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211.
Low pressure-high temperature (LPHT) metamorphism, with geothermal gradients in the order of 50–100°C/km, is a common feature of the late evolution of collisional orogens. These abnormal thermal conditions may be the results of complex interactions between magmatism, metamorphism and deformation. The Agly massif, in the French Pyrenees, preserves the metamorphic footprints of the late Variscan thermal structure of an almost continuous section from the upper and middle continental crust. The upper crust is characterized by a very high geothermal gradient of ~55°C/km, evolving from greenschist to amphibolite facies, while the middle crust, exposed in a gneissic core, exhibits granulite facies conditions with a near isothermal geothermal gradient (<8°C/km) between 740 and 790°C. The abnormal and discontinuous crustal geothermal gradient, dated at c. 305 Ma on syn-granulitic monazite by LA-ICP-MS, is interpreted to be the result of magmatic intrusions at different structural levels in the crust: the Ansignan charnockite (c. 305 Ma) in the deepest part of the gneissic core, the Tournefort granodiorite (c. 308 Ma) at the interface between the gneissic core and the upper crust and the Saint-Arnac granite (c. 304 Ma) in the upper section of the massif. The heat input from these magmas combined with the thermal buffering effect of the biotite dehydration-melting reaction resulted in the near isothermal geothermal gradient in the gneissic core (melt-enhanced geotherm). The higher geothermal gradient (>50°C/km) in the upper crust is only due to conduction between the hot middle crust and the Earth's surface. The estimated maximum finite pressure range suggests that ~10 to 12 km of crust are exposed in the Agly massif while the present-day thickness does not exceed 5–6 km. This pressure/depth gap is consistent with the presence of several normal mylonitic shear zones that could have contributed to the subtraction of ~5 km of the rock pile. Monazite U–Th–Pb ages carried out on monazite overgrowths from a highly mylonitized sample suggest that this vertical thinning of the massif occurred at c. 296–300 Ma. This later Variscan extension might have slightly perturbed the 305 Ma geothermal gradient, resulting in an apparent higher conductive geothermal gradient in the upper crust. Although the Agly massif has been affected by Cretaceous extension and Eocene Alpine compression, we suggest that most of the present-day thickness of the column rock was acquired by the end of the Palaeozoic.  相似文献   
212.
The 8.2 ka bp cooling event is assumed to be the most clearly marked abrupt climate event in the Holocene at northern mid‐ to high latitudes. In this study, we simulate the vegetation responses to the 8.2 ka bp climate change event over Europe and Northern Africa. Our results show that all dominant plant functional types (PFTs) over Europe and North Africa respond to these climate changes, but the magnitude, timing and impact factor of their responses are different. Compared with pollen‐based vegetation reconstructions, our simulation generally captures the main features of vegetation responses to the 8.2 ka bp event. Interestingly, in Western Europe, the simulated vegetation after perturbation is different from its initial state, which is consistent with two high‐resolution pollen records. This different vegetation composition indicates the long‐lasting impact of abrupt climate change on vegetation through eco‐physiological and ecosystem demographic processes, such as plant competition. Moreover, our simulations suggest a latitudinal gradient in the magnitude of the event, with more pronounced vegetation responses to the severe cooling in the north and weaker responses to less severe cooling in the south. This effect is not seen in pollen records. © 2019 The Authors. Journal of Quaternary Science Published by John Wiley & Sons, Ltd.  相似文献   
213.
Solar UV radiation is a major source of energy for chemical evolution of organic materials in the Solar System. Therefore studies on the photostability of organic compounds in extraterrestrial environments are of prime importance for the understanding of the extraterrestrial origin of organic materials on Earth. A series of organic samples have been photolysed in Earth orbit during the ESA BIOPAN 6 mission (14-26/09/2007). Their photochemical lifetime has been measured and compared to results recorded in the laboratory using a lamp that simulates the solar radiation in the VUV domain. The half-lives at a distance of 1 AU from the Sun have been measured for glycine, xanthine, hypoxanthine, adenine, guanine, urea, carbon suboxide polymer ((C3O2)n) and HCN polymer. They range from a few days to a lower limit of a few tens of days for the most photoresistant (e.g. adenine, guanine, hypoxanthine). Lifetimes measured in terrestrial orbit are very different from those derived with laboratory experiments. These measurements confirm that it is difficult to simulate the solar spectrum below 200 nm in the laboratory. Results are discussed and highlight the necessity to conduct experiments in orbit, and for longer duration. It also appears that the laboratory measurements made in VUV must be extrapolated very cautiously to the different environments they are supposed to simulate.  相似文献   
214.
We report on a comprehensive analysis of the kilohertz (≥300 Hz) quasi-periodic oscillations (kHz QPOs) detected from the neutron star low-mass X-ray binary 4U 0614+09 with the Rossi X-ray Timing Explorer. With a much larger data set than previously analysed (all archival data from 1996 February up to 2007 October), we first investigate the reality of the 1330 Hz QPO reported by van-Straaten et al. This QPO would be of particular interest since it has the highest frequency reported for any source. A thorough analysis of the same observation fails to confirm the detection. On the other hand, over our extended data set, the highest QPO frequency we measure for the upper kHz QPO is at ∼1224 Hz; a value which is fully consistent with the maximum values observed in similar systems. Secondly, we demonstrate that the frequency dependence of the quality factor  ( Q =ν/Δν)  and amplitude of the lower and upper kHz QPOs follow the systematic trends seen in similar systems. In particular, 4U 0614+09 shows a drop of the quality factor of the lower kHz QPO above ∼700 Hz. If this is due to an approach to the innermost stable circular orbit, it implies a neutron star mass of  ∼1.9 M  . Finally, when analysing the data over fixed durations, we have found a gap in the frequency distribution of the upper QPO, associated with a local minimum of its amplitude. A similar gap is not present in the distribution of the lower QPO frequencies, suggesting some cautions when interpreting frequency ratio distributions, based on the occurrence of the lower QPO only.  相似文献   
215.
The vertical distribution of reduced sulfur species (RSS including H2S/HS, S0, electroactive FeS) and dissolved Fe(II) was studied in the anoxic water column of meromictic Lake Pavin. Sulfide concentrations were determined by two different analytical techniques, i.e. spectophotometry (methylene blue technique) and voltammetry (HMDE electrode). Total sulfide concentrations determined with methylene blue method (∑H2SMBRS) were in the range from 0.6 µM to 16.7 µM and were substantially higher than total reduced sulfur species (RSSV) concentrations determined by voltammetry, which ranged from 0.1 to 5.6 μM. The observed difference in the sulfide concentrations between the two methods can be assigned to the presence of FeS colloidal species.Dissolved Fe was high (> 1000 µM), whereas dissolved Mn was only 25 µM, in the anoxic water column. This indicates that Fe is the dominant metal involved in sulfur redox cycling and precipitation. Consequently, in the anoxic deep layer of Lake Pavin, “free” sulfide, H2S/HS, was low; and about 80% of total sulfide detected was in the electroactive FeS colloidal form. IAP calculations showed that the Lake Pavin water column is saturated with respect to FeSam phase. The upper part of monimolimnion layer is characterized by higher concentrations of S(0) (up to 3.4 µM) in comparison to the bottom of the lake. This behavior is probably influenced by sulfide oxidation with Fe(III) oxyhydroxide species.  相似文献   
216.
Chemical mass transfer was quantified in a metacarbonate xenolith enclosed within the granodiorite of the Quérigut massif (Pyrenees, France). Mass balance calculations suggest a strong decrease of CaO, SrO and CO2 contents (up to −90%), correlated with a decrease of modal calcite content as the contact is approached. Most other chemical elements behave immobile during metasomatism. They are therefore passively enriched. Only a small increase of SiO2, Al2O3 and Fe2O3 contents occurs in the immediate vicinity of the contact. Hence, in this study, skarn formation is characterized by the lack of large chemical element influx from the granitoid protolith. A large decrease of the initial carbonate volume (up to −86%) resulted from a combination of decarbonation reactions and loss of CaO and CO2. The resulting volume change has potentially important consequences for the interpretation of stable isotope profiles: the isotope alteration could have occured over greater distances than those observed today.  相似文献   
217.
A relative water-depth model for the Chalk of the Paris Basin is proposed, based on the lateral variations of the high-frequency metre-scale cycles, which are characteristic features easily identified in the field. The studied outcrops are the Cenomanian–Middle Coniacian cliffs of Normandy. The main result of this study is to highlight the importance of storm activity in the deposition of the Chalk. The relative water-depth model is based on storm-induced shell concentrations observed within the two components of the metre-thick cycles: the depositional interval itself and the top hiatal surface.Six types of shell concentrations are defined, along with seven types of depositional facies making up the depositional units, as well as eight types of hiatal surface. Three cycle associations, differing in their thickness and the amount and type of non-carbonate constituents, can be identified in the Lower to Upper Cenomanian, the Upper Cenomanian to Lower Turonian and the Middle Turonian to Middle Coniacian.A relative water-depth profile model for all these cycles is based on the shell concentrations and a “water-depth equivalence” is proposed between the three cycle associations (lateral “facies” substitution diagram). This model is tested using palaeocological data (irregular echinoids) and by correlating field sections in terms of stacking patterns. Most of the studied deposits accumulated above the storm wave base (upper offshore zone or mid ramp).  相似文献   
218.
219.
The Aar Massif forms part of the polycyclic basement of the External Crystalline Massifs in central Switzerland. Strong heterogeneous Alpine deformation produced a network of broad, anastomosing shear zones, with deformation strongly localized in mylonitic domains. This study investigates the combined effects of high‐strain deformation and synkinematic metamorphism on magnetic fabric evolution in Tertiary shear zones of the Aar granite and Grimsel granodiorite. In transects across several mesoscale shear zones with large strain gradients, magnetic fabric orientations are in excellent agreement with principal strain orientations determined from outcrop fabrics and strain markers. However, the magnitude and shape of the magnetic anisotropy do not change systematically with increasing finite strain, likely as a result of recrystallization and metamorphism. The overall pattern of steeply dipping fabrics is consistent with the main shortening stage of regional Alpine kinematics, while some mylonite structures reflect a local component of dextral shearing.  相似文献   
220.
Recent scientific work has highlighted the presence of an up to 12 km thick Cenozoic siliclastic and carbonate infill in the Levant Basin. Since the Late Eocene, several regional geodynamic events affecting Afro‐Arabia and Eurasia (collision and strike slip deformation) induced marginal uplifts. The initiation of local and long‐lived regional drainage systems in the Oligo‐Miocene period (e.g., Lebanon, Arabia and Nile) provoked a change in the depositional pattern along the Levant region from carbonate‐dominated to mixed clastic‐rich systems. Herein, we explore the importance of multi‐scale constraints (i.e., seismic, well and field data) in the quantification of subsidence history, sediment transport and deposition of a Middle to Upper Miocene “multi‐source” to sink system along the northern Levant frontier region. Through a comprehensive 4D forward stratigraphic modelling workflow, we suggest that the contribution to basin infill is split between proximal and more distal clastic sources as well as in situ carbonate and hemipelagic deposition. The results show that single‐source scenarios could not reasonably satisfy the basin‐scale constraints. The worldwide application of such new multi‐disciplinary workflows in frontier regions highlights the additional data constraints that are needed to de‐risk highly uncertain geological models in the hydrocarbon exploration phase.  相似文献   
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