Determination of the Tin Stable Isotopic Composition in Tin‐bearing Metals and Minerals by MC‐ICP‐MS          下载免费PDF全文

Gerhard Brügmann  Daniel Berger  Ernst Pernicka 《Geostandards and Geoanalytical Research》2017,41(3):437-448

This study uses MC‐ICP‐MS for the precise analysis of the stable tin isotopic composition in ore minerals of tin (cassiterite, stannite), tin metal and tin bronze. The ultimate goal is to determine the provenance of tin in ancient metal objects. We document the isotope compositions of reference materials and compare the precision of different isotope ratios and the accuracy of different procedures of mass fractionation correction. These data represent a base with which isotopic data of future studies can be directly compared. The isotopic composition of cassiterite and stannite can be determined after reduction to tin metal and bronze, respectively. Both metals readily dissolve in HCl, but while the solutions of tin metal can be directly measured, the bronze solutions must be purified with an anion exchanger. The correction of the mass bias is best performed with an internal Sb standard and an empirical regression method. A series of Sn isotope determinations on commercially available mono‐element Sn solutions as well as reference bronze materials and tin minerals show fractionations ranging from about ?0.09‰ to 0.05‰/amu. The combined analytical uncertainty (2s) was determined by replicate dissolutions of reference materials of bronze (BAM 211, IARM‐91D) and averages at about 0.005‰/amu.  相似文献   

Stable Sulfur Isotopic Evidence for Historical Changes of Sulfur Cycling in Estuarine Sediments from Northern Florida     

Volker Brüchert  Lisa M. Pratt 《Aquatic Geochemistry》1999,5(3):249-268

Data on abundance and isotopic composition of porewater and sedimentary sulfur species are reported for relatively uncontaminated and highly contaminated fine-grained anoxic sediments of St. Andrew Bay, Florida. A strong contrast in amount and composition of sedimentary organic matter at the two sites allows a comparative study of the historical effects of increased organic loading on sulfur cycling and sulfur isotopic fractionation. In the contaminated sediments, an increase in organic loading caused increased sedimentary carbon/sulfur ratios and resulted in higher rates of bacterial sulfate reduction, but a lower efficiency of sulfide oxidation. These differences are well reflected in the isotopic composition of dissolved sulfate, sulfide, and sedimentary pyrite. Concentration and isotopic profiles of dissolved sulfate, organic carbon, and total sulfur suggest that the anaerobic decomposition of organic matter is most active in the upper 8cm but proceeds at very slow rates below this depth. The rapid formation of more than 90% of pyrite in the uppermost 2 cm which corresponds to about 3 years of sediment deposition allows the use of pyrite isotopic composition for tracing changing diagenetic conditions. Sediment profiles of the sulfur isotopic composition of pyrite reflect present-day higher rates of bacterial sulfate reduction and lower rates of sulfide oxidation, and record a profound change in the diagenetic cycling of sulfur in the contaminated sediments coincident with urban and industrial development of the St. Andrew Bay area.  相似文献   

Modern and historical tropical cyclone and tsunami deposits at the coast of Myanmar: Implications for their identification and preservation in the geological record     

Dominik Brill  Katharina Seeger  Anna Pint  Felix Reize  Kay Thwe Hlaing  Martin Seeliger  Stephan Opitz  Khin Mi Mi Win  Win Thuzar Nyunt  Nilar Aye  Aung Aung  Kyaw Kyaw  Frauke Kraas  Helmut Brückner 《Sedimentology》2020,67(3):1431-1459

The catastrophic storm surge of tropical cyclone Nargis in May 2008 demonstrated Myanmar's exposure to coastal flooding. The investigation of sediments left by tropical cyclone Nargis and its predecessors is an important contribution to prepare for the impact of future tropical cyclones and tsunamis in the region, because they may extend the database for long-term hazard assessment beyond the relatively short instrumental and historical record. This study, for the first time, presents deposits of modern and historical tropical cyclones and tsunamis from the coast of Myanmar. The aim is to establish regional sedimentary characteristics that may help to identify and discriminate cyclones and tsunamis in the geological record, and to document post-depositional changes due to tropical weathering in the first years after deposition. These findings if used to interpret older deposits will extend the existing instrumental record of flooding events in Myanmar. Evaluating deposits that can be related to specific events, such as the 2006 tropical cyclone Mala and the 2004 Indian Ocean tsunami, indicates similar sedimentary characteristics for both types of sediments. Landward thinning and fining trends, littoral sediment sources and sharp lower contacts allow for the differentiation from underlying deposits, while discrimination between tropical cyclone and tsunami origin is challenging based on the applied methods. The modern analogues also demonstrate a rather low preservation potential of the sand sheets due to carbonate dissolution, formation of organic top soils, and coastal erosion. However, in coastal depressions sand sheets of sufficient thickness (>10 cm) may be preserved where the shoreline is prograding or stable. In the most seaward swale of a beach-ridge plain at the Rakhine coast, two sand sheets have been identified in addition to the deposits of 2006 tropical cyclone Mala. Based on a combination of optically stimulated luminescence, radiocarbon and ¹³⁷Cs dating, the younger sand layer is related to 1982 tropical cyclone Gwa, while the older sand layer is most probably the result of an event that took place prior to 1950. Comparison with historical records indicates that the archive is only sensitive to tropical cyclones of category 4 (or higher) with landfall directly in or a few tens of kilometres north of the study area. While the presented tropical cyclone records are restricted to the last 100 years, optically stimulated luminescence ages of the beach ridges indicate that the swales landward of the one investigated in this study might provide tropical cyclone information for at least the past 700 years.  相似文献   

Experimental investigation on sea ripple evolution over sloping beaches     

Carmelo Petrotta  Carla Faraci  Pietro Scandura  Enrico Foti 《Ocean Dynamics》2018,68(9):1221-1237

This paper reports on a wave flume experimental campaign carried out to investigate the appearance, the growth and the migration of small scale bedforms on a sloping sandy bed due to both regular and random waves. A Vectrino Profiler along with a structured light approach were used for velocity and morphodynamic measurements at two positions, one located above the horizontal bed, and the other one above the sloping beach. The velocity was computed by phase averaging the velocity measurements. Several velocity profiles were analyzed, identifying an offshore-directed steady current that extends from few centimeters above the bottom for all the analyzed water column. Ripple geometry was measured by a structured light approach and compared with that predicted by several models to shed light on the effects induced by the sloping beach on the shape and asymmetry. Along the sloping beach, the ripples appeared strongly asymmetric with the onshore half wavelengths smaller than the offshore ones. Finally, ripple geometry and migration triggered by regular waves were compared with those generated by random waves with comparable flow orbital amplitude showing a good agreement.  相似文献   

The influence of structural organization of epilithic and endolithic lichens on limestone weathering          下载免费PDF全文

Mariagrazia Morando  Katrin Wilhelm  Enrica Matteucci  Luca Martire  Rosanna Piervittori  Heather A. Viles  Sergio Enrico Favero‐Longo 《地球表面变化过程与地形》2017,42(11):1666-1679

Hyphal penetration, mineral dissolution and neoformation at the lichen–rock interface have been widely characterized by microscopic and spectroscopic studies, and considered as proxies of lichen deterioration of stone substrates. However, these phenomena have not been clearly related to experimental data on physical properties related to stone durability, and the physical consequences of lichen removal from stone surfaces have also been overlooked. In this study, we combine microscopic and spectroscopic characterization of the structural organization of epi‐ and endolithic lichens (Caloplaca marina (Wedd.) Du Rietz, Caloplaca ochracea (Schaer.) Flagey, Bagliettoa baldensis (A.Massal.) Vězda, Porina linearis (Leight.) Zahlbr., Verrucaria nigrescens Pers.) at the interface with limestones of interest for Cultural Heritage (Portland Limestone, Botticino Limestone), with analysis of rock properties (water absorption, surface hardness) relevant for durability, before and after the removal or scraping of lichen thalli. Observations using reflected‐light and electron microscopy, and Raman analyses, showed lichen–limestone stratified interfaces, differing in the presence/absence and depth of lichen anatomical layers (lithocortex, photobiont layer, pervasive and sparse hyphal penetration component) depending on species and lithology. Specific structural organizations of lichen–rock interface were found to be associated with differential patterns of water absorption increase, evaluated by Karsten tube, in comparison with surfaces with microbial biofilms only, even more pronounced after the removal or scraping of the upper structural layers. Equotip measurements on surfaces bearing intact thalli showed lower hardness in comparison with control surfaces. By contrast, after the removal or scraping procedures, Equotip values were similar to or higher than those of controls, suggesting that the increasing open porosity may be related to a biogenic hardening process. Such counterposed patterns of porosity increase and hardening need to be considered when models relating lichen occurrence on limestones and biogeomorphological surface evolution are proposed, and to evaluate the consequences of lichen removal from stone‐built cultural heritage. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Seismic depth imaging of iron-oxide deposits and their host rocks in the Ludvika mining area of central Sweden     

Lena Bräunig  Stefan Buske  Alireza Malehmir  Emma Bäckström  Monica Schön  Paul Marsden 《Geophysical Prospecting》2020,68(1):24-43

The development of cost-effective and environmentally acceptable geophysical methods for the exploration of mineral resources is a challenging task. Seismic methods have the potential to delineate the mineral deposits at greater depths with sufficiently high resolution. In hardrock environments, which typically host the majority of metallic mineral deposits, seismic depth-imaging workflows are challenged by steeply dipping structures, strong heterogeneity and the related wavefield scattering in the overburden as well as the often limited signal-to-noise ratio of the acquired data. In this study, we have developed a workflow for imaging a major iron-oxide deposit at its accurate position in depth domain while simultaneously characterizing the near-surface glacial overburden including surrounding structures like crossing faults at high resolution. Our workflow has successfully been showcased on a 2D surface seismic legacy data set from the Ludvika mining area in central Sweden acquired in 2016. We applied focusing prestack depth-imaging techniques to obtain a clear and well-resolved image of the mineralization down to over 1000 m depth. In order to account for the shallow low-velocity layer within the depth-imaging algorithm, we carefully derived a migration velocity model through an integrative approach. This comprised the incorporation of the tomographic near-surface model, the extension of the velocities down to the main reflectors based on borehole information and conventional semblance analysis. In the final step, the evaluation and update of the velocities by investigation of common image gathers for the main target reflectors were used. Although for our data set the reflections from the mineralization show a strong coherency and continuity in the seismic section, reflective structures in a hardrock environment are typically less continuous. In order to image the internal structure of the mineralization and decipher the surrounding structures, we applied the concept of reflection image spectroscopy to the data, which allows the imaging of wavelength-specific characteristics within the reflective body. As a result, conjugate crossing faults around the mineralization can directly be imaged in a low-frequency band while the internal structure was obtained within the high-frequency bands.  相似文献