The influence of increased iron concentration on survival and growth of seedlings and young plants of eelgrass Zostera marina          下载免费PDF全文

Xi‐Tao Wang  Qian Zhang  Yan‐Shan Liu  Pei‐Dong Zhang  Wen‐Tao Li 《Marine Ecology》2017,38(3)

Iron (Fe) is an essential nutrient for plants but toxic at high concentrations. We subjected seedlings and young plants of eelgrass Zostera marina to different seawater iron concentrations (500, 600, 700, 800, 1,000 and 1,500 μg/L) for 30 days under controlled laboratory conditions. Natural seawater without added iron (500 μg/L) was used as reference seawater. No sediments were provided to avoid iron scavenging by particle surfaces in the sediment. We measured plant response in terms of survivorship, morphology, growth rate and productivity. Survival analysis combined with morphological, dynamic and productive assessment suggested that the optimum seawater iron concentration for the establishment of Z. marina seedlings and young plants is 700 μg/L. The no observed effect concentration, lowest observed effect concentration, lethal concentration that caused an increase in mortality to 10% of that of the control, and the effect concentration that caused a decrease in growth to 10% of that of the control values of young plants were significantly lower than those of seedlings, implying an increased sensitivity to high Fe concentrations (>1,000 μg/L). This study further develops our understanding of the physiological ecology of the early life stages of Z. marina and provides data that could prove helpful in the development of successful eelgrass restoration and conservation.  相似文献   

Interpretation of shear strength uncertainty and reliability analyses of slopes     

Michael P. McGuire  Daniel R. VandenBerge 《Landslides》2017,14(6):2059-2072

The variance of the friction angle or friction coefficient (tan ?) is often considered in geotechnical reliability analyses, which implies that the variance of the shear strength as defined by a Mohr-Coulomb envelope increases as the normal stress on the shearing surface increases. However, shear strength data sometimes has approximately constant variance, and most simple regression techniques assume constant variance. Four effective stress shear strength data sets are evaluated using both the constant variance (homoscedastic) and constant coefficient of variation (heteroscedastic) interpretations. The impact of the variance interpretation on slope stability is evaluated using infinite slope, homogeneous dam, and zoned dam examples. For relatively shallow infinite slope surfaces, the reliability index for the heteroscedastic interpretation of shear strength variance was about twice the reliability index obtained using the homoscedastic approach. In the dam examples, the difference in the reliability indices resulting from the heteroscedastic and homoscedastic interpretations was about one, indicating a tenfold increase in the probability of failure. The typical assumption of constant coefficient of variation of shear strength may result in unconservative estimates of the reliability of shallow failure surfaces and overly conservative results for deeper failure surfaces.  相似文献   

Biotite Reference Materials for Secondary Ion Mass Spectrometry 18O/16O Measurements          下载免费PDF全文

Guillaume Siron  Lukas Baumgartner  Anne‐Sophie Bouvier  Benita Putlitz  Torsten Vennemann 《Geostandards and Geoanalytical Research》2017,41(2):243-253

Five new biotite reference materials were calibrated at the SwissSIMS laboratory (University of Lausanne) for oxygen isotope determination by secondary ion mass spectrometry (SIMS) and are available to the scientific community. The oxygen isotope composition of the biotites, UNIL_B1 to B5, was determined by laser‐heating fluorination to be 11.4 ± 0.11‰, 8.6 ± 0.15‰, 6.1 ± 0.04‰, 7.1 ± 0.05‰ and 7.6 ± 0.04‰, respectively. SIMS analyses on spots smaller than 20 μm gave a measurement repeatability of 0.3‰ (2 standard deviation, 2s). The matrix effect due to solid solution in natural biotite could be expressed as a linear function of X_Mg and X_F for biotite. No effect was found for different crystallographic orientations. SIMS analysis allows the oxygen isotope composition of biotite to be measured with a measurement uncertainty of 0.3–0.4‰ (2s) for biotites with similar major element compositions. A measurement uncertainty of 0.5‰ (2s) is realistic when F poor biotites (lower than 0.2% m/m oxides) within the compositional range of X_Mg of 0.3–0.9 were compared from different sessions. The linear correlation with F content offers a reasonable working curve for F‐rich biotites, but additional reference materials are needed to confirm the model.  相似文献   

Geochemistry,Zircon U–Pb Analysis,and Biotite 40Ar/39Ar Geochronology of the Maoling Gold Deposit,Liaodong Rift,NE China          下载免费PDF全文

Peng Zhang  Yan Zhao  Peng Chai  Hong‐Zhi Yang  Fu‐Chao Na 《Resource Geology》2017,67(4):426-441

The Maoling gold deposit is located in the southwestern part of the Liaodong rift, NE China, and has estimated reserves of 25 t. In this paper we present the results of an investigation into the geochronology and geodynamic mechanisms of igneous activity and metallogenesis within the Maoling gold deposit. New zircon U–Pb age data, biotite ⁴⁰Ar/³⁹Ar age data, whole‐rock geochemistry, and Hf isotopic analyses are presented in order to constrain the petrogenesis and mineralization of the deposit. Zircon U–Pb dating of the Wolongquan biotite monzogranite and Maoling biotite granite yielded mean ages of 194.0 ± 1.1 Ma and 196.1 ± 1.1 Ma, respectively. All the granites are characteristically high‐K calc‐alkaline, enriched in light rare earth elements and large ion lithophile elements, and depleted in high field strength elements, which is consistent with the geochemical characteristics of arc‐type magmas. The Hf isotope characteristics indicate that the granites formed by partial melting of early Paleoproterozoic crustal material. In addition, biotite ⁴⁰Ar/³⁹Ar dating indicates that the Maoling gold deposit formed at 188.9 ± 1.2 Ma, implying that the mineralization was related to both the granite intrusions. Taking into account previous data on S–Pb–O–H isotopes and our new age data, the Maoling deposit can be classified as an intrusion‐related gold deposit. Taking into account the geology of the study area and adjacent regions, we propose that the Maoling gold deposit and its associated granitic intrusions formed in a geodynamic setting that was dominated by subduction of the Paleo‐Pacific Plate beneath the Eurasian continent.  相似文献   

Fluid Inclusions and Hydrogen,Oxygen, and Lead Isotopes of the Antuoling Molybdenum Deposit,Northern Taihang Mountains,China   总被引：1，自引：0，他引：1       下载免费PDF全文

Meng Zhe  Jian‐zhong Hu  Yang Song  Xue‐qin Zhang  Hai‐yang Ding  Wei Zhou 《Resource Geology》2017,67(4):399-413

The Antuoling Mo deposit is a major porphyry‐type deposit in the polymetallic metallogenic belt of the northern Taihang Mountains, China. The processes of mineralization in this deposit can be divided into three stages: an early quartz–pyrite stage, a middle quartz–polymetallic sulfide stage, and a late quartz–carbonate stage. Four types of primary fluid inclusions are found in the deposit: two‐phase aqueous inclusions, daughter‐mineral‐bearing multiphase inclusions, CO₂–H₂O inclusions, and pure CO₂ inclusions. From the early to the late ore‐forming stages, the homogenization temperatures of the fluid inclusions are 300 to >500°C, 270–425°C, and 195–330°C, respectively, with salinities of up to 50.2 wt%, 5.3–47.3 wt%, and 2.2–10.4 wt% NaCl equivalent, revealing that the ore‐forming fluids changed from high temperature and high salinity to lower temperature and lower salinity. Moreover, based on the laser Raman spectra, the compositions of the fluid inclusions evolved from the NaCl–CO₂–H₂O to the NaCl–H₂O system. The δ¹⁸O_H2O and δD values of quartz in the deposit range from +3.9‰ to +7.0‰ and ?117.5‰ to ?134.2‰, respectively, reflecting the δD of local meteoric water after oxygen isotopic exchange with host rocks. The Pb isotope values of the sulfides (²⁰⁸Pb/²⁰⁴Pb, 36.320–37.428; ²⁰⁷Pb/²⁰⁴Pb, 15.210–15.495; ²⁰⁶Pb/²⁰⁴Pb, 16.366–17.822) indicate that the ore‐forming materials originated from a mixed upper mantle–lower crust source.  相似文献   

Sedimentary roles on hyporheic exchange in karst conduits at low Reynolds numbers by laboratory experiments     

Wu  Yuexia  Hunkeler  Daniel 《Hydrogeology Journal》2017,25(3):787-798

Hydrogeology Journal - The relative roles of the sediment grain size/permeability, conduit flow rate and conduit geometry/angle on the hyporheic exchange between a karst conduit and its underlying...  相似文献   

GGR Biennial Critical Review: Analytical Developments Since 2014          下载免费PDF全文

Kathryn L. Linge  L. Paul Bédard  Roxana Bugoi  Jacinta Enzweiler  Klaus Peter Jochum  Rüdiger Kilian  Jingao Liu  Johanna Marin‐Carbonne  Silke Merchel  Frans Munnik  Luiz F.G. Morales  Claire Rollion‐Bard  A. Kate Souders  Paul J. Sylvester  Ulrike Weis 《Geostandards and Geoanalytical Research》2017,41(4):493-562

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.  相似文献   

Instrumentation Development for In Situ 40Ar/39Ar Planetary Geochronology          下载免费PDF全文

Leah E. Morgan  Madicken Munk  Brett Davidheiser‐Kroll  Nicholas H. Warner  Sanjeev Gupta  Rachel Slaybaugh  Patrick Harkness  Darren F. Mark 《Geostandards and Geoanalytical Research》2017,41(3):381-396

The chronology of the Solar System, particularly the timing of formation of extra‐terrestrial bodies and their features, is an outstanding problem in planetary science. Although various chronological methods for in situ geochronology have been proposed (e.g., Rb‐Sr, K‐Ar), and even applied (K‐Ar), the reliability, accuracy, and applicability of the ⁴⁰Ar/³⁹Ar method makes it by far the most desirable chronometer for dating extra‐terrestrial bodies. The method however relies on the neutron irradiation of samples, and thus a neutron source. Herein, we discuss the challenges and feasibility of deploying a passive neutron source to planetary surfaces for the in situ application of the ⁴⁰Ar/³⁹Ar chronometer. Requirements in generating and shielding neutrons, as well as analysing samples are described, along with an exploration of limitations such as mass, power and cost. Two potential solutions for the in situ extra‐terrestrial deployment of the ⁴⁰Ar/³⁹Ar method are presented. Although this represents a challenging task, developing the technology to apply the ⁴⁰Ar/³⁹Ar method on planetary surfaces would represent a major advance towards constraining the timescale of solar system formation and evolution.  相似文献   

Probabilistic evaluation of tunnel face stability in spatially random soils using sparse polynomial chaos expansion with global sensitivity analysis     

Qiujing Pan  Daniel Dias 《Acta Geotechnica》2017,12(6):1415-1429

The sparse polynomial chaos expansion is employed to perform a probabilistic analysis of the tunnel face stability in the spatially random soils. A shield tunnel under compressed air is considered which implies that the applied pressure is uniformly distributed on the tunnel face. Two sets of failure mechanisms in the context of the limit analysis theory with respect to the frictional and the purely cohesive soils are used to calculate the required face pressure. In the case of the frictional soils, the cohesion and the friction angle are modeled as two anisotropic cross-correlated lognormal random fields; for the purely cohesive soils, the cohesion and the unit weight are modeled as two anisotropic independent lognormal random fields. The influences of the spatial variability and of the cross-correlation between the cohesion and the friction angle on the probability density function of the required face pressure, on the sensitivity index and on the failure probability are discussed. The obtained results show that the spatial variability has an important influence on the probability density function as well as the failure probability, but it has a negligible impact on the Sobol’s index.  相似文献   

Learning soil parameters and updating geotechnical reliability estimates under spatial variability – theory and application to shallow foundations     

Iason Papaioannou  Daniel Straub 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2017,11(1):116-128

ABSTRACT

Field data is commonly used to determine soil parameters for geotechnical analysis. Bayesian analysis allows combining field data with other information on soil parameters in a consistent manner. We show that the spatial variability of the soil properties and the associated measurements can be captured through two different modelling approaches. In the first approach, a single random variable (RV) represents the soil property within the area of interest, while the second approach models the spatial variability explicitly with a random field (RF). We apply the Bayesian concept exemplarily to the reliability assessment of a shallow foundation in a silty soil with spatially variable data. We show that the simpler RV approach is applicable in cases where the measurements do not influence the correlation structure of the soil property at the vicinity of the foundation. In other cases, it is expected to underestimate the reliability, and a RF model is required to obtain accurate results.  相似文献