氧化锰矿物的生物成因及其性质的研究进展   总被引：5，自引：0，他引：5  

刘凡  冯雄汉  陈秀华  邱国红  谭文峰  贺纪正 《地学前缘》2008,15(6):66

土壤中的氧化锰矿物是原生矿物风化和成土过程的产物,是最具反应活性的一类矿物,决定着环境中许多物质的形态、迁移和转化,在元素生物地球化学循环中起着重要的作用,其形成机制和环境效应备受关注。已有的研究表明,环境中氧化锰的形成与微生物作用紧密相关,微生物作用可使自然环境中的Mn(Ⅱ)氧化速率提高105倍。参与Mn(Ⅱ)氧化的微生物在环境中广泛存在,已知的典型锰氧化细菌分布在变形菌门、放线菌门或厚壁菌门,它们均通过胞外聚合物中的多铜氧化酶来催化氧化Mn(Ⅱ)。细菌氧化Mn(II)成Mn(Ⅳ)是酶催化的两个连续的快速单电子传递过程,Mn(Ⅲ)在溶液中以与酶结合的瞬时中间态出现。生物形成氧化锰的最初形态为层状锰矿物,与δ-MnO2或酸性水钠锰矿很类似,且结晶弱,粒径小,锰氧化度高,结构中的八面体空穴多,因而比化学形成的氧化锰具有更强的吸附、氧化等表面活性。环境中Mn(Ⅱ)微生物氧化及形成的Mn(Ⅲ)中间体与碳、氮、硫等生命元素的地球化学循环的关系令人关注。  相似文献   

研究“源兆”的若干问题及途径分析   总被引：3，自引：3，他引：0  

王贵宣  张肇诚 《地震》1996,16(4):391-395

从位场理论的观点讨论了场和源的概念,建议将“场兆”改称为构造前兆,将“源兆”称为震源前兆。文中还分析了震源体与各种前兆观测方法探测的深度,并根据地磁与重力观测方法不同的物理基础和地质基础,指出震磁效应对于研究震源前兆的特殊意义,文中还介绍了１９７６唐山地震观测到震源前兆的部分实际地磁资料。  相似文献   

化探背景与异常划分中的C型转换法     

陈明  范继璋  矫希国 《吉林大学学报(地球科学版)》1996,(2)

化学背景与异常在统计学上的差异同时表现在浓度和变差两个方面。在划分背景与异常时,把这两方面信息提取出来并作显化处理,使背景与异常的差别更大,以利划分,这就是Ｃ型转换的基本思想。介绍了Ｃ型转换法的基本原理及其在条件模拟和实际金矿区中的应用。  相似文献   

Gold Solubility in SiO2—HCl—H2O System at 200℃：a Preliminary Assessment of the Implications of Silicification with Regard to Gold Mineralization     

Shengyuan Wang  Wenling Fan 《中国地球化学学报》1994,13(1):13-23

The complexation between gold and silica was experimentally, confirmed and calibrated at 200 °C: $$\begin{gathered} Au^ + + H_3 SiO_4^ - \rightleftharpoons AuH_3 SiO_4^0 \hfill \\ \log K_{(200^\circ C)} = 19.26 \pm 0.4 \hfill \\ \end{gathered} $$ Thermodynamic calculations show that AuH₃SiO ₄ ⁰ would be far more abundant than AuCl ₂ ^? under physicochemical conditions of geological interest, suggesting that silica is much more important than chloride as ligands for gold transport. In systems containing both sulfur and silica, AuH₃SiO ₄ ⁰ would be increasingly more important than Au (HS) ₂ ^? as the proportion of SiO₂ in the system increases. The dissolution of gold in aqueous SiO₂ solutions can be described by the reaction: $$\begin{gathered} Au + 1/4O_2 + H_4 SiO_4^0 \rightleftharpoons AuH_3 SiO_4^0 + 1/2H_2 O \hfill \\ log K_{(200^\circ C)} = 6.23 \hfill \\ \end{gathered} $$ which indicates that SiO₂ precipitation is an effective mechanism governing gold deposition, and thus explains the close association of silicification and gold mineralization.  相似文献   

青藏高原东南缘次林错岩体晚白垩世- 早新生代快速剥蚀     

沈续文  沈晓明  刘静  曾令森  杨超群  葛玉魁  邢宇堃  曾宪阳  王子君  李云帅  李金阳 《地质学报》2022,96(10):3332-3344

青藏高原东南缘是研究构造、地貌演化和气候变化相互作用的理想场所，前人研究主要揭示了晚始新世—早中新世和晚中新世以来的快速剥蚀事件，缺乏晚白垩世—早新生代时期地貌演化过程的研究。次林错花岗岩已有的低温热年代学数据覆盖了整个新生代时期，为探索该区域新生代早期的剥露演化历史提供了重要资料。该岩体新生代早期冷却事件是岩浆冷却单一作用的结果，还是受快速剥蚀作用的影响，目前仍然存疑，需要定量研究。因此，本文结合已有的岩石地化和年代学数据，对次林错花岗岩开展了锆石饱和温度和一维岩浆冷却模拟研究。锆石饱和温度计算结果表明次林错花岗岩的岩浆结晶温度介于647~705℃之间，属低温花岗岩。一维岩浆冷却模拟结果显示岩体侵位时的最小围岩温度为160~120℃，对应深度约为3. 7~5. 0 km。结合锆石和磷灰石(U- Th)/He年代学数据，本文认为该岩体在晚白垩世—早新生代时期(67~40 Ma)经历了一期剥蚀量至少为2 km的快速剥蚀事件。已发表成果的综合分析表明，此次快速剥露事件可能是整个青藏高原地区广泛存在的构造剥蚀事件，新特提斯洋的俯冲闭合与印亚板块的初始碰撞可能是触发此次大规模区域剥蚀的主要原因  相似文献   

Two-dimensional pH distributions and dynamics in bioturbated marine sediments   总被引：2，自引：0，他引：2  

Qingzhi Zhu  Yanzhen Fan 《Geochimica et cosmochimica acta》2006,70(19):4933-4949

The seafloor is the site of intense biogeochemical and mineral dissolution-precipitation reactions which generate strong gradients in pH near the sediment-overlying water interface. These gradients are usually measured in one-dimension vertically with depth. Two-dimensional pH distributions in marine sediments were examined at high resolution (65 × 65 μm pixel) and analytical precision over areas of ∼150 to 225 cm² using a newly developed pH planar fluorosensor. Dramatic three-dimensional gradients, complex heterogeneity, and dynamic changes of pH occur in the surficial zone of deposits inhabited by macrofauna. pH can vary by ±2 units horizontally as well as vertically over millimeter scales. pH minima zones often form in association with redoxclines within a few millimeters of inner burrow walls, and become more pronounced with time if burrows remain stable and irrigated for extended periods. Microenvironmental pH minima also form locally around decaying biomass and relict burrow tracks, and dissipate with time (∼5 d). H⁺ concentrations and fluxes in sandy mud show complex acid-base reaction distributions with net H⁺ fluxes around burrows up to ∼12 nmol cm⁻² d⁻¹ and maximum net reaction rates varying between −90 (consumption) to 120 (production) μM d⁻¹ (∼90 nmol cm⁻¹ d⁻¹ burrow length). Acid producing zones that surround irrigated burrows are largely balanced by acid titration zones along inner burrow walls and outer radial boundaries. The geometry and scaling of pH microenvironments are functions of diagenetic reaction rates and three-dimensional transport patterns determined by sediment properties, such as diffusive tortuosity, and by benthic community characteristics such as the abundance, mobility, and size of infauna. Previously, undocumented biogeochemical phenomena such as low pH regions associated with in-filled relict biogenic structures and burrowing tracks are readily demonstrated by two-dimensional and time-dependent images of pH and sedimentary structure.  相似文献   

Fluid unmixing/immiscibility as an ore-forming process in the giant REE–Nb–Fe deposit, Inner Mongolian, China: Evidence from fluid inclusions     

Hong-Rui Fan  Fang-Fang Hu  Kui-Feng Yang  Kai-Yi Wang 《Journal of Geochemical Exploration》2006,89(1-3):104

The giant Bayan Obo REE–Nb–Fe deposit consists of replacement bodies hosted in dolomite marble made up of magnetite, REE fluorocarbonates, fluorite, aegirine, amphibole, calcite and barite. Two or three phase CO₂-rich, three phase hypersaline liquid–vapor–solid, and two phase liquid-rich inclusions have been recognized in mineralized fluorite and quartz samples. Microthermometry measurements indicate that the carbonic phase in CO₂-rich inclusions is nearly pure CO₂. Fluids involving in REE–Nb–Fe mineralization at Bayan Obo might be mainly of H₂O–CO₂–NaCl–(F–REE) system. Coexistences of brine inclusions and CO₂-rich inclusions with similar homogenization temperatures give evidence that immiscibility happened during REE mineralization. An unmixing of an original H₂O–CO₂–NaCl fluid probably derived from carbonatitic magma. The presence of REE-carbonates as an abundant solid in fluid inclusions shows that the original ore-forming fluids are very rich in REE, and therefore, have the potential to produce economic REE ores at Bayan Obo.  相似文献   

辽东栎萌生个体的地上生物量及其构件分配与生长参数的关系   总被引：1，自引：0，他引：1  

孟令彬  包维楷  张咏梅  庞学勇  孙凡 《山地学报》2006,24(2):202-208

选择岷江上游海拔2100-2300m地段的辽东栎萌生株个体69株，测定了每株生长参数（年龄、高度、基径、冠幅）、各器官生物量及地上总生物量，分析了各器官生物量及构件分配与生长参数的相互关系。结果表明，辽东栎萌生株构件分配的大小排序为：茎干〉枝〉皮〉叶：随径级增大。茎干、大枝生物量所占总生物量比例上升，其他器官所占比例减小。辽东栎年龄与高度呈S曲线关系，其他均表现出很好的幂指数函数关系；各构件器官生物量与生长参数大多也呈幂指数函数W=aD^h（D为基径）关系。基径为估测辽东栎萌生株地上各器官生物量及总生物量的最佳因子。  相似文献   

邢台矿区山字型构造的发现及其地质意义   总被引：1，自引：0，他引：1  

张纪勋  范志平 《中国煤田地质》2006,18(4):18-21

邢台山字型构造位于河北省邯邢煤田内，其前弧向ES突出，脊柱呈ES-WN走向。分别分析了山字型构造脊柱及其东、西翼反射弧构造形迹特征，对研究区找矿具有重要意义。  相似文献   

淮北煤田孙庄勘探区煤层气赋存规律及影响因素分析     

樊爱英 《中国煤田地质》2006,18(5):25-27

通过对淮北煤田孙庄勘探区地质构造、沉积特征、煤层煤质及煤层气赋存特征的分析，研究认为有利于本区煤层气赋存的主要因素是较大的埋藏深度、较高的壳质组＋镜质组、较高的变质程度、较大的煤层厚度、低透气性的盖层、较缓的地层倾角和封闭性较好的构造条件，推测煤田深部可能具有一定工业价值的煤层气资源。  相似文献