Physical processes contributing to the water mass transformation of the Indonesian Throughflow   总被引：1，自引：1，他引：0  

Ariane Koch-Larrouy  Gurvan Madec  Daniele Iudicone  Agus Atmadipoera  Robert Molcard 《Ocean Dynamics》2008,58(3-4):275-288

The properties of the waters that move from the Pacific to the Indian Ocean via passages in the Indonesian archipelago are observed to vary with along-flow-path distance. We study an ocean model of the Indonesian Seas with reference to the observed water property distributions and diagnose the mechanisms and magnitude of the water mass transformations using a thermodynamical methodology. This model includes a key parameterization of mixing due to baroclinic tidal dissipation and simulates realistic water property distributions in all of the seas within the archipelago. A combination of air–sea forcing and mixing is found to significantly change the character of the Indonesian Throughflow (ITF). Around 6 Sv (approximately 1/3 the model net ITF transport) of the flow leaves the Indonesian Seas with reduced density. Mixing transforms both the intermediate depth waters (transforming 4.3 Sv to lighter density) and the surface waters (made denser despite the buoyancy input by air–sea exchange, net transformation?=?2 Sv). The intermediate transformation to lighter waters suggests that the Indonesian transformation contributes significantly to the upwelling of cold water in the global conveyor belt. The mixing induced by the wind is not driving the transformation. In contrast, the baroclinic tides have a major role in this transformation. In particular, they are the only source of energy acting on the thermocline and are responsible for creating the homostad thermocline water, a characteristic of the Indonesian outflow water. Furthermore, they cool the sea surface temperature by between 0.6 and 1.5°C, and thus allow the ocean to absorb more heat from the atmosphere. The additional heat imprints its characteristics into the thermocline. The Indonesian Seas cannot only be seen as a region of water mass transformation (in the sense of only transforming water masses in its interior) but also as a region of water mass formation (as it modifies the heat flux and induced more buoyancy flux). This analysis is complemented with a series of companion numerical experiments using different representations of the mixing and advection schemes. All the different schemes diagnose a lack of significant lateral mixing in the transformation.  相似文献   

Chromium(VI) reduction by sulphur(IV) in aqueous solutions     

Maurizio Pettine  Daniele Tonnina  Frank J. Millero 《Marine Chemistry》2006,99(1-4):31

The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔH_app of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression