Composition of the core,I. Solubility of oxygen in molten iron at high temperatures     

E. Ohtani  A.E. Ringwood 《Earth and Planetary Science Letters》1984,71(1):85-93

Experiments on the solubility of FeO in molten iron have been carried out at temperatures between 2100 and 2550°C. The results show that liquid FeO is extensively soluble in molten iron at 2500°C and indicate that they probably become completely miscible above 2800°C. Liquid iron in equilibrium with crystalline magnesiowüstite (Mg_0.8Fe_0.2)O which is believed to be an important mineral in the lower mantle, would dissolve about 14 mol.% of FeO at 2500°C and 40 mol.% of FeO at 2800°C. The geochemical implications of these results are discussed. It is concluded that the outer core probably contains a large amount of dissolved FeO and that oxygen is probably the principal light element in the outer core.  相似文献   

Application of an infrared carbon dioxide and humidity instrument to studies of turbulent transport   总被引：4，自引：0，他引：4  

Eiji Ohtaki 《Boundary-Layer Meteorology》1984,29(1):85-107

A calibration equation and some results of the field performance of an infrared instrument, which is designed to measure simultaneous fluctuations of atmospheric carbon dioxide and water vapor, are described. Field observations show that the instrument is suitable for simultaneous measurement of turbulent fluxes of carbon dioxide and water vapor in conjunction with a sonic anemometer. Measured values of carbon dioxide and water vapor fluxes show diurnal variations characterized by crop activity with respect to assimilation, respiration and evapotranspiration. Carbon dioxide is transferred downward during the daytime and upward at night, while latent heat and sensible heat are transferred in the opposite sense. The non-dimensional gradient of carbon dioxide is expressed in the following form under weak unstable conditions: _c = (1 – 16 _v )^-1/2. Here, _v is the Monin-Obukhov stability parameter including the humidity effect. This relation was originally proposed for temperature and humidity. Thus, the results indicate that the turbulent mechanisms of carbon dioxide fluctuations are similar to those of other scalar entities. This is strongly supported by the high correlation coefficient found between fluctuations of carbon dioxide and temperature or humidity in the air layer over crop fields.  相似文献   

Turbulent transport of carbon dioxide over a paddy field     

Eiji Ohtaki 《Boundary-Layer Meteorology》1980,19(3):315-336

Turbulent fluctuations in CO₂ concentrations over a paddy field are measured by a fastresponse device with an open sensing path. This IR device coupled with a sonic anemometer constitutes an eddy correlation instrument to measure CO₂ fluxes. Three experiments were conducted in the surface layer over paddy 90 cm high. The stability (z – d)/L ranged from -0.14 to 0.20, where L denotes the Monin-Obukhov length.CO₂ power spectra show the range of applicability of the -2/3 power law to be between f = 0.2 and f = 2, where f is the frequency normalized by wind speed and height. The cospectral estimate between CO₂ and vertical component of wind speed ranging from f = 0.005 to f = 2 shows a peak at about f = 0.15 under near-neutral stratification.Hourly means of CO₂ flux measured by the eddy correlation method increase with intensity of net radiation. The maximum value of downward flux of CO₂ rises to 0.6 mg cm^-2 hr^-1 over the paddy field at the stage of ear emergence.Some turbulence statistics relating to the CO₂ transport are evaluated: the correlation coefficient between CO₂ and vertical velocity is about -0.3, and that between CO₂ and humidity attains -0.7 ~ -0.8 under unstable stratification; nondimensional gradients _c for CO₂ and _m for wind speed are 0.89 and 0.99, respectively.  相似文献   

Experimental constraints on the role of chloride in the origin and evolution of kimberlitic magma     

K. D. Litasov  I. S. Sharygin  A. F. Shatskiy  E. Ohtani  N. P. Pokhilenko 《Doklady Earth Sciences》2010,435(2):1641-1646

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Hydrothermal Alteration Related to Silver Mineralization at the Iwami Silver Deposit,Shimane Prefecture,Japan     

Nanshi Zeng  Eiji Izawa  Koichiro Watanabe  Yoshinobu Motomura 《Resource Geology》2010,60(3):234-248

The Iwami epithermal silver deposit consists of Ag-Cu veins in a dacitic intrusive body at the deep portion of the Eikyu area, and veinlets with disseminated Ag mineralization in dacitic tuff breccia at a shallow portion of the Fukuishi area. Hydrothermal alteration associated with the silver mineralization is characterized by intense potassium metasomatism with oxidizing conditions. An illite zone occurs around the pathways of uprising fluids in both the Eikyu and Fukuishi areas. It grades laterally into the illite/smectite zone, which is surrounded by a broad smectite zone. Because of boiling, abundant adularia associated with silver mineralization overlaps on the altered tuff breccia in the Fukuishi area. The alteration zoning suggests that the western Eikyu area and the eastern Fukuishi area belong to a single hydrothermal system. The data of fluid inclusion microthermometry indicate that the temperatures range 220–270°C, and salinities range 5–7 wt percent NaCl equivalent for the silver mineralization at the upper portion in the Eikyu area and the lower portion in the Fukuishi area. Radiometric ages for volcanic rocks in the area range from 2.19 to 1.64 Ma, and the dacitic intrusion formed at approximately 1.6 Ma. The silver-dominant mineralizing hydrothermal fluids system was active around 1.44 to 1.07 Ma, which formed the Eikyu Ag-Cu veins at depth, and the Fukuishi Ag ores at the shallower portion.  相似文献   

http://www.sciencedirect.com/science/article/pii/S167498711300162X     

Fumiko Tajima  Masaki Yoshida  Eiji Ohtani 《地学前缘(英文版)》2015,6(1):79-93

Seismic observations have shown structural variation near the base of the mantle transition zone(MTZ)where subducted cold slabs,as visualized with high seismic speed anomalies(HSSAs),flatten to form stagnant slabs or sink further into the lower mantle.The different slab behaviors were also accompanied by variation of the "660 km" discontinuity depths and low viscosity layers(LVLs) beneath the MTZ that are suggested by geoid inversion studies.We address that deep water transport by subducted slabs and dehydration from hydrous slabs could affect the physical properties of mantle minerals and govern slab dynamics.A systematic series of three-dimensional numerical simulation has been conducted to examine the effects of viscosity reduction or contrast between slab materials on slab behaviors near the base of the MTZ.We found that the viscosity reduction of subducted crustal material leads to a separation of crustal material from the slab main body and its transient stagnation in the MTZ.The once trapped crustal materials in the MTZ eventually sink into the lower mantle within 20-30 My from the start of the plate subduction.The results suggest crustal material recycle in the whole mantle that is consistent with evidence from mantle geochemistry as opposed to a two-layer mantle convection model.Because of the smaller capacity of water content in lower mantle minerals than in MTZ minerals,dehydration should occur at the phase transformation depth,~660 km.The variation of the discontinuity depths and highly localized low seismic speed anomaly(LSSA) zones observed from seismic P waveforms in a relatively high frequency band(~1 Hz) support the hypothesis of dehydration from hydrous slabs at the phase boundary.The LSSAs which correspond to dehydration induced fluids are likely to be very local,given very small hydrogen(H~+) diffusivity associated with subducted slabs.The image of such local LSSA zones embedded in HSSAs may not be necessarily captured in tomography studies.The high electrical conductivity in the MTZ beneath the northwestern Pacific subduction zone does not necessarily require a broad range of high water content homogeneously.  相似文献   

NanoSIMS analysis of organic carbon from the Tissint Martian meteorite: Evidence for the past existence of subsurface organic‐bearing fluids on Mars     

Yangting Lin  Ahmed El Goresy  Sen Hu  Jianchao Zhang  Philippe Gillet  Yuchen Xu  Jialong Hao  Masaaki Miyahara  Ziyuan Ouyang  Eiji Ohtani  Lin Xu  Wei Yang  Lu Feng  Xuchao Zhao  Jing Yang  Shin Ozawa 《Meteoritics & planetary science》2014,49(12):2201-2218

Two petrographic settings of carbonaceous components, mainly filling open fractures and occasionally enclosed in shock‐melt veins, were found in the recently fallen Tissint Martian meteorite. The presence in shock‐melt veins and the deuterium enrichments (δD up to +1183‰) of these components clearly indicate a pristine Martian origin. The carbonaceous components are kerogen‐like, based on micro‐Raman spectra and multielemental ratios, and were probably deposited from fluids in shock‐induced fractures in the parent rock of Tissint. After precipitation of the organic matter, the rock experienced another severe shock event, producing the melt veins that encapsulated a part of the organic matter. The C isotopic compositions of the organic matter (δ¹³C = ?12.8 to ?33.1‰) are significantly lighter than Martian atmospheric CO₂ and carbonate, providing a tantalizing hint for a possible biotic process. Alternatively, the organic matter could be derived from carbonaceous chondrites, as insoluble organic matter from the latter has similar chemical and isotopic compositions. The presence of organic‐rich fluids that infiltrated rocks near the surface of Mars has significant implications for the study of Martian paleoenvironment and perhaps to search for possible ancient biological activities on Mars.  相似文献   

The partitioning of Pt-Re-Os between solid and liquid metal in the Fe-Ni-S system at high pressure: Implications for inner core fractionation     

Hiromi Hayashi  Eiji Ohtani  Hidenori Terasaki  Yoshinori Ito 《Geochimica et cosmochimica acta》2009,73(16):4836-4475

Coupled ¹⁸⁶Os/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os enrichments of plume-derived lavas have been suggested to reflect contributions of materials from the outer core (Brandon et al., 1998). This hypothesis is based on the assumption that the Earth’s liquid outer core has high Pt/Os and slightly high Re/Os ratios as a result of the crystallization of the solid inner core, and shows coupled enrichments in the ¹⁸⁶Os/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os ratios, reflecting the decay of ¹⁹⁰Pt and ¹⁸⁷Re to ¹⁸⁶Os and ¹⁸⁷Os, respectively. Partitioning experiments of Pt-Re-Os between solid and liquid metal were performed at 5-20 GPa and 1250-1400 °C, to examine the effects of pressure in the Fe-Ni-S system. The ratios (D_Os/D_Pt, D_Os/D_Re) of measured partition coefficients of Pt, Re and Os are almost constant with increasing pressure. D_Os/D_Pt increases significantly, whereas D_Os/D_Re decreases, with increasing sulphur content in the liquid metal. On the basis of the present experimental results, it is unlikely that the required Pt-Re-Os fractionation is generated during inner core crystallization, assuming that the light element in the Earth’s core is sulphur.  相似文献   

Improved Method for Calculating Anthropogenic CO2 in the Upper Layer of the North Pacific Subtropical Gyre along 175°E     

Yoshiyuki Takahashi  Eiji Matsumoto  Yutaka W. Watanabe 《Journal of Oceanography》1999,55(6):717-729

Seawater samples were collected in the North Pacific along 175°E during a cruise of the Northwest Pacific Carbon Cycle Study (NOPACCS) program in 1994. Many properties related to the carbonate system were analyzed. By using well-known ratios to correct for chemical changes in seawater, the CO₂ concentration at a given depth was back calculated to its initial concentration at the time when the water left the surface in winter. We estimated sea-surface CO₂ and titration alkalinity (TA) in present-day winter, from which we evaluated the degree of air-sea CO₂ disequilibrium in winter was. Using a correction factor for air-sea CO₂ disequilibrium in winter, we reconstructed sea-surface CO₂ in pre-industrial times. The difference between the back-calculated initial CO₂ and sea-surface CO₂ in pre-industrial times should correspond to anthropgenic CO₂ input. Although the mixing of different water masses may cause systematic error in the calculation, we found that the nonlinear effect induced by the mixing of different water masses was negligible in the upper layer of the North Pacific subtropical gyre along 175°E. The results of our improved method of assessing the distribution of anthropogenic CO₂ in that region show marked differences from those obtained using the previous back-calculation method.  相似文献   

Response of hybrid isolation system during a shake table experiment of a full‐scale isolated building          下载免费PDF全文

Keri L. Ryan  Taichiro Okazaki  Camila B. Coria  Eiji Sato  Tomohiro Sasaki 《地震工程与结构动力学》2018,47(11):2214-2232

A full‐scale 5‐story steel moment frame building was subjected to a series of earthquake excitations using the E‐Defense shake table in August, 2011. For one of the test configurations, the building was seismically isolated by a hybrid system of lead‐rubber bearings and low friction roller bearings known as cross‐linear bearings, and was designed for a very rare 100 000‐year return period earthquake at a Central and Eastern US soil site. The building was subject to 15 trials including sinusoidal input, recorded motions and simulated earthquakes, 2D and 3D input, and a range of intensities including some beyond the design basis level. The experimental program was one of the first system‐level full‐scale validations of seismic isolation and the first known full‐scale experiment of a hybrid isolation system incorporating lead‐rubber and low friction bearings. Stable response of the hybrid isolation system was demonstrated at displacement demands up to 550 mm and shear strain in excess of 200%. Torsional amplifications were within the new factor stipulated by the code provisions. Axial force was observed to transfer from the lead‐rubber bearings to the cross‐linear bearings at large displacements, and the force transfer at large displacements exceeded that predicted by basic calculations. The force transfer occurred primarily because of the flexural rigidity of the base diaphragm and the larger vertical stiffness of the cross‐linear bearings relative to the lead‐rubber bearings.  相似文献