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331.
Both Atlantic and Indian Ocean climate dynamics exert influence over tropical African hydroclimate, producing complex patterns of convergence and precipitation. To isolate the Indian Ocean influence on African paleohydrology, we analyzed the deuterium/hydrogen ratio of higher plant leaf waxes (δDwax) in a 25 000-year sediment record from Lake Challa (3° S, 38° E) in the easternmost area of the African tropics. Whereas both the seismic record of inferred lake level fluctuations and the Branched and Isoprenoidal Tetraether (BIT) index proxy record changes in hydrology within the Challa basin, δDwax, as a proxy for the isotopic composition of precipitation (δDP) is interpreted as a tracer of large-scale atmospheric circulation that integrates the history of the moisture transported to the Lake Challa area. Specifically, based on modern-day isotope–rainfall relationships, we argue that Lake Challa δDwax reflects the intensity of East African monsoon circulation. The three hydrological proxy records show generally similar trends for the last 25 000 years, but there are important differences between them, primarily during the middle Holocene. We interpret this deviation of δDwax from local hydrological history as a decoupling of East African monsoon intensity – which heavily influences the isotopes of precipitation in East Africa today – from rainfall amount in the Challa basin. In combination, the hydrological proxy data from Lake Challa singularly highlight zonal gradients in tropical African climate that occur over a variety of timescales, suggesting that the Congo Air Boundary plays a fundamental role in controlling hydroclimate in the African tropics.  相似文献   
332.
Peatlands play a major role in the global carbon cycle but are largely overlooked in current large-scale vegetation mapping efforts. In this study, we investigated the potential of the Moderate Resolution Imaging Spectroradiometer (MODIS) to capture the extent and distribution of peatlands in the St. Petersburg region of Russia by analyzing the relationships between peatland cover fractions derived from reference maps and  1-km resolution MODIS Nadir BRDF-Adjusted Reflectance (NBAR) data from year 2002.First, we characterized and mapped 50 peatlands from forest inventory and peat deposit inventory data. The peatlands represent three major nutritional types (oligotrophic, mesotrophic, eutrophic) and different sizes (0.6–7800 ha). In addition, parts of 6 peatlands were mined for peat and these were mapped separately. The reference maps provided information on peatland cover for 1105 MODIS pixels. We performed regression analysis on 50% of the pixels and reserved the remainder for model validation. Canonical correlation analysis on the MODIS reflectance bands and the peatland cover fractions produced a multi-spectral peatland cover index (PCI), which served as the predictor in a reduced major axis (RMA) regression model. The results suggest a high potential for mapping peatlands with MODIS. The RMA regression models explained much of the variance in the PCI (r2 = 0.74 for mined and r2 = 0.81 for unmined peatlands). Model validation showed high correlation between observed versus predicted peatland cover (mined: r = 0.87; unmined: r = 0.92). We used the models to derive peatland cover estimates for the St. Petersburg region and compared the results to current MODIS land cover maps.  相似文献   
333.
Monthly temperature series for Central Europe back to AD 1500 are developed from documentary index series from Germany, Switzerland and the Czech Republic (1500–1854) and 11 instrumental temperature records (1760–2007). Documentary evidence from the Low Countries, the Carpathian Basin and Poland are used for cross-checking for earlier centuries. The instrumental station records are corrected for inhomogeneities, including insufficient radiation protection of early thermometers and the urban heat island effect. For overlapping period (1760–1854), the documentary data series correlate with instrumental temperatures, most strongly in winter (86% explained variance in January) and least in autumn (56% in September). For annual average temperatures, 81% of the variance is explained. Verification statistics indicate high reconstruction skill for most months and seasons. The last 20 years (since 1988) stand out as very likely the warmest 20-year period, accounting for the calibration uncertainty and decreases in proxy data quality before the calibration period. The new reconstruction displays a previously unobserved long-term decrease in DJF, MAM and JJA temperature variability over last five centuries. Compiled monthly, seasonal and annual series can be used to improve the robustness of gridded large-scale European temperature reconstructions and possible impact studies. Further improvement of the reconstruction would be achieved if documentary data from other European countries are further developed.  相似文献   
334.
We determined experimentally the Nernst distribution coefficient between orthopyroxene and anhydrous silicate melt for trace elements i in the system Na2O–CaO–MgO–Al2O3–SiO2 (NCMAS) along the dry model lherzolite solidus from 1.1 GPa/1,230°C up to 3.2 GPa/1,535°C in a piston cylinder apparatus. Major and trace element composition of melt and orthopyroxene were determined with a combination of electron microprobe and ion probe analyses. We provide partitioning data for trace elements Li, Be, B, K, Sc, Ti, V, Cr, Co, Ni, Rb, Sr, Y, Zr, Nb, Cs, Ba, La, Ce, Sm, Nd, Yb, Lu, Hf, Ta, Pb, U, and Th. The melts were chosen to be boninitic at 1.1 and 2.0 GPa, picritic at 2.3 GPa and komatiitic at 2.7 and 3.2 GPa. Orthopyroxene is Tschermakitic with 8 mol% Mg-Tschermaks MgAl[AlSiO6] at 1.1 GPa while at higher pressure it has 18–20 mol%. The rare earth elements show a continuous, significant increase in compatibility with decreasing ionic radius from D Laopx−melt ∼ 0.0008 to D Luopx−melt ∼ 0.15. For the high-field-strength elements compatibility increases from D Thopx−melt ∼ 0.001 through D Nbopx−melt ∼ 0.0015, D Uopx−melt ∼ 0.002, D Taopx−melt ∼ 0.005, D Zropx−melt ∼ 0.02 and D Hfopx−melt ∼ 0.04 to D Tiopx−melt ∼ 0.14. From mathematical and graphical fits we determined best-fit values for D 0M1, D 0M2, r 0M1, r 0M2, E 0M1, and E 0M2 for the two different M sites in orthopyroxene according to the lattice strain model and calculated the intracrystalline distribution between M1 and M2. Our data indicate extreme intracrystalline fractionation for most elements in orthopyroxene; for the divalent cations D i M2−M1 varies by three orders of magnitude between D CoM2−M1 = 0.00098–0.00919 and D BaM2−M1 = 2.3–28. Trivalent cations Al and Cr almost exclusively substitute on M1 while the other trivalent cations substitute on M2; D LaM2−M1 reaches extreme values between 6.5 × 107 and 1.4 × 1016. Tetravalent cations Ti, Hf, and Zr almost exclusively substitute on M1 while U and Th exclusively substitute on M2. Our new comprehensive data set can be used for polybaric-polythermal melting models along the Earth’s mantle solidus. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   
335.
The Gamma Ray Spectrometer (Mars Odyssey spacecraft) has revealed elemental distributions of potassium (K), thorium (Th), and iron (Fe) on Mars that require fractionation of K (and possibly Th and Fe) consistent with aqueous activity. This includes weathering, evolution of soils, and transport, sorting, and deposition, as well as with the location of first-order geomorphological demarcations identified as possible paleoocean boundaries. The element abundances occur in patterns consistent with weathering in situ and possible presence of relict or exhumed paleosols, deposition of weathered materials (salts and clastic minerals), and weathering/transport under neutral to acidic brines. The abundances are explained by hydrogeology consistent with the possibly overlapping alternatives of paleooceans and/or heterogeneous rock compositions from diverse provenances (e.g., differing igneous compositions).  相似文献   
336.
337.
Summary The distribution of polychlorinated biphenyls (PCB) and organochlorine pesticides, e.g. the isomers of hexachlorocyclohexane (HCH), hexachlorobenzene (HCB), p,p’-dichiorodiphenyitrichloroethane (DDT) and its primary metabolites DDE and DDD was investigated in surface sediments (0–2 cm) and sediment cores (0–45 cm) from the western Baltic Sea and the coastal waters of Mecklenburg-Vorpommern. Sediment sampling was carried out in the Belt Sea, the Arkona Basin, the Pomeranian Bight and in almost all Bodden and Haff areas of Mecklenburg-Vorpommern in autumn 1993 and 1994. The highest concentrations of PCB and DDT compounds, measured in the innercoastal waters, reached 214 ng g-1 dry weight (d. w.). The values of HCH isomers ranged between 0.01 and 2.9 ng g-1 d.w., the highest levels being those of Β-HCH. Levels of chlorinated hydrocarbons, which varied depending on the sediment properties, indicated increased riverine inputs (Oder, Peene, and Uecker). Elevated levels in the Oderhaff and Peenestrom characterize that area as a sink and, due to remobilization of the upper sediment layer (fluffy layer) into the pelagic, also as a source of organic contaminants. Input from agriculture and industrial point sources (shipyards, shipbuilding) was observed in the coastal waters. The homogeneous PCB and DDT distribution (TOC standardization) observed in the surface sediments of some areas in the western Baltic indicates high sediment dynamics. This is supported by the results of sediment core analyses which showed a constant PCB and DDT distribution down to a depth of 15 to 20 cm.
Polychlorierte Biphenyle (PCB) und Organochlorpestizide im Sediment der Ostsee und der Küsten-gew?sser Mecklenburg-Vorpommerns
Zusammenfassung Die Verteilungen von polychlorierten Biphenylen (PCB) und Organochlorpestiziden (DDT, HCH und HCB) wurden in Oberfl?chensedimenten (0–2 cm) und in Sedimentkernen (0–45 cm) der westlichen Ostsee und der Küstengew?sser Mecklenburg-Vorpommerns untersucht. Die Sedimentprobenahme erfolgte in der Beltsee, der Arkonasee, der Pommerschen Bucht und in nahezu allen Bodden-und Haffgew?ssern Mecklenburg-Vorpommerns im Herbst 1994 und 1995. Die h?chsten Konzentrationen wurden für die PCB-und DDT-Verbindungen bis 214 ng g-1 Trockenmasse (TM) in den Küstengew?ssern gemessen. Für die HCH-Isomeren lagen die Werte zwischen 0,01 und 2,9 ng g-1 TM, mit h?chsten Konzentrationen für das Β-HCH. Die Werte der chlorierten Kohlenwasserstoffe (CKW) variieren nach der Sedimentbeschaffenheit und weisen auf erh?hte Eintr?ge über die Flu\systeme (Oder und Peene) hin. Die h?heren Konzentrationen in den Bodden-und Haffgew?ssern charakterisieren diese Gebiete als Senke und durch erneute Mobilisierung der oberen Sedimentschicht in das Pelagial auch als Quelle für die organischen Schadstoffe. Insbesondere konnten die Eintr?ge aus der Landwirtschaft und aus industriellen Punktquellen (Werftstandorte, Schiffbau) in den Küstengew?ssern festgestellt werden. Die nahezu homogene PCB-und DDT-Verteilung im Oberfl?chensediment der westlichen Ostsee ist ein Hinweis auf die hohe Sedimentdynamik in diesem Gebiet. Dieses wird durch die Ergebnisse der Untersuchungen an Sedimentkernen unterstützt, die eine konstante PCB-und DDT-Verteilung bis zu einer Tiefe von 15 bis 20 cm zeigten.
  相似文献   
338.
A finite-difference approach of aP-SV modeling scheme is applied to compute seismic wave propagation in heterogeneous isotropic media, including fluid-filled boreholes. The discrete formulation of the equation of motion requires the definition of the material parameters at the grid points of the numerical mesh. The grid spacing is chosen as coarse as possible with respect to the accurate representation of the shortest wavelength. If we assume frequencies lower than 250 Hz then the grid spacing is usually chosen in the range of a few meters. One encounters difficulties because of the large-scale difference between the grid spacing and the size of the borehole, usually several centimeters.These difficulties can be overcome by a grid refinement technique. This technique provides the construction of grids with varying grid spacing. The grid spacing in the vicinity of the borehole is chosen such that the borehole is properly represented. An example demonstrates the accuracy of this technique by comparisons with other methods. Unlike many analytical methods, the FD method can handle complex subsurface geometries. Further numerical examples of walk-awayVSP configurations show tube wave propagation within fluid-filled boreholes of realistic diameters.  相似文献   
339.
Large-scale zonal flow driven across submarine topography establishes standing Rossby waves. In the presence of stratification, the wave pattern can be represented by barotropic and baroclinic Rossby waves of mixed planetary topographic nature, which are locked to the topography. In the balance of momentum, the wave pattern manifests itself as topographic formstress. This wave-induced formstress has the net effect of braking the flow and reducing the zonal transport. Locally, it may lead to acceleration, and the parts induced by the barotropic and baroclinic waves may have opposing effects. This flow regime occurs in the circumpolar flow around Antarctica. The different roles that the wave-induced formstress plays in homogeneous and stratified flows through a zonal channel are analyzed with the BARBI (BARotropic-Baroclinic-Interaction ocean model, Olbers and Eden, J Phys Oceanogr 33:2719–2737, 2003) model. It is used in complete form and in a low-order version to clarify the different regimes. It is shown that the barotropic formstress arises by topographic locking due to viscous friction and the baroclinic one due to eddy-induced density advection. For the sinusoidal topography used in this study, the transport obeys a law in which friction and wave-induced formstress act as additive resistances, and windstress, the effect of Ekman pumping on the density stratification, and the buoyancy forcing (diapycnal mixing of the stratified water column) of the potential energy stored in the stratification act as additive forcing functions. The dependence of the resistance on the system parameters (lateral viscosity ε, lateral diffusivity κ of eddy density advection, Rossby radius λ, and topography height δ) as well as the dependence of transport on the forcing functions are determined. While the current intensity in a channel with homogeneous density decreases from the viscous flat bottom case in an inverse quadratic law ~δ –2 with increasing topography height and always depends on ε, a stratified system runs into a saturated state in which the transport becomes independent of δ and ε and is determined by the density diffusivity κ rather than the viscosity: κ/λ 2 acts as a vertical eddy viscosity, and the transport is λ 2/κ times the applied forcing. Critical values for the topographic heights in these regimes are identified.  相似文献   
340.
Synoptic scale variability of the Southern Ocean wind field in the high-frequency range of barotropic Rossby waves results in transport variations of the Antarctic Circumpolar Current (ACC), which are highly coherent with the bottom pressure field all around the Antarctic continent. The coherence pattern, in contrast to the steady state ACC, is steered by the geostrophic f/h contours passing through Drake Passage and circling closely around the continent. At lower frequencies, with interannual and decadal periods, the correlation with the bottom pressure continues, but baroclinic processes gain importance. For periods exceeding a few years, variations of the ACC transport are in geostrophic balance with the pressure field associated with the baroclinic potential energy stored in the stratification, whereas bottom pressure plays a minor role. The low-frequency variability of the ACC transport is correlated with the baroclinic state variable in the entire Southern Ocean, mediated by baroclinic topographic–planetary Rossby waves that are not bound to f/h contours. To clarify the processes of wave dynamics and pattern correlation, we apply a circulation model with simplified physics (the barotropic–baroclinic-interaction model BARBI) and use two types of wind forcing: the National Centers for Environmental Prediction (NCEP) wind field with integrations spanning three decades and an artificial wind field constructed from the first three empirical orthogonal functions of NCEP combined with a temporal variability according to an autoregressive process. Experiments with this Southern Annular Mode type forcing have been performed for 1,800 years. We analyze the spin-up, trends, and variability of the model runs. Particular emphasis is placed on coherence and correlation patterns between the ACC transport, the wind forcing, the bottom pressure field and the pressure associated with the baroclinic potential energy. A stochastic dynamical model is developed that describes the dominant barotropic and baroclinic processes and represents the spectral properties for a wide range of frequencies, from monthly periods to hundreds of years.  相似文献   
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