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21.
María del Carmen Blanco Juan Darío Paoloni Hector Morrás Carmen Fiorentino Mario Eduardo Sequeira Nilda N. Amiotti Oscar Bravo Silvana Diaz Martín Espósito 《Environmental Earth Sciences》2012,66(7):2075-2084
Excessive arsenic concentrations above the Argentinean and WHO guidelines for drinking water (10 μg L−1) affects shallow aquifers of the southern Pampean Plain (Argentina) hosted in the Pampean and the Post Pampean formations
(loess and reworked loess; Plio-Pleistocene–Holocene). Health problems related to high As concentrations in drinking waters
are known as Endemic Regional Chronic Hydroarsenicism. Hydrochemistry of shallow groundwaters and soil geochemistry were investigated
aiming to (1) understand the partition of As in the solid phase and its relationship with unacceptable As concentrations in
waters, (2) identify the provision source of As to groundwaters. Only 5% of the samples had As concentrations <10 μg L−1; in 27% As concentrations ranged from 10 to 50 μg L−1 and in 58% it reached 60–500 μg L−1. The coarse fraction (50–2,000 μm) hosts about 27% of the total As in the solid phase, being positively correlated to Ba
(p < 0.01; r
2 = 0.93). About 70% is included in the <2 μm fraction and had positive correlations of As–Fe (p < 0.05; r
2 = 0.85) and As–Cr (p < 0.05; r
2 = 0.68). Soils and sediment sand fractions of vadose zones are the primary sources of As in shallow groundwater while adsorption–desorption
processes, codisolution–coprecipitation, and evaporation during the dry seasons raise As concentrations in waters exceeding
the guideline value for drinking water. 相似文献
22.
Major, trace and rare earth elements of phosphatic rocks around Sonrai block of Paleo-Mesoproterozoic age having phosphatic breccia, quartzite, shale, sandstone, limestone and ironstone, have been determined to evaluate their correlation, relationship with the phosphorus content, the nature of possible substitution of various elements and regional distribution pattern over the area. The study indicates that the number of elements is substituted in the apatite structures; few of them are associated with phosphate and carbonate minerals. The variable concentration of major, trace and rare earth elements in the phosphatic rocks has been influenced by various physico-chemical processes involved during weathering and leaching of the source rocks. The distribution of the major, trace and rare earth elements is controlled by the environmental variations in the sediment water interface. The majority of trace elements were mainly influenced by the principle adsorbents like the phosphate minerals in addition to clay, iron oxides and silicate minerals. The PAAS normalized REE patterns of Sonrai block of phosphorites are characterized by negative Ce anomalies and Positive Eu anomalies. It is inferred from the distribution and interrelationship of major, trace and rare earth elements that the deposition of phosphate minerals might have occurred in highly oxidizing to slightly reducing conditions in supratidal to intertidal continental margins and shallow marine environment. The deposition was controlled by marine upwelling leading to excess charge of phosphate in certain zones of phosphogenic basins, lithologic facies variations in restricted circulations of basinal waters and electrochemical factors such as negative Eh, pH and other factors, which influenced the deposition of phosphates. The replacement, precipitation in voids and fissures and diagenesis were also important mechanisms of phosphate generation in Sonrai basin. The main source for various elements may be the minerals of cratonic mass of Bundelkhand Granitic Complex, a basement of Bijawar Basin, which also provided land derived phosphorus through weathering of the terrestrial cover. 相似文献
23.
Spectrally based remote sensing of river bathymetry 总被引：1，自引：0，他引：1
This paper evaluates the potential for remote mapping of river bathymetry by (1) examining the theoretical basis of a simple, ratio‐based technique for retrieving depth information from passive optical image data; (2) performing radiative transfer simulations to quantify the effects of suspended sediment concentration, bottom reflectance, and water surface state; (3) assessing the accuracy of spectrally based depth retrieval under field conditions via ground‐based reflectance measurements; and (4) producing bathymetric maps for a pair of gravel‐bed rivers from hyperspectral image data. Consideration of the relative magnitudes of various radiance components allowed us to define the range of conditions under which spectrally based depth retrieval is appropriate: the remotely sensed signal must be dominated by bottom‐reflected radiance. We developed a simple algorithm, called optimal band ratio analysis (OBRA), for identifying pairs of wavelengths for which this critical assumption is valid and which yield strong, linear relationships between an image‐derived quantity X and flow depth d. OBRA of simulated spectra indicated that water column optical properties were accounted for by a shorter‐wavelength numerator band sensitive to scattering by suspended sediment while depth information was provided by a longer‐wavelength denominator band subject to strong absorption by pure water. Field spectra suggested that bottom reflectance was fairly homogeneous, isolating the effect of depth, and that radiance measured above the water surface was primarily reflected from the bottom, not the water column. OBRA of these data, 28% of which were collected during a period of high turbidity, yielded strong X versus d relations (R2 from 0·792 to 0·976), demonstrating that accurate depth retrieval is feasible under field conditions. Moreover, application of OBRA to hyperspectral image data resulted in spatially coherent, hydraulically reasonable bathymetric maps, though negative depth estimates occurred along channel margins where pixels were mixed. This study indicates that passive optical remote sensing could become a viable tool for measuring river bathymetry. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
24.
Jorge Moreda-Piñeiro Elia Alonso-Rodríguez Isabel Turnes-Carou Carmen Moscoso-Pérez Gustavo Blanco-Heras Loreto Gómez Tellado Purificación López-Mahía Soledad Muniategui-Lorenzo Darío Prada-Rodríguez 《Journal of Atmospheric Chemistry》2017,74(1):1-21
The inorganic chemical composition (major ions and trace metals) of bulk deposition samples collected monthly with bulk collectors at seven Atlantic Coastal European cities (Galicia, Northwest of Spain) during wet season (September 2011 to March 2012) has been assessed and compared. Trace metals (Al, As, Ba, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, V and Zn) were analysed in soluble fraction and non-soluble fraction (after acid extraction) of the bulk deposition by inductively coupled plasma-mass spectrometry. Major inorganic ions (Cl?, NO3 ?, SO4 2?, Na+, K+, Ca2+, Mg2+ and NH4 +) were analysed in the soluble fraction of the bulk deposition by capillary zone electrophoresis. Univariate analysis (ANOVA and Multiple Range Test) according to the location of each sampling site was performed. Results also suggest a great influence of cleaner Atlantic air masses. After partition coefficients and enrichment factor estimation, similar sources could be assigned for the ionic and metal composition of bulk deposition at seven urban sites. 相似文献
25.
26.
Marc Mayes Kelly K. Caylor Michael Bliss Singer John C. Stella Dar Roberts Pamela Nagler 《水文研究》2020,34(25):4884-4903
Semi-arid riparian woodlands face threats from increasing extractive water demand and climate change in dryland landscapes worldwide. Improved landscape-scale understanding of riparian woodland water use (evapotranspiration, ET) and its sensitivity to climate variables is needed to strategically manage water resources, as well as to create successful ecosystem conservation and restoration plans for potential climate futures. In this work, we assess the spatial and temporal variability of Cottonwood (Populus fremontii)-Willow (Salix gooddingii) riparian gallery woodland ET and its relationships to vegetation structure and climate variables for 80 km of the San Pedro River corridor in southeastern Arizona, USA, between 2014 and 2019. We use a novel combination of publicly available remote sensing, climate and hydrological datasets: cloud-based Landsat thermal remote sensing data products for ET (Google Earth Engine EEFlux), Landsat multispectral imagery and field data-based calibrations to vegetation structure (leaf-area index, LAI), and open-source climate and hydrological data. We show that at landscape scales, daily ET rates (6–10 mm day−1) and growing season ET totals (400–1,400 mm) matched rates of published field data, and modelled reach-scale average LAI (0.80–1.70) matched lower ranges of published field data. Over 6 years, the spatial variability of total growing season ET (CV = 0.18) exceeded that of temporal variability (CV = 0.10), indicating the importance of reach-scale vegetation and hydrological conditions for controlling ET dynamics. Responses of ET to climate differed between perennial and intermittent-flow stream reaches. At perennial-flow reaches, ET correlated significantly with temperature, whilst at intermittent-flow sites ET correlated significantly with rainfall and stream discharge. Amongst reaches studied in detail, we found positive but differing logarithmic relationships between LAI and ET. By documenting patterns of high spatial variability of ET at basin scales, these results underscore the importance of accurately accounting for differences in woodland vegetation structure and hydrological conditions for assessing water-use requirements. Results also suggest that the climate sensitivity of ET may be used as a remote indicator of subsurface water resources relative to vegetation demand, and an indicator for informing conservation management priorities. 相似文献
27.
Farooq Ahmad Dar Jerome Perrin Shakeel Ahmed Allu China Narayana 《Hydrogeology Journal》2014,22(7):1493-1506
About 3 % of India’s total land surface is occupied by carbonate rocks which are mostly karstified and constitute a significant source of groundwater. The groundwater drawn from these aquifers matches the water demand of ~35 million people living in 106 districts of the country and also the water needs of livestock, irrigation and industry. The studies on karst in India carried out so far have mostly addressed geology, hydrology and groundwater contamination. A literature survey suggests that there is a need for detailed research, applying new approaches and techniques for proper carbonate aquifer identification, characterization and management. Such specific approaches will improve modeling, exploitation and protection of karst groundwater. An overview of the research carried out on groundwater resources of karst formations in India is presented, which also throws light on the protection of karst aquifers from existing anthropogenic activities such as mining and groundwater over-exploitation. 相似文献
28.
Distribution patterns of some heavy metals in the surface sediment fractions at northern Safaga Bay, Red Sea, Egypt 总被引：2，自引：0，他引：2
Mahmoud A. Dar 《Arabian Journal of Geosciences》2014,7(1):55-67
The distribution patterns, the index of geo-accumulations (MIgeo), and the enrichment ratios (ER n ) of the contaminant metals: Fe, Mn, Zn, Cu, Pb, and Ni were studied in gravel, sand, mud, coarse, medium, and fine sediment fractions of the uppermost layer of the bottom sediments collected from 12 stations covering the northern part of Safaga Bay. The distribution levels of these metals were increasing with grain size decreasing toward the central axis of the bay that extends NE–SW and southward to Safaga Harbour indicating that these metals concentrated mainly in the fine, very fine, and particulate fractions of sediments and to many anthropogenic sources. The geo-accumulation factor of Zn was more significant (MIgeo?≈?0.62–4.23) relative to the other metals. The bay was classified as moderately to strongly polluted by Zn while it is unpolluted to moderately polluted with the other metals with accumulation sequence of: Zn>Ni>Cu>Mn≥Pb. Zn and Ni recorded the highest enrichment ratios (average ERZn?≈?3.07 to 8.89; average ERNi?≈?0.84 to 3.63) in the different sediment fractions relative the other metals. These enrichment ratios classified the bay as minimal enrichment, suggestive of no or minimal pollution, to significant enrichment, suggestive of a significant pollution signals with metals sequence of: Zn>Ni>Cu>Pb>Mn. 相似文献
29.
The concentrations of six heavy metals (Fe, Mn, Ni, Cu, Pb and Zn) were studied in 11 hard and 4 soft common coral species
collected from Hurghada, Wadi Al-Gemal and Gola’an along the Red Sea coast to assess the differential abilities of corals
to concentrate and assimilate the heavy metals inside soft coral tissues and hard coral skeletons. These results reveal the
order of Fe > Zn > Ni > Pb ≥ Mn > Cu. Fe recorded significant high concentrations in mushroom (funnel) forms of the soft corals
at the different sites; 125.19, 101.71 and 90.44 ppm at Gola’an, Hurghada and Wadi Al-Gemal, respectively. The soft coral
species recorded the highest average concentration of Mn, Ni, Cu and Zn than the hard corals, which were 13.22, 16.05, 13.08
and 148.17 ppm, respectively. Generally, soft corals show higher metal concentrations than the hard ones; moreover, Hurghada
recorded a higher trend of metal concentrations in soft and hard corals than the other sites. The study concluded that many
biological and local environmental factors influenced the metal occurrences and uptakes in both coral forms such as, the exposed
surface area for metal uptake, turbidity, overlying mucus thickness and the ability of metals to substitute inside the crystal
lattice of the hard corals. 相似文献
30.
L. V. Zamana A. B. Ptitsyn G. Chu S. A. Reshetova A. V. Dar’in I. A. Kalugin 《Doklady Earth Sciences》2011,437(1):335-339
On the basis of bottom sediment core dating performed by the technogenic isotope 137Cs, the rate of sedimentation in periodically drying Zun-Torei Lake (water area is up to 300 km2) is estimated at 2.88 mm per year over the last 59 years. This value is in agreement with the data of palinological determinations
(3.44 mm per year). High sedimentation rates are attributed to intensive evaporite sedimentation and probable eolian addition
of terrigenous material. 相似文献