Molecules, ices and astronomy     

D A Williams  W A Brown  S D Price  J M C Rawlings  S Viti 《Astronomy& Geophysics》2007,48(1):1.25-1.34

David A Williams, Wendy A Brown, Stephen D Price, Jonathan M C Rawlings and Serena Viti of University College London review how far experimental work on molecular synthesis can be applied to the interstellar medium – and how it is becoming a tool for the understanding of astrophysical processes.  相似文献   

Geochemical and Hydrogeological Impacts of a Wood Particle Barrier Treating Nitrate and Perchlorate in Ground Water   总被引：2，自引：0，他引：2  

W.D. Robertson  C.J. Ptacek  S.J. Brown 《Ground Water Monitoring & Remediation》2007,27(2):85-95

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Littoral fish assemblages of the alien-dominated Sacramento-San Joaquin Delta,California, 1980–1983 and 2001–2003     

Larry R. Brown  Dennis Michniuk 《Estuaries and Coasts》2007,30(1):186-200

We analyzed monthly boat electrofishing data to characterize the littoral fish assemblages of five regions of the Sacramento-San Joaquin Delta (northern, southern, eastern, western, and central), California, during two sampling periods, 1980–1983 (1980s) and 2001–2003 (2000s), to provide information pertinent to the restoration of fish populations in this highly altered estuary. During the 1980s, almost 11,000 fish were captured, including 13 native species and 24 alien species. During the 2000s, just over 39,000 fish were captured, including 15 native species and 24 alien species. Catch per unit effort (CPUE) of total fish, alien fish, and centrarchid fish were greater in the 2000s compared with the 1980s, largely because of increased centrarchid fish CPUE. These differences in CPUE were associated with the spread of submerged aquatic vegetation (SAV), particularly an alien aquatic macrophyte,Egeria densa. Native fish CPUE declined from the 1980s to the 2000s, but there was no single factor that could explain the decline. Native fish were most abundant in the northern region during both sampling periods. Nonmetric multidimensional scaling indicated similar patterns of fish assemblage composition during the two sampling periods, with the northern and western regions characterized by the presence of native species. The separation of the northern and western regions from the other regions was most distinct in the 2000s. Our results suggest that native fish restoration efforts will be most successful in the northern portion of the Delta. Management decisions on the Delta should include consideration of possible effects on SAV in littoral habitats and the associated fish assemblages and ecological processes.  相似文献   

Invited comments on Clemens's ‘Granites and granitic magmas’: Proceedings, Vol. 116, 2005, pp. 9-16     

Michael Brown 《Proceedings of the Geologists' Association. Geologists' Association》2005,116(1):17-32

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The long period behavior of the orbits of the Galilean satellites of Jupiter     

Bryan Brown 《Celestial Mechanics and Dynamical Astronomy》1977,16(2):229-259

Some of the results of an investigation into the long period behavior of the orbits of the Galilean satellites of Jupiter are presented. Special purpose computer programs were used to perform all the algebraic manipulations and series expansions that are necessary to describe the mutual interactions among the satellites.The disturbing function was expanded as a Poisson series in the modified Keplerian elements referred to a Jovicentric coordinate system. The differential equations for the modified Keplerian elements were then formed, and all short period perturbations were removed using Kamel's perturbation method. Approximate analytical solutions for these differential equations are derived, and the general form of the solutions are given.  相似文献   

Turbulent Form Drag On Anisotropic Three-Dimensional Orography     

A. R. Brown  N. Wood 《Boundary-Layer Meteorology》2001,101(2):229-241

Results are presented from a large number of numerical simulations performed to investigate the dependence of the turbulentform drag on three-dimensional ellipsoidal hills upon aspect ratio and wind direction. For isolatedisotropic hills the results are, as expected, found to beindependent of wind direction. However directionaldependence rapidly becomes important as the ridges are elongated,and the results quickly converge onto those obtained in the limitingcase of two-dimensional ridges. Based on the numerical results,a simple parametrization of the drag is proposed.  相似文献   

Orogeny, migmatites and leucogranites: A review   总被引：13，自引：0，他引：13  

Michael Brown 《Journal of Earth System Science》2001,110(4):313-336

The type ofP-T-t path and availability of fluid (H₂O-rich metamorphic volatile phase or melt) are important variables in metamorphism. Collisional orogens are characterized by clockwiseP-T evolution, which means that in the core, where temperatures exceed the wet solidus for common crustal rocks, melt may be present throughout a significant portion of the evolution. Field observations of eroded orogens show that lower crust is migmatitic, and geophysical observations have been interpreted to suggest the presence of melt in active orogens. A consequence of these results is that orogenic collapse in mature orogens may be controlled by a partially-molten layer that decouples weak crust from subducting lithosphere, and such a weak layer may enable exhumation of deeply buried crust. Migmatites provide a record of melt segregation in partially molten crustal materials and syn-anatectic deformation under natural conditions. Grain boundary flow and intra-and inter-grain fracture flow are the principal grain scale melt flow mechanisms. Field observations of migmatites in ancient orogens show that leucosomes occur oriented in the metamorphic fabrics or are located in dilational sites. These observations are interpreted to suggest that melt segregation and extraction are syntectonic processes, and that melt migration pathways commonly relate to rock fabrics and structures. Thus, leucosomes in depleted migmatites record the remnant permeability network, but evolution of permeability networks and amplification of anomalies are poorly understood. Deformation of partially molten rocks is accommodated by melt-enhanced granular flow, and volumetric strain is accommodated by melt loss. Melt segregation and extraction may be cyclic or continuous, depending on the level of applied differential stress and rate of melt pressure buildup. During clockwiseP-T evolution, H₂O is transferred from protolith to melt as rocks cross dehydration melting reactions, and H₂O may be evolved above the solidus at lowP by crossing supra-solidus decompression-dehydration reactions if micas are still present in the depleted protolith. H₂O dissolved in melt is transported through the crust to be exsolved on crystallization. This recycled H₂O may promote wet melting at supra-solidus conditions and retrogression at subsolidus conditions. The common growth of ‘late’ muscovite over sillimanite in migmatite may be the result of this process, and influx of exogenous H₂O may not be necessary. However, in general, metasomatism in the evolution of the crust remains a contentious issue. Processes in the lower-most crust may be inferred from studies of xenolith suites brought to the surface in lavas. Based on geochemical data, we can use statistical methods and modeling to evaluate whether migmatites are sources or feeder zones for granites, or simply segregated melt that was stagnant in residue, and to compare xenoliths of inferred lower crust with exposed deep crust. Upper-crustal granites are a necessary complement to melt-depleted granulites common in the lower crust, but the role of mafic magma in crustal melting remains uncertain. Plutons occur at various depths above and below the brittle-to-viscous transition in the crust and have a variety of 3-D shapes that may vary systematically with depth. The switch from ascent to emplacement may be caused by amplification of instabilities within (permeability, magma flow rate) or surrounding (strength or state of stress) the ascent column, or by the ascending magma intersecting some discontinuity in the crust that enables horizontal magma emplacement followed by thickening during pluton inflation. Feedback relations between rates of pluton filling, magma ascent and melt extraction maintain compatibility among these processes.  相似文献   

Pyrolysis-combustion C dating of soil organic matter     

Hong Wang  Keith C. Hackley  Samuel V. Panno  Dennis D. Coleman  Jack Chao-li Liu  Johnie Brown 《Quaternary Research》2003,60(3):348-355

Radiocarbon (¹⁴C) dating of total soil organic matter (SOM) often yields results inconsistent with the stratigraphic sequence. The onerous chemical extractions for SOM fractions do not always produce satisfactory ¹⁴C dates. In an effort to develop an alternative method, the pyrolysis-combustion technique was investigated to partition SOM into pyrolysis volatile (Py-V) and pyrolysis residue (Py-R) fractions. The Py-V fractions obtained from a thick glacigenic loess succession in Illinois yielded ¹⁴C dates much younger but more reasonable than the counterpart Py-R fractions for the soil residence time. Carbon isotopic composition (δ¹³C) was heavier in the Py-V fractions, suggesting a greater abundance of carbohydrate- and protein-related constituents, and δ¹³C was lighter in the Py-R fractions, suggesting more lignin- and lipid-related constituents. The combination of ¹⁴C dates and δ¹³C values indicates that the Py-V fractions are less biodegradation resistant and the Py-R fractions are more biodegradation resistant. The pyrolysis-combustion method provides a less cumbersome approach for ¹⁴C dating of SOM fractions. With further study, this method may become a useful tool for analyzing unlithified terrestrial sediments when macrofossils are absent.  相似文献   

Selenium speciation and partitioning within Burkholderia cepacia biofilms formed on α-Al₂O₃ surfaces     

Alexis S. Templeton  Thomas P. Trainor  Gordon E. Brown Jr. 《Geochimica et cosmochimica acta》2003,67(19):3547-3557

The distribution and speciation of Se within aerobic Burkholderia cepacia biofilms formed on α-Al₂O₃ (1-102) surfaces have been examined using grazing-angle X-ray spectroscopic techniques. We present quantitative information on the partitioning of 10⁻⁶ M to 10⁻³ M selenate and selenite between the biofilms and underlying alumina surfaces derived from long-period X-ray standing wave (XSW) data. Changes in the Se partitioning behavior over time are correlated with microbially induced reduction of Se(VI) and Se(IV) to Se(0), as observed from X-ray absorption near edge structure (XANES) spectroscopy.Selenite preferentially binds to the alumina surfaces, particularly at low [Se], and is increasingly partitioned into the biofilms at higher [Se]. When B. cepacia is metabolically active, B. cepacia rapidly reduces a fraction of the SeO₃²⁻ to red elemental Se(0). In contrast, selenate is preferentially partitioned into the B. cepacia biofilms at all [Se] tested due to a lower affinity for binding to the alumina surface. Rapid reduction of SeO₄²⁻ by B. cepacia to Se(IV) and Se(0) subsequently results in a vertical segregation of Se species at the B. cepacia/α-Al₂O₃ interface. Elemental Se(0) accumulates within the biofilm with Se(VI), whereas Se(IV) intermediates preferentially sorb to the alumina surface.B. cepacia/α-Al₂O₃ samples incubated with SeO₄²⁻ and SeO₃²⁻ when the bacteria were metabolically active result in a significant reduction in the mobility of Se vs. X-ray treated biofilms. Remobilization experiments show that a large fraction of the insoluble Se(0) produced within the biofilm is retained during exchange with Se-free solutions. In addition, Se(IV) intermediates generated during Se(VI) reduction are preferentially bound to the alumina surface and do not fully desorb. In contrast, Se(VI) is rapidly and extensively remobilized.  相似文献   

The charge-density distribution, its multipole refinement and the antiferromagnetic structure of dioptase, Cu6[Si6O18]·6H2O     

E. L. Belokoneva  Yu. K. Gubina  J. B. Forsyth  P. J. Brown 《Physics and Chemistry of Minerals》2002,29(6):430-438

 The chemical bonding in the ring silicate mineral dioptase is investigated on the basis of accurate single-crystal X-ray diffraction data. A multipole model is used in the refinements. Static deformation electron density is mapped for the silicon tetrahedron, Cu-octahedron and water molecule in different sections. The silicon tetrahedron exhibits peaks resulting from σ-bonds between Si–sp³ hybrid orbitals and O–p orbitals. The excess density is located on bonds between the Si atom and bridge (in ring) O(1)-, O(1′)-oxygens and across the interior of the Si–O–Si angle. In the Jahn-Teller distorted Cu octahedron, in addition to peaks which result from single Cu–O σ-bonds, there are peaks which are due to 3d electrons. The analysis of crystal-field influence on the Cu charge distribution is made using the tetragonal D _{4 d} approximation for the low-symmetry (C1) Cu octahedron. The calculation of the occupancies of the 3d atomic orbitals shows that the Cu non-bonding orbitals are most populated (˜20%) and the bonding orbitals least populated (14%), as is typical for the Jahn-Teller octahedron. The effective atomic charge on the Cu atom in dioptase determined from the multipoles is +1.23e: closer to the Cu⁺¹ than to the Cu⁺² state. The charge on the Si atom has a value +1.17e, which is in the range typical for Si atoms already determined by this method. The accumulation of density on bridge oxygens and across the interior of the Si–O–Si angle may be explained by additional strain in the bond with the decrease of the Si–O–Si angle in dioptase to 132°. The same effect was found earlier in coesite. A single-crystal neutron diffraction study shows that dioptase becomes antiferromagnetic below a Néel temperature of 15.9(1) K, in contrast to the previously reported specific heat anomaly at 21 K. The magnetic propagation vector is (0, 0, 3/2) on the hexagonal triple cell or (1/2, 1/2, 1/2) in rhombohedral indices. The relation between the antiferromagnetic and the charge-density models for dioptase is discussed. The less occupied Cu d _x2−y2 orbitals are responsible for the magnetic properties. These lie in the Cu–O squares, which are approximately perpendicular to c _hex, but which are alternately inclined to it by a small angle. The magnetic moments of 0.59(1)μ _B on the Cu ions in the same level are ordered ferromagnetically, but between ions in alternate levels the coupling is antiferromagnet. Within experimental error the magnetic moments are perpendicular to the square planes, which make an angle ±13(3)° to the triad axis. Received: 8 June 2001 / Accepted: 10 January 2002  相似文献