Iron oxidation state in impact glass from the K/T boundary at Beloc,Haiti, by high‐resolution XANES spectroscopy     

Gabriele Giuli  Sigrid Griet Eeckhout  Eleonora Paris  Christian Koeberl  Giovanni Pratesi 《Meteoritics & planetary science》2005,40(11):1575-1580

Abstract— We examined the local iron environment in nine impact glasses from the Cretaceous‐Tertiary (K/T) boundary section at Beloc, Haiti, which formed as the result of impact melting during the Chicxulub impact event. The samples have been analyzed by Fe K‐edge high‐resolution X‐ray absorption near edge structure (XANES) spectroscopy to obtain data on both the Fe oxidation state and the coordination number. The pre‐edge peak of our high‐resolution XANES spectra display noticeable variations indicative of significant changes in the Fe oxidation state spanning a wide range from about 20 to 75 mol% trivalent Fe. All data plot along the same trend, falling between two mixing lines joining a point calculated as the mean of a group of tektites studied so far (consisting of four‐ and five‐coordinated Fe²⁺) to ^[4]Fe³⁺ and ^[5]Fe³⁺, respectively. Thus, the XANES spectra can be interpreted as a mixture of ^[4]Fe²⁺, ^[5]Fe²⁺, ^[4]Fe³⁺, and ^[5]Fe³⁺. There is no evidence for six‐fold coordinated Fe; however, its presence in small amounts cannot be excluded from XANES data alone. Our observations can be explained by two possible scenarios: either these impact glasses formed under very reducing conditions and, because of their small size, were easily oxidized in air while still molten, or they formed under a variety of different oxygen fugacities resulting in different Fe oxidation states. In the first case, the oxidation state and coordination number would imply similar formation conditions as splash‐form tektites, followed by progressive oxidation.  相似文献   

Australasian microtektites from Antarctica: XAS determination of the Fe oxidation state     

Gabriele Giuli  Maria Rita Cicconi  Sigrid Griet Eeckhout  Giovanni Pratesi  Eleonora Paris  Luigi Folco 《Meteoritics & planetary science》2014,49(4):696-705

The Fe oxidation state and coordination number of 29 impact glass spherules recently recovered from the Transantarctic Mountains (Antarctica) have been determined by X‐ray absorption near edge structure (XANES) spectroscopy. Based on geochemical, isotopic, and fission track data, these spherules are considered as microtektites from the Australasian tektite/microtektite strewn field. Their find location is the farthest so far discovered from the possible source crater region, and their alkali content is the lowest compared with other published data on Australasian microtektite glasses. The Fe³⁺/(Fe²⁺+Fe³⁺) ratio, determined from the analysis of the pre‐edge peak energy position and integrated intensity, is below 0.1 (±0.04) for all the samples, and is comparable to that of most tektites and microtektites from the Australasian strewn field. Also, the pre‐edge peak integrated intensity, which is sensitive to the average Fe coordination geometry, is comparable to that of other Australasian microtektites reported in the literature. The agreement of the Fe oxidation state and coordination number, between the Transantarctic Mountain microtektites (TAM) and the Australasian tektites and microtektites, further confirms the impact origin of these glass spherules and provides an independent suggestion that they represent a major extension southeastward of the Australasian strewn field. The fact that similar redox conditions are observed in tektites and microtektites within the Australasian strewn field regardless of the distance from the source crater area (up to approximately 11000 km) could be an important constraint for better understanding the different processes affecting microtektite formation and transport. The fact that the Fe oxidation state of microtektites does not increase with distance, as in the case of North American microtektites, means that thermal and redox histories of Australasian and TAM microtektites could differ significantly from those of North American microtektites.  相似文献   

Yellow impact glass from the K/T boundary at Beloc (Haiti): XANES determination of the Fe oxidation state and implications for formation conditions     

Gabriele GIULI  Sigrid Griet EECKHOUT  Christian KOEBERL  Giovanni PRATESI  Eleonora PARIS 《Meteoritics & planetary science》2008,43(5):981-986

Abstract— We determined the iron oxidation state and coordination number in five samples of yellow impact glass from the Cretaceous‐Tertiary (K/T) boundary section at Beloc, Haiti, which formed as the result of impact melting during the Chicxulub impact event. The samples were analyzed by Fe K‐edge XANES spectroscopy and the results were compared with published data on eight black impact glasses and one high Si‐K impact spherule from the same impact layer. The pre‐edge peak of our high‐resolution XANES spectra displays evident variations indicative of significant changes in the Fe oxidation state, spanning a wide range from about 75 to 100 mole% Fe³⁺. Yellow K/T glasses have significantly higher Fe³⁺/(Fe²⁺ + Fe³⁺) ratios compared to black K/T impact glasses (from 20 to 75 mole% Fe³⁺) and high Si‐K glass (20 mole% Fe³⁺). In particular, all the pre‐edge peak data on these three types of impact glasses plot between two mixing lines joining a point calculated as the mean of a group of tektites studied so far (consisting of ^[4]Fe²⁺ and ^[5]Fe²⁺) to ^[4]Fe³⁺ and ^[5]Fe³⁺, respectively. Thus, the XANES spectra of the yellow K/T glasses can be interpreted as a mixture of ^[4]Fe^{2+, [5]}Fe^{2+, [4]}Fe³⁺, and ^[5]Fe³⁺. Our observations can be explained by a very large range of oxygen fugacity conditions during melt formation. Furthermore, there is a clear positive relationship between the Fe³⁺/(Fe²⁺ + Fe³⁺) ratio and the Ca content of these glasses, suggesting that the Fe oxidation state was influenced by the relative contribution of Ca‐sulfate‐ and Ca‐carbonate‐bearing sedimentary rocks at the impact site.  相似文献   

The edge dislocation problem in a layered elastic medium   总被引：2，自引：0，他引：2  

Eleonora Rivalta  Walter Mangiavillano  Maurizio Bonafede 《Geophysical Journal International》2002,149(2):508-523

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On strike-slip faulting in layered media   总被引：2，自引：0，他引：2  

Maurizio Bonafede  Beatrice Parenti  Eleonora Rivalta 《Geophysical Journal International》2002,149(3):698-723

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How does co-registration affect geomorphic change estimates in multi-temporal surveys?     

Sara Cucchiaro  Eleonora Maset  Marco Cavalli  Stefano Crema  Lorenzo Marchi  Alberto Beinat 《地理信息系统科学与遥感》2020,57(5):611-632

ABSTRACT

High-Resolution Topography (HRT) data sets are becoming increasingly available, improving our ability and opportunities to monitor geomorphic changes through multi-temporal Digital Terrain Models (DTMs). The use of repeated topographic surveys enables inferring the sediment dynamics of hazardous geomorphic processes such as floods, debris flows, and landslides, and allows us to derive important information on the risks often associated with these processes. The topographic surveying platforms, georeferencing systems, and processing tools have seen important developments in the last two decades, in particular Light Detection And Ranging (LiDAR) technology used in Airborne Laser Scanning (ALS) and Terrestrial Laser Scanning (TLS). Moreover, HRT data, produced through these techniques, changed a lot in terms of point cloud density, accuracy and precision over time. Therefore, old “legacy” data sets and recent surveys can often show comparison problems, especially when multi-temporal data are not homogeneous in terms of quality and uncertainties. In this context, data co-registration should be used to guarantee the coherence among multi-temporal surveys, minimizing, on stable areas, the distance between corresponding points acquired at different epochs. Although several studies highlight that this process is fundamental to properly compare multi-temporal DTMs, it is often not addressed in LiDAR post-processing workflows. In this paper we focus on the alignment of multi-temporal surveys in a topographically complex and rugged environment as the Moscardo debris-flow catchment (Eastern Italian Alps), testing various co-registration methods to align multi-temporal ALS point clouds (i.e. years 2003, 2009 and 2013) and the derived DTMs. In particular, we tested the pairwise registration with manual correspondences, the Iterative Closest Point (ICP) algorithm and a mathematical model that allows aligning simultaneously a generic number of point clouds, the so-called Generalized Procrustes Analysis (GPA), also in its GPA-ICP variant. Then, to correct the possible small inaccuracies generated from the gridding interpolation process, a custom-developed DTM co-registration tool (GRD-CoReg) was used to align gridded data. Both alignment phases (i.e. at point cloud and DTM level) proved to be fundamental and allowed us to obtain proper and reliable DTMs of Difference (DoDs), useful to quantify the debris mobilized and to detect the spatial and temporal patterns of catchment-scale erosion and deposition. The consistency of DoDs data was verified through the comparison between the erosion estimate of DoDs and the volumes of debris-flow events measured by the monitoring station close to the Moscardo torrent catchment outlet. The GPA-ICP algorithm followed by the GRD-CoReg tool proved to be the most effective solution for improving DoDs results with a decrease of systematic trend due to vertical and horizontal uncertainties between surveys, especially at steep slopes. The net volume difference (i.e. the sediment output from the catchment) of the 2003–2013 period changed from 3,237,896 m³ to 135,902 m³ in DoDs obtained from not co-registered and co-registered DTMs. The volume of debris flows measured at the catchment outlet during the same time interval amounts to 169,660 m³. The comparison with debris-flow volume measures at the monitoring station shows, therefore, that the DTMs obtained from the co-registration processes generate more reliable DoDs than those obtained from the raw DTMs (without the alignment).  相似文献   

Theoretical analysis of X-ray absorption near-edge structure in forsterite, Mg2SiO4-Pbnm, and fayalite, Fe2SiO4-Pbnm, at room temperature and extreme conditions     

Ziyu Wu  Annibale Mottana  Augusto Marcelli  Calogero Rino Natoli  Eleonora Paris 《Physics and Chemistry of Minerals》1996,23(3):193-204

We calculated the forsterite Mg K-edge and the fayalite Fe K-edge X-ray absorption spectra both for the M 1 and M 2 sites and for the overall edge by using the one-electron multiple-scattering theory. The validity of the theoretical model is well illustrated by comparison of calculations with experimental data at the Mg K-edge of MgO (periclase) and at the Mg and Fe K-edges spectra of forsterite and fayalite. Starting from these results at room conditions, we calculated the Mg and Fe K-edges X-ray absorption spectra of forsterite and fayalite at low and high temperatures and at high pressures as well. Variations of fine structures occur mostly in the intermediate multiple scattering (IMS) regions and as a result of the applied pressure. In order to demonstrate the capability of XAS to lead to deeper knowledge of structure relevant to Earth's upper mantle we also attempted calcuating the high-P edge for Fe ²⁺ in low-spin using a different occupation of valence electrons. If a change in spin state really occurs in fayalite, our simple model shows that XAS would evidence it easily even with low resolution.  相似文献   

Hydrochemical variability associated with rainfall regime: a case study in the coastal wetland of the outer Río de la Plata Estuary,Argentina     

Eleonora S. Carol  Eduardo E. Kruse 《Environmental Earth Sciences》2016,75(10):907

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Studies on the contribution of some geological factors to seismic hazard     

Eleonora Spânoche 《Natural Hazards》1990,3(3):261-264

The present study is primarily meant to make a separation of the amplification effects in the intensity distribution within the macroseismic field function of their different causes, i.e. the activation of some regional tectonic lines during the seismic motion and local seismogeological conditions.With this end in view, the methodology used consists of filtering the direct macroseismic observations by means of the weighted mean-values method and outlining the regional and local field anomalies.The regional anomaly map of the macroseismic field of the 4 March 1977 Vrancea earthquake, including the southern and south-eastern part of the Outer Carpathian Zone, has been analyzed. Some dislocations, located in the platform basement, which functioned as seismic energy amplifiers during the event, have been identified.The results obtained can be used in seismotectonic and microzoning studies.Paper presented at the 21st General Assembly of the European Seismological Commission, Sofia, 1988.  相似文献   

Correction to: Impact of climate change on landslides frequency: the Esino river basin case study (Central Italy)     

Lorenzo Sangelantoni  Eleonora Gioia  Fausto Marincioni 《Natural Hazards》2018,92(2):885-905

We refine the 1-D velocity model of the Central India Tectonic Zone (CITZ) using well-selected arrival times of P- and S-phases of 354 local earthquakes of magnitude (M_w) between 2.0 and 5.8, recorded by national seismic network from May 1997 to March 2016. Further, we have determined the source mechanisms of 26 selected local events using moment tensor inversion to characterize the dynamics beneath the CITZ. The best-fit simulation between observed and synthetic waveforms obtained the nodal and auxiliary planes of the each faults associated with the earthquake moment magnitude (M_w) for each event. Depth of the fault plane along the CITZ varies from 5 to 38 km. From this study, we found that the western part along the CITZ shows minimum focal depth and reaches maximum 38 kms at Jabalpur in the eastern part. This complex nature of earthquake dynamics occurrence along the CITZ. We propose that the curviplanar the CITZ dominated with sinistral curvature is subjected to compression along the longer ~E–W segments and transtension along shorter segments with ~NE–SW orientations. The occurrences of normal faulting, intrusion of mafic plutons and CLVD mechanisms for earthquakes are interpreted to be linked to the transtension zones and reverse mechanisms associated with the compressions along ~E–W segments.  相似文献