper. The present method differs from previous approaches in that the use of very fine mesh and small time steps was not needed to stabilize the calculation. The domain involving the large displacement was modeled using discrete elements, whereas the rest of the domain was modeled using finite elements. Forces acting on the discrete and finite elements were related by introducing interface elements at the boundary of the two domains. To improve the stability of the developed method, we used explicit time integration with different damping schemes applied to each domain to relax the system and to reach stability condition. With appropriate damping schemes, a relatively coarse finite element mesh can be used, resulting in significant savings in the computation time. The proposed algorithm was validated using three different benchmark problems, and the numerical results were compared with existing analytical and numerical solutions. The algorithm performance in solving practical soil–structure interaction problems was also investigated by simulating a large‐scale soft ground tunneling problem involving soil loss near an existing lining. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Anticipated changes in analysis accuracy with the removal of Ocean Weather Ship P     

H. Jean Thiébaux 《大气与海洋》2013,51(4):261-285

Abstract

Analysis error patterns have been established for the Pacific Weather Centre Experiment Area, and comparisons made between errors computed for meteorological observing arrays, including Ocean Weather Ship (OWS) P, and errors computed for several alternative arrays which excluded OWS P. These assessments of the impact of replacing the ocean weather ship with alternative observing equipment indicate that, above the 1000‐mb pressure surface, there will be a significant loss of accuracy in the forecast‐minus‐observation analyses regardless of proposed additional report systems. Near the surface, forecast error variances are estimated to decrease slightly with an increase of reports from buoys and ships of opportunity within the region.

The dependence of the assessments on the data selection procedure and on correlation representations for the region suggest that some loss may be compensated by more efficient use of available data. Refinements in the objective analysis scheme are seen to be especially important to analysis accuracy in regions lacking radiosonde coverage.  相似文献   

PGE geochemical constraints on the origin of the Ni-Cu-PGE sulfide mineralization in the Suoi Cun intrusion,Cao Bang province,Northeastern Vietnam     

Tatyana V. Svetlitskaya  Nadezhda D. Tolstykh  Andrey E. Izokh  Phuong Ngo Thi 《Mineralogy and Petrology》2015,109(2):161-180

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