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Polarized Fourier-transform infrared and Raman spectra were acquired on an elbaite sample previously characterized by electron- and ion microprobe analysis, X-ray diffraction and structure refinement. Spectra from the two vibrational spectroscopy techniques reveal a close similarity in the OH-stretching region, with three main absorption bands strongly polarized in the c-axis direction. By means of bond-valence theory arguments, the observed OH bands are interpreted and assigned to specific local cation arrangements around the O1 (≡W) and O3 (≡V) anion sites. In combination with the relatively simple composition of the studied sample, bond-valence constraints are used to identify stable anion-cation arrangements, which permit the occurrence of short-range ordering to be assessed. Evidence for nearly complete short-range order at the O1 site, with the stable arrangements Y(LiAlAl)0.6–W(OH)0.6 and Y(LiLiAl)0.4–W(F)0.4, are presented. These two local arrangements can be further expanded to obtain the larger ordered clusters [W(OH)–Y(LiAl2)–V(OH)3–Z(Al)6]0.6 and [W(F)–Y(Li2Al)–V(OH)3–Z(Al)6]0.4. 相似文献
33.
This paper presents an example of the application of error monitoring techniques to the results of a pseudodynamic test performed at variable testing speeds. For the faster testing speeds, the control errors increased and the test reliability was lost in terms of accuracy and stability, as observed by the evolution of the monitoring parameters. The applied monitoring methods were the spatial model identification of frequency and damping distortions and the error energy, which have been proposed in previous publications. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
34.
Ferdinando Patat Giovanni Carraro 《Monthly notices of the Royal Astronomical Society》2001,325(4):1591-1602
We report on the first UBVRI CCD photometry of three poorly known star clusterings in the region of η Carinae: Bochum 9, 10 and 11. We find that they are young, rather poor, loose open clusters.
We argue that Bochum 9 is probably a small and loose open cluster with about 30 probable members having E ( B − V )=0.63±0.08 , located 4.6 kpc far from the Sun, beyond the Carina spiral arm.
Similarly, Bochum 10 is a sparse aggregate with 14 probable members having E ( B − V )=0.47±0.05 and at a distance of 2.7 kpc from the Sun.
Finally, Bochum 11 is a less than 4×106 yr old cluster for which we identify 24 members. It has a reddening E ( B − V )=0.58±0.05 , and lies between Bochum 10 and 9, at 3.5 kpc from the Sun. We propose that in the field of the cluster some stars might be pre-main-sequence candidates. 相似文献
We argue that Bochum 9 is probably a small and loose open cluster with about 30 probable members having E ( B − V )=0.63±0.08 , located 4.6 kpc far from the Sun, beyond the Carina spiral arm.
Similarly, Bochum 10 is a sparse aggregate with 14 probable members having E ( B − V )=0.47±0.05 and at a distance of 2.7 kpc from the Sun.
Finally, Bochum 11 is a less than 4×10
35.
Marine Protected Areas in the Mediterranean Sea: Objectives, Effectiveness and Monitoring 总被引：1，自引：0，他引：1
Simonetta Fraschetti Antonio Terlizzi Fiorenza Micheli Lisandro Benedetti-Cecchi Ferdinando Boero 《Marine Ecology》2002,23(S1):190-200
Abstract. The number of Marine Protected Areas (MPAs) is continuously increasing worldwide because of the increasing recognition of the profound effects that humans can have on marine systems. A large body of literature deals with marine reserves and their potential as conservation and management tools. In several cases, empirical evidence demonstrated that reserves can harbour greater diversity, higher abundance, and larger organisms than unprotected areas. In most cases, however, reserve design and site selection involved little scientific justification, with no direct test of most of the mechanisms assumed to work in a marine reserve. Field investigations of subtidal marine reserves are generally confounded by intrinsic ecological differences between sites investigated inside and outside reserves, by a lack of site and reserve replication, or by the absence of information about the biota before reserve establishment. This is particularly true in the Mediterranean Sea. The aim of this paper is to show that, at least in the Mediterranean basin, the effectiveness of MPAs has been rarely demonstrated because of lack of appropriate sampling designs. An MPA can be considered as a zone subjected to human impact, presumably a positive one. As a consequence, we propose the use of experimental procedures generally utilised for detecting environmental impacts. 相似文献
36.
Plankton-Derived Resting Stages in Marine Coastal Sediments along the Salento Peninsula (Apulia, South-Eastern Italy) 总被引：1，自引：0，他引：1
Fernando Rubino Salvatore Moscatello Orestina D. Saracino Giovanni Fanelli Genuario Belmonte Ferdinando Boero 《Marine Ecology》2002,23(S1):329-339
Abstract. An oceanographic survey was carried out along the Salento Peninsula in March 2000. Resting stages of plankton were searched for in coastal sediments to study the microplankton composition in addition to the classical analysis of active stages in the water column. A total of 215 taxa were recognised, 149 as active stages in the water column and 74 as resting stages in the sediments. Cysts were widely distributed and at Brindisi and Alimini their abundance was higher than elsewhere. A general trend was observed with resting stage abundance, species richness and diversity in the sediments: all three decreased with distance from the coast. The integrated water/sediments approach used in this study allowed us to collect 37 species (mainly as resting stages) new for the studied area. 相似文献
37.
Abstract. The ecology and systematics of the hydroid population of Posidonia oceanica meadows have been studied in two different zones of the Western Mediterranean. A new sampling method has been employed and the results obtained have been compared with those of a standard method. The distribution of the species and several morphological variations are pointed out. Depth-related faunistic zones are evidenced. The key-species of the Posidonia hydroid population arc individuated. 相似文献
38.
Francesca Barnaba Ferdinando De Tomasi Gian Paolo Gobbi Maria Rita Perrone Anna Tafuro 《Atmospheric Research》2004,70(3-4):229-259
Functional relationships linking at λ0=351 nm aerosol extinction αλ0aer and backscatter coefficient βλ0aer of maritime and desert type aerosols are determined to allow for inversion of the single-wavelength lidar signals. Such relationships are derived as mean behavior of 20,000 extinction versus backscatter computations, performed for aerosol size distributions and compositions whose describing parameters are randomly chosen within the naturally observed variability. For desert-type aerosols, the effect of the particle non-sphericity is considered and it is shown that the extinction to backscatter ratio of non-spherical dust particles can be up to 60% larger than the values obtained for spherical particles. Aerosol extinction and backscatter coefficient profiles obtained inverting the single-wavelength lidar signal with the modeled relationships are then compared to the same profiles measured by a combined elastic-Raman lidar operating at 351 nm. Analytical back trajectories and satellite images are used to characterize advection patterns during lidar measurements and to properly choose the modeled functional relationship. A good accordance between the two techniques is found for advection patterns over the lidar site typical of maritime and dust conditions. Maximum differences between the model-based αλ0aer and βλ0aer vertical profiles and the corresponding ones measured by the combined elastic-Raman lidar technique are of 30% and 40% in maritime and desert dust conditions, respectively. The comparison of elastic-Raman lidar measurements and model-based results also reveals that particle non-sphericity must be taken into account when mineral dust-type aerosols are directly advected over the measurement site. 相似文献
39.
The stabilisation of deep landslides is still a challenge for geotechnical engineers, mainly due to the high cost of structural control works that generally lead engineers to opt for drain systems. Unfortunately there are operative difficulties affecting excavation of deep drain trenches in soils dislocated by landslides (especially as regards the provisional support of the excavation walls). Small- and medium-diameter wells are a valid alternative in deep landslides, being less expensive than large-diameter wells equipped with horizontal pipes and simpler to construct than deep trenches. However, no technical procedures for their proper design are reported in the literature: design criteria commonly used in practice are derived from pumping problems and are largely inadequate, being based on Dupuit’s hypothesis that presumes stream lines to be horizontal. This paper presents numerical solutions obtained from three-dimensional seepage and consolidation analyses of a slope drained by small- and medium-diameter wells, arranged according to various positions, showing that the efficiency of the well system decreases as the depth of the landslide slip surface increases. Comparison is also made between well systems and deep trenches occupying the same draining volume in the landslide body, showing that the former attains much greater efficiency than the latter. Non-dimensional abaci for the square grid of wells (which is the most effective arrangement) are reported herein to be used for practical purposes.
相似文献40.
Julia Bosiö Christian Stiegler Margareta Johansson Herbert N. Mbufong Torben R. Christensen 《Climatic change》2014,127(2):321-334
This study was initiated to analyze the effect of increased snow cover on plant photosynthesis in subarctic mires underlain by permafrost. Snow fences were used to increase the accumulation of snow on a subarctic permafrost mire in northern Sweden. By measuring reflected photosynthetic active radiation (PAR) the effect of snow thickness and associated delay of the start of the growing season was assessed in terms of absorbed PAR and estimated gross primary production (GPP). Six plots experienced increased snow accumulation and six plots were untreated. Incoming and reflected PAR was logged hourly from August 2010 to October 2013. In 2010 PAR measurements were coupled with flux chamber measurements to assess GPP and light use efficiency of the plots. The increased snow thickness prolonged the duration of the snow cover in spring. The delay of the growing season start in the treated plots was 18 days in 2011, 3 days in 2012 and 22 days in 2013. Results show higher PAR absorption, together with almost 35 % higher light use efficiency, in treated plots compared to untreated plots. Estimations of GPP suggest that the loss in early season photosynthesis, due to the shortening of the growing season in the treatment plots, is well compensated for by the increased absorption of PAR and higher light use efficiency throughout the whole growing seasons. This compensation is likely to be explained by increased soil moisture and nutrients together with a shift in vegetation composition associated with the accelerated permafrost thaw in the treatment plots. 相似文献