Iron oxidation state in the Fe‐rich layer and silica matrix of Libyan Desert Glass: A high‐resolution XANES study     

Gabriele Giuli  Eleonora Paris  Giovanni Pratesi  Christian Koeberl  Curzio Cipriani 《Meteoritics & planetary science》2003,38(8):1181-1186

Abstract— Libyan Desert Glass (LDG) is an enigmatic type of glass that occurs in western Egypt in the Libyan Desert. Fairly convincing evidence exists to show that it formed by impact, although the source crater is currently unknown. Some rare samples present dark‐colored streaks with variable amounts of Fe, and they are supposed to contain a meteoritic component. We have studied the iron local environment in an LDG sample by means of Fe K‐edge highresolution X‐ray absorption near edge structure (XANES) spectroscopy to obtain quantitative data on the Fe oxidation state and coordination number in both the Fe‐poor matrix and Fe‐rich layers. The pre‐edge peak of the high‐resolution XANES spectra of the sample studied displays small but reproducible variations between Fe‐poor matrix and Fe‐rich layers, which is indicative of significant changes in the Fe oxidation state and coordination number. Comparison with previously obtained data for a very low‐Fe sample shows that, while iron is virtually all trivalent and in tetrahedral coordination (^[4]Fe³⁺) in the low‐Fe sample, the sample containing the Fe‐rich layers display a mixture of tetra‐coordinated trivalent iron (^[4]Fe³⁺) and penta‐coordinated divalent iron (^[5]Fe²⁺), with the Fe in the Fe‐rich layer being more reduced than the matrix. From these data, we conclude the following: a) the significant differences in the Fe oxidation state between LDG and tektites, together with the wide intra‐sample variations in the Fe‐oxidation state, confirm that LDG is an impact glass and not a tektite‐like glass; b) the higher Fe content, coupled with the more reduced state of the Fe, in the Fe‐rich layers suggests that some or most of the Fe in these layers may be directly derived from the meteoritic projectile and that it is not of terrestrial origin.  相似文献   

Environmental hydrogeology of the southern sector of the Samborombon Bay wetland,Argentina     

Eleonora Carol  Eduardo Kruse  Jorge Pousa 《Environmental Geology》2008,54(1):95-102

The Samborombon Bay wetland is located on the west margin of the Rio de la Plata estuary, in the Province of Buenos Aires, Argentina. This paper analyses the geological, geomorphologic, soil and vegetation characteristics of the southernmost sector of this wetland and their influence on surface water and groundwater. The study area presents three hydrologic units: coastal dunes, sand sheets and coastal plain. Coastal dunes and sand sheets are recharge zones of high permeability with well-drained, non-saline soils, and a few surface water flows. Changes in the water table are related to rainfall. Groundwater in coastal dunes is Ca–Mg–HCO₃ to Na–HCO₃, and of low salinity (590 mg/l). Groundwater in sand sheets is mainly Na–HCO₃ with a salinity of about 1,020 mg/l. The coastal plain exhibits medium to low permeability sediments, with submerged saline soils poorly drained. Groundwater is Na–Cl with a mean salinity of 16,502 mg/l. A surface hydrological network develops in the coastal plain. Surface water levels near the shoreline are affected by tidal fluctuations; far from the shoreline water accumulates because of poor drainage. Both sectors have Na–Cl water, but the former is more saline. Human intervention and sea level rise may affect the wetland severely.  相似文献   

The local structure of Ca-Na pyroxenes. I. XANES study at the Na K-edge     

Annibale Mottana  Takatoshi Murata  Ziyu Wu  Augusto Marcelli  Eleonora Paris 《Physics and Chemistry of Minerals》1997,24(7):500-509

 X-ray absorption Na K-edge spectra have been recorded on synthetic endmember jadeite and on a series of natural Ca-Na pyroxenes compositionally straddling the Jd-Di join. The C2/c members of the series are systematically different from the P2/n members. Differences can be interpreted and explained by comparing the experimental spectra with theoretical spectra. These have been calculated by the multiple-scattering formalism from the atomic positional parameters determined by single-crystal X-ray diffraction structure refinement on the same samples. In the full multiple scattering region of the spectra (1075 to 1090 eV) C-pyroxenes exhibit three features which reflect the 6-2 configuration of the O back-scattering atoms around the Na absorber located at the center of the cluster (site M2 of the jadeite structure). P-pyroxenes show more complicated spectra in which at least four (possibly five) features can be recognized; they reflect the two types of configuration (6-2 and 4-2-2) of O around Na in the two independent M2 and M21 eight-fold coordinated sites of the omphacite structure. A weak, sometimes poorly resolved peak at 1079 eV is diagnostic and discriminates C- from P-pyroxenes. The Garnet Ridge C2/c impure jadeite exhibits a spectrum which is intermediate between those of jadeite and omphacite. The Hedin-Lundqvist potential proves best for these insulating materials and allows multiple-scattering calculations agreeing well with experiments. Received: July 11, 1996/Revised, accepted: October 21, 1996  相似文献   

Intra-interstadial environmental changes in Last Glacial loess revealed by molluscan assemblages from the Upper Palaeolithic site of Amiens-Renancourt 1 (Somme,France)     

Olivier Moine  Pierre Antoine  Sylvie Coutard  Gilles Guérin  Christine Hatté  Clément Paris  Ségolène Saulnier-Copard 《第四纪科学杂志》2021,36(8):1322-1340

The Amiens-Renancourt 1 site recently yielded one of the most important Upper Palaeolithic human occupations of northern France by the number of flint artefacts and especially by the presence of Venus figurines. All the material comes from a single archaeological layer located in a tundra gley bracketed by loess units. A multi-proxy study combining a detailed stratigraphy, luminescence and radiocarbon datings and high-resolution (5 cm per sample) grain size and molluscan analyses was therefore carried out to reconstruct and date the associated environmental changes and to determine the exact context of the human occupation. The chronological frame thus established supports the correlations of the archaeology-bearing tundra gley and of an underlying arctic brown soil with Greenland interstadials GI-4 and GI-3. Composition changes in the molluscan population enabled the identification of transitional and optimum phases and sub-phases within these two pedogenetic horizons. A conceptual correlation model linking molluscan phases with millennial-scale variations of Greenland ice-core and Sieben Hengste speleothem climate records is proposed. The Human occupation appears contemporaneous to the end of the stadial–interstadial transition of GI-3. Synchronous in Amiens-Renancourt 1 and Nussloch, subsequent micro-gleys may also result from a regional/global forcing. Such a level of detail is unprecedented in a loess sequence.  相似文献   

Wave attenuation in the marginal ice zone during LIMEX     

Antony K. Liu  Paris W. Vachon  Chin Y. Peng  A.S. Bhogal 《大气与海洋》2013,51(2):192-206

Abstract

During the Labrador Ice Margin Experiments, LIMEX ‘87 in March 1987 and LIMEX ‘89 in March and April 1989, the Canada Centre for Remote Sensing (CCRS) CV‐580 aircraft collected synthetic aperture radar (SAR) image data over the marginal ice zone off the east coast of Newfoundland, Canada. One aspect of these experimental programs was the observation of ocean waves penetrating into the marginal ice zone (MIZ). Based upon directional wavenumber spectra derived from SAR image data, the wave attenuation rate is estimated using SAR image spectra and compared with predictions from a model developed by Liu and Mollo‐Christensen (1988). The wave and ice conditions were considerably different in LIMEX ‘87 and LIMEX ‘89. However, the model‐data comparisons are very good for all ice conditions observed. Both the model and the SAR‐derived wave attenuation rates show a characteristic roll‐over at high wavenumbers. A model for the eddy viscosity is proposed, using dimensional analysis, as a simple function of ice roughness and wave‐induced velocity. Eddy viscosities derived from SAR and wave buoy data for the wave attenuation rate show a trend that is consistent with the proposed model.  相似文献   

Iron site geometry in orthopyroxene: Multiple scattering calculations and XANES study     

Eleonora Paris  Trevor A. Tyson 《Physics and Chemistry of Minerals》1994,21(5):299-308

The iron site geometry in orthopyroxenes (OPX) and synthetic FeO, has been investigated by X-ray Absorption Near Edge Structure (XANES) spectroscopy. Multiple scattering calculations have been used to determine how the iron polyhedral geometry affects the absorption spectra. The results reported here demonstrate that this approach is effective in determining the site geometry around the absorbing atom, allowing the assignment of features in the XANES spectrum to specific structural aspects of the coordination environment. In the case of the orthopyroxenes this method allows discrimination between the multiple scattering contributions to the absorption spectrum due to the two octahedral sites M1 and M2 of the OPX structure. The results obtained with the MS calculation were used to evaluate the effects of polyhedral distortion, symmetry changes and iron site occupancies on the experimental spectra. The results indicate a more quantitative way to interpret XANES experimental spectra and give insights into the interpretation of site geometries of more complex or unknown structures and amorphous materials.  相似文献   

Thaumasite from the Tschwinning mine,South Africa     

O. Grubessi  A. Mottana  E. Paris 《Mineralogy and Petrology》1986,35(3):149-156

Summary Thaumasite from the manganese mine of Tschwinning, South Africa, has the formula Ca_3.097 Si_1.062OH_6.372(CO₃)_0.994(SO₄)_1.000·11.596 H₂O. Unit cell parameters (a=11.013(2) Å,c=10.379(5) Å,V=1090.1(6) ų) and refraction indices (n_e=1.458(2),n _o=1.498(2)) compare well with the best ones available in the literature. The IR spectrum and DT-TG profiles are given. Contradictions between the IR spectrum, a recent structural refinement and the DT-TG are discussed, but cannot be explained satisfactorily.

---

Thaumasit aus der Mangan-Mine von Tschwinning, Süd-Afrika

Zusammenfassung Thaumasit aus der Mangan-Mine von Tschwinning, Süd-Afrika, besitzt die Formel Ca_3.097 Si_1.062OH_6.372(CO₃)_0.994(SO₄)_1.000·11.596 H₂O. Die Parameter der Elementarzelle (a=11.013(2) Å,c=10.379(5) Å,V=1090.1(6) ų) und die Brechungsindizes (n _e=1.458(2),n _o=1.498(2)) zeigen gute Übereinstimmung mit verfügbaren Literaturdaten. Es werden ein IR-Spektrum und DT-TG-Profile präsentiert. Gegensätze zwischen dem IR-Spektrum, einer neueren Strukturverfeinerung und dem DT-TG werden diskutiert, können jedoch nicht zufriedenstellend erklärt werden.

---

---

With 2 Figures  相似文献   

Granulite-amphibolite facies metasediments from the Serre (Calabria,Southern Italy): their protoliths and the processes controlling their chemistry     

Eleonora Maccarrone  Antonio Paglionico  Giuseppe Piccarreta  Allesandro Rottura 《Lithos》1983,16(2):95-111

In the northwestern Serre, a near continuous section through the Palaeozoic lower continental crust crops out. This paper deals with granulite facies metasedimentary rocks of this section. Fifty-five chemical analyses (major elements, Sc, V, Cr, Co, Ni, Rb, Sr, Y, Nb and Ba) are given. Chemical data indicate that the original sedimentary sequence was made up of arenites in the lower part and mainly Fe and Mg rich pelites in the upper part. The metapelites experienced anatexis and removal of some melt, whereas the meta-arenites suffered only incipient anatexis and became dehydration granulites. The various rock types display an overall relatively low K/Rb ratio due mainly to the stability of K- and Rb-retaining phases. A weighted mean composition of the fragment of the lower continental crust outcropping in the Serre has been established by integrating the chemical data for metasediments (55 analyses), metabasites (92 analyses) and dioritic and tonalitic gneisses (10 analyses) with the field data. This composition compared to the compositions of the bulk continental crust and of other sections considered as belonging to the lower crust, confirms the hypothesis that (1) the lower crust is heterogeneous, and (2) it is more basic than the continental crust.  相似文献   

Consequences of a freshwater canal discharge on the benthic community and its habitat on an exposed sandy beach     

Lercari D  Defeo O  Celentano E 《Marine pollution bulletin》2002,44(12):1397-1404

This paper analyses the spatial and temporal effects of a freshwater discharge (Canal Andreoni) on the macroinfauna community and its habitat in a sandy beach of Uruguay. Bimonthly, we examined 17 environmental variables plus macroinfauna abundance, biomass, richness, evenness and diversity of three sites: Andreoni, at the canal mouth, Coronilla, at 1 km, and Barra, at 13 km from the mouth. Both univariate and multivariate techniques showed an increasing degree of perturbation towards the canal. This was reflected by abiotic and biotic differences between sites and by a consistent two-dimensional ordination of the samples. A clear seasonal pattern was found, specially accentuated at Coronilla, where the effects of the canal were stronger in winter and weaker in summer. Multivariate linking between macroinfauna and its habitat highlighted the role of salinity as explanatory variable of the observed trends.  相似文献   

Re-Os geochronology of Cu and W-Mo deposits in the Balkhash metallogenic belt,Kazakhstan and its geological significance   总被引：2，自引：0，他引：2  

Xuanhua Chen  Wenjun Qu  Shuqin Han  Seitmuratova Eleonora  Nong Yang  Zhengle Chen  Fagang Zeng  Andao Du  Zhihong Wang 《地学前缘(英文版)》2010,1(1)

<正>The Central Asian metallogenic domain(CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems.The Balkhash metallogenic belt in Kazakhstan,in which occur many large and super-large porphyritic Cu—Mo deposits and some quartz vein- and greisen-type W—Mo deposits,is a well-known porphyritic Cu—Mo metallogenic belt in the CAMD.In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re—Os compositional analyses and Re—Os isotopic dating.Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W—Mo deposits—East Kounrad.Akshatau and Zhanet—all have relatively high Re contents(2712—2772μg/g for Borly and 2.267—31.50μg/g for the other three W—Mo deposits),and lower common Os contents(0.670—2.696 ng/g for Borly and 0.0051—0.056 ng/g for the other three).The molybdenites from the Borly porphyry Cu—Mo deposit and the East Kounrad,Zhanet,and Akshatau quartz vein- and greisen-type W—Mo deposits give average model Re—Os ages of 315.9 Ma,298.0 Ma,295.0 Ma,and 289.3 Ma respectively.Meanwhile,molybdenites from the East Kounrad,Zhanet,and Akshatau W—Mo deposits give a Re—Os isochron age of 297.9 Ma,with an MSWD value of 0.97.Re-Os dating of the molybdenites indicates that Cu—W—Mo metallogenesis in the western Balkhash metallogenic belt occurred during Late Carboniferous to Early Permian(315.9—289.3 Ma),while the porphyry Cu—Mo deposits formed at—316 Ma,and the quartz vein-greisen W—Mo deposits formed at ~298 Ma.The Re—Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercynian movement.Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China,the formation of the Cu—Mo metallogenesis in the Balkhash metallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively,the large-scale Late Carboniferous porphyry Cu—Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.  相似文献