Fluid inclusions in chromite from a pyroxenite dike of the Pindos ophiolite complex     

Ahmed Al-Boghdady  Maria Economou-Eliopoulos 《Chemie der Erde / Geochemistry》2005,65(2):191-202

Chromitite occurrences in the Pindos ophiolite complex are located in elongated dunite bodies hosted in harzburgite of the mantle sequence, and show a compositional variation from high-Al to high-Cr type. Although the majority of the chromite ores is characterized by paucity in fluid inclusions, abundant fluid inclusions were found in chromite hosted by a coarse-grained pyroxenite dike at the Spanos Valley, Pindos complex. Chromite occurs in highly variable proportion in an orthopyroxene matrix or as inclusions in orthopyroxenes. Its composition is homogeneous and has an average Cr/(Cr+Al) ratio 0.73.The investigation of chromitites revealed the presence of primary and secondary fluid inclusions. The primary inclusions are of following types: Three-phase solid-liquid-gas, three-phase liquid-liquid-gas, two-phase liquid-gas and one-phase octahedron crystal-shaped. The secondary fluid inclusions are two-phase liquid-gas and mono-phase fluid inclusions.The presence of fluid inclusions in chromite aggregates hosted in orthopyroxenite dikes, in combination with the trace element contents in chromite concentrates and the mineralogical composition of the dikes may indicate that an aqueous phase separated from the magma.  相似文献   

Reply to the discussion to “On the evolution of salt diapirs in Tunisian Atlas” by Christopher J. Talbot     

Chokri Jallouli  Mongi Chikhaoui  Ahmed Brahem  Mohamed Moncef Turki  Kevin Mickus  Ramdhane Benassi 《Tectonophysics》2005,406(3-4):255-258

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A menagerie of graphite morphologies in the Acapulco meteorite with diverse carbon and nitrogen isotopic signatures: Implications for the evolution history of acapulcoite meteorites     

Ahmed El Goresy  Ernst Zinner  Catherine Caillet 《Geochimica et cosmochimica acta》2005,69(18):4535-4556

Morphologies, petrographic settings and carbon and nitrogen isotopic compositions of graphites in the Acapulco meteorite, the latter determined by secondary ionization mass spectrometry, are reported. Seven different graphite morphologies were recognized, the majority of which occur enclosed exclusively in kamacite. Individual graphite grains also rarely occur in the silicate matrix. Kamacite rims surrounding taenite cores of metal grains are separated from the Ni-rich metal cores by graphite veneers. These graphite veneers impeded or prevented Ni-Fe interdiffusion during cooling. In addition, matrix FeNi metal contains considerable amounts of phosphorous (≈ 700 ppm) and silicon (≈ 300 ppm) (Pack et al., 2005 in preparation) thus indicating that results of laboratory cooling experiments in the Fe-Ni binary system are inapplicable to Acapulco metals. Graphites of different morphologies display a range of carbon and nitrogen isotopic compositions, indicating a diversity of source regions before accretion in the Acapulco parent body. The isotopic compositions point to at least three isotopic reservoirs from which the graphites originated: (1) A reservoir with heavy carbon, represented by graphite in silicates (δ¹³C = 14.3 ± 2.4 ‰ and δ¹⁵N = −103.4 ± 10.9 ‰), (2) A reservoir with isotopically light carbon and nitrogen, characteristic for the metals. Its C- and N-isotopic compositions are probably preserved in the graphite exsolutions that are isotopically light in carbon and lightest in nitrogen (δ¹³C = −17 to −23 ‰ δ¹⁵N = −141 to −159 ‰). (3) A reservoir with an assumed isotopic composition (δ¹³C ∼ −5 ‰; δ¹⁵N ∼ −50 ‰). A detailed three-dimensional tomography in reflected light microscopy of the decorations of metal-troilite spherules in the cores of orthopyroxenes and olivines and metal-troilite veins was conducted to clarify their origin. Metal and troilite veins are present only near the fusion crust. Hence, these veins are not pristine to Acapulco parent body but resulted during passage of Acapulco in Earth’s atmosphere. A thorough search for symplectite-type silicate-troilite liquid quench textures was conducted to determine the extent of closed-system partial silicate melting in Acapulco.Metal-troilite spherules in orthopyroxenes and olivines are not randomly distributed but decorate ferromagnesian silicate restite cores, indicating that the metal-spherule decoration around restite silicates took place in a silicate partial melt. Graphite inclusions in these spherules have C- and N- isotopic compositions (δ¹³C = −2.9 ± 2.5 ‰ and δ¹⁵N = −101.2 ± 32 ‰) close to the average values of graphite in metals and in the silicate matrix, thus strongly suggesting that they originated from a mixture of graphite inclusions in metals and silicate matrix graphite during a closed system crystallization process subsequent to silicate-metal-sulfide partial melting. Troilite-orthopyroxene quench symplectite textures in orthopyroxene rims are clear evidence that silicate-sulfide partial melting took place in Acapulco. Due to petrographic heterogeneity on a centimeter scale, bulk REE abundances of individual samples or of individual minerals provide only limited information and the REE abundances alone are not entirely adequate to unravel the formational processes that prevailed in the acapulcoite-lodranite parent body. The present investigations demonstrate the complexity of the evolutionary stages of acapulcoites from accretion to parent body processes.  相似文献   

Two-dimensional modeling of contaminant transport in porous media in the presence of colloids   总被引：3，自引：0，他引：3  

Hesham M. Bekhit  Ahmed E. Hassan   《Advances in water resources》2005,28(12):1320-1335

It has long been known that colloids can facilitate the transport of contaminants in groundwater systems by reducing the effective retardation factor. A significant effort has been devoted to study colloid-facilitated contaminant transport during the past decade. Many of the previous studies were restricted to one-dimensional analyses and comparisons with finite-column experiments. In this work, a two-dimensional numerical model is developed and used to study the different interactions between colloids, contaminants, and porous media under homogeneous conditions. The numerical formulation of the model is based on discretizing mass balance equations and reaction equations using finite differences having a third-order, total variance-diminishing scheme for the advection terms. This scheme significantly reduces numerical dispersion and leads to greater accuracy compared to the standard central-differencing scheme. The model is tested against analytical solutions under simplified conditions as well as against experimental data, and the results are favorable. The model is used to investigate the impact of the various reaction rates and parameter values on the movement of contaminant plumes in two dimensions. The model is also used to investigate the hypothesis that colloids may increase the effective retardation factor of contaminant plumes. The analysis shows that assuming kinetic mass exchange between contaminant and colloids with constant reaction rate coefficients that are not related to the concentrations may lead to inaccurate results. These inaccurate results are exemplified in the finding that under the kinetic assumption the ratio of the initial concentration of colloids to the initial concentration of contaminant does not affect the amount of facilitation or retardation that occurs in the system. It is also found that colloids can increase the effective retardation factor for the contaminant under certain combinations of reaction rates and distribution coefficients. A quantitative empirical expression to identify whether colloids retard or facilitate the contaminant movement is presented.  相似文献   

High pressure deformation in two-phase aggregates   总被引：1，自引：0，他引：1  

Li Li  Ahmed Addad  Donald Weidner  Hongbo Long  Jiuhua Chen 《Tectonophysics》2007,439(1-4):107-117

We investigate the rheological behavior of multi-phase aggregates at high pressure and high temperature. Using synchrotron X-ray radiation as the probing tool, we are able to quantify the stress state of individual phases within the aggregates. This method provides fundamental information in interpreting the behavior of two phase/multi-phase mixtures, which contribute to our understanding of the deformation process at deep earth conditions. We choose MgAl₂O₄ spinel and MgO periclase as our model materials. Mixtures of various volume proportions were deformed in a multi-anvil high pressure deformation apparatus at pressure of 5 GPa and elevated temperatures. Stress is determined from X-ray diffraction, providing a measure of stress in each individual phase of the mixture in situ during the deformation. Macroscopic strain is determined from X-ray imaging. We compare the steady state strength of various mixtures at 1000 °C and 800 °C and at the strain rate in the range of 1.8 to 8.8 × 10^− 5 s^− 1. Our data indicate that the weak phase (MgO) is responsible for most of the accumulated strains while the strong phase (spinel) is supporting most of the stress when the volume proportion is 75% spinel and 25% MgO. The intermediate compositions (40/60) are much weaker than either of the end members, while the grain sizes for the intermediate compositions (submicrons) are much smaller than the end members (5–10 μm). We conclude that a change in flow mechanism resulting from these smaller grains is responsible for the low strength of the intermediate composition mixtures. This study demonstrates an approach of using synchrotron X-rays to study the deformation behaviors of multi-phase aggregates at high pressure and high temperature.  相似文献   

Integrated studies for characterization of lineaments used to locate groundwater potential zones in a hard rock region of Karnataka, India     

Subash Chandra  V. A. Rao  N. S. Krishnamurthy  S. Dutta  Shakeel Ahmed 《Hydrogeology Journal》2006,14(5):767-776

An integrated study was carried out to investigate the subsurface geological conditions in a hard rock environment, with the aim of identifying zones with groundwater resource potential. The study, in Bairasagara watershed, Karnataka, India, considered geomorphology, water level, resistivity imaging, self potential, total magnetic field and susceptibility. The signatures due to lineaments have been clearly identified and their role in groundwater movement has been documented. Synthetic simulation methods were used to model the electrical response of the lineament using finite differential modeling scheme. The inverted image of the field data is compared with the synthetic image and iteration were performed on the initial model until a best match was obtained resulting on the generation of the calibrated resistivity image of the subsurface. Resistivity imaging revealed that the dykes are weathered/fractured to a depth of 6–8 m and are compact at deeper levels, and that they behave as barriers to groundwater movement, yet facilitate a good groundwater potential zone on the upgradient side. The results of magnetic surveys were utilized in differentiating granites and dolerite dykes with an insignificant resistivity contrast. Geomorphological expression alone cannot reveal the groundwater potential associated with a lineament. However, characterizing the nature of the feature at depth with integrated geophysical methods provides essential information for assessing that potential.An erratum to this article can be found at  相似文献   

Association of hydrogeological factors in temporal variations of fluoride concentration in a crystalline aquifer in India   总被引：6，自引：0，他引：6  

P. D. Sreedevi  S. Ahmed  B. Made  E. Ledoux  J. M. Gandolfi 《Environmental Geology》2006,50(1):1-11

The major part of groundwater in India is found in granitic aquifers. Fluoride in groundwater from a crystalline aquifer in a semi-arid region of granitic rocks in India, known as Maheshwaram watershed, was analyzed for spatial and temporal variability during 1999–2002 to assess the effect of hydrogeological factors on fluoride concentration. Samples were collected from 32 representative wells in the area for the pre- and post-monsoon seasons and analyzed for F content. The CHESS computer program was used to calculate ionic activities of aqueous species and the mineral saturation index (SI) for calcite and fluorite. The GARDENIA computer program was used to calculate the recharge values in the study area. The influences of dissolution kinetics of fluoride minerals and recharge from rainfall on fluoride concentration were of interest and results clearly indicate that fluoride content in groundwater depends on the interaction period of groundwater with host rock. Results could also be utilized for designing remedial measures particularly with dilution method in an optimal way.  相似文献   

Formation and mineral chemistry of a calcic skarn from Al-Madhiq, SW Saudi Arabia   总被引：2，自引：0，他引：2  

Zulfiqar Ahmed  Mustafa M. Hariri 《Chemie der Erde / Geochemistry》2006,66(3):187-201

A newly identified skarn occurrence is described from the Neoproterozoic rocks of the SW Arabian shield. It is exposed to the SE, E and NE of the Al-Madhiq town. The skarn attributes correspond to those typical of the calcic skarns that host W-deposits. It is characterized as an exoskarn of the proximal type, related to a granitoid contact close to an impure quartzite bed within the regional metamorphic rocks of mixed sedimentary and volcanic derivation. The skarn is localized along a shear zone parallel to the regional faults and other major shear zones. Samples from the studied area contain characteristic skarn minerals that include both the prograde (brownish red grossular, ferrosalite, aluminian titanite-grothite, albite-oligoclase, scapolite), and retrograde (epidote, quartz, hornblende, calcite) assemblages. The pyroxenes are ferrosalites, Mn-bearing, and more like those from “oxidized” skarns; although garnets indicate it to be a “reduced” type skarn. Epidote mimicks that from typical skarns, as it bears a pistacite content of 15.9–20.7%. Grossular composition reflects a largely reduced genetic environment; as it is in solid solution with 6.5–21.6% andradite, 0–0.15% uvarovite, 0–0.47% pyrope, 4.33–18.75% almandine, and 0.4–8.58% spessartine molecules. Titanite composition varies from aluminian titanite to grothite, that may be analogous to the newly described Al-rich titanite from the low-pressure calc-silicate rocks.  相似文献   

Soil Characterization Using Joint Interpretation of Remote Sensing,Resistivity and Induced Polarization Data along the Coast of the Nile Delta     

Attwa  Mohamed  El Mahmoudi  Ahmed  Elshennawey  Ahmed  Günther  Thomas  Altahrany  Ayman  Mohamed  Lamees 《Natural Resources Research》2021,30(5):3407-3428

Natural Resources Research - Soil characterization in coastal areas is essential for strategic coastal engineering implementation and for understanding the paleo-environmental conditions. However,...  相似文献   

Data-Driven Modeling Approach to Predict the Recovery Performance of Low-Salinity Waterfloods     

Kalam  Shams  Khan  Rizwan Ahmed  Khan  Shahnawaz  Faizan  Muhammad  Amin  Muhammad  Ajaib  Rameez  Abu-Khamsin  Sidqi A. 《Natural Resources Research》2021,30(2):1697-1717

Natural Resources Research - Low-salinity waterflooding (LSWF) has, in the past decade, attained a lot of attention to enhance oil recovery. In LSWF, diluted water is injected into an oil reservoir...  相似文献