Alteration patterns of chromian spinels from La Cabaña peridotite,south-central Chile     

Fernando Barra  Fernando Gervilla  Elkin Hernández  Martin Reich  José Alberto Padrón-Navarta  José Maria González-Jiménez 《Mineralogy and Petrology》2014,108(6):819-836

La Cabaña peridotite is part of a dismembered ophiolite complex located within the metamorphic basement of the Coastal Cordillera of south-central Chile, and is the only location in Chile were Cr-spinels have been described so far. The La Cabaña peridotite is part of the Western Series unit, which comprises meta-sedimentary rocks, metabasites, and serpentinized ultramafic rocks. This unit has been affected by greenschist-facies metamorphism with reported peak PT conditions of 7.0–9.3 kbar and 380°–420 °C. Within La Cabaña peridotite Cr-spinels are present in two localities: Lavanderos and Centinela Bajo. In Lavanderos, Cr-spinel occurs in small chromitite pods and as accessory/disseminated grains with a porous or spongy texture in serpentinite, whereas in Centinela Bajo Cr-spinel is present as accessory zoned grains in partly serpentinized dunites, and in chromitite blocks. All Cr-spinels display variable degrees of alteration to Fe²⁺-rich chromite with a variation trend of major elements from chromite to Fe²⁺-rich chromite similar to those observed in other locations, i.e., an increase in Fe₂O₃ and FeO, a decrease in Al₂O₃ and MgO. Cr₂O₃ content increases from chromite to Fe²⁺-rich chromite in chromitite pods from Lavanderos and chromitite blocks from Centinela Bajo, but decreases in ferrian chromite zones in accessory grains from Centinela Bajo. The minor element (Ti, V, Zn, Ni) content is mostly low and does not exceed 0.4 wt.%, with the exception of MnO (<0.9 wt.%), which shows a correspondence with increasing degree of alteration. Cr# (Cr/Cr?+?Al) versus Mg# (Mg/Mg?+?Fe²⁺) and Fe³⁺/Fe³⁺+Fe²⁺ versus Mg# plots are used to illustrate the Cr-spinel alteration process. Overall, the Cr-spinels from Lavanderos (chromitite pods and disseminated grains) exhibit Cr# values ranging from 0.6 to 1.0, Mg# (Mg/Mg?+?Fe²⁺) below 0.5, and (Fe³⁺/Fe³⁺+Fe²⁺) <0.4. Cr-spinels from chromitites in Centinela Bajo have Cr# and Mg# values that range from 0.65 to 1.0, and 0.7-0.3, respectively, and (Fe³⁺/Fe³⁺+Fe²⁺)?3+/Fe³⁺+Fe²⁺) ratio is less than 0.4 in chromite cores and Fe²⁺-rich chromite, and >0.5 in ferrian chromite and Cr-magnetite. Interpretation of the data obtained and Cr-spinel textures indicate that the alteration of Cr-spinel is a progressive process that involves in its initial stages the reaction of chromite with olivine under water-saturated conditions to produce clinochlore and Fe²⁺-rich chromite. During this stage the chromite can also incorporate Ni, Mn, and/or Zn from the serpentinization fluids. As alteration progresses, Fe²⁺-rich chromite loses mass resulting in the development of a spongy texture. In a later stage and under more oxidizing conditions Fe³⁺ is incorporated in chromite/Fe²⁺-rich chromite shifting its composition to an Fe³⁺-rich chromite (i.e., ferrian chromite). Depending on the fluid/rock and Cr-spinel/silicate ratios, Cr-magnetite can also form over Fe²⁺-rich chromite and/or ferrian chromite as a secondary overgrowth. The compositional changes observed in Cr-spinels from La Cabaña reflect the initial stages of alteration under serpentinization conditions. Results from this study show that the alteration of Cr-spinels is dependent on temperature. The degree and extent of alteration (formation of Fe²⁺-rich and/or ferrian chromite) are controlled by the redox nature of the fluids, the Cr-spinel/silicate and the fluid/rock ratios.  相似文献   

Detrital provenance of the Grenvillian Oaxacan Complex,southern Mexico: a zircon perspective     

Luigi A. Solari  Fernando Ortega-Gutiérrez  Mariano Elías-Herrera  Carlos Ortega-Obregón  Consuelo Macías-Romo  Margarita Reyes-Salas 《International Journal of Earth Sciences》2014,103(5):1301-1315

The Oaxacan Complex is the largest exposure of Grenvillian-age rocks in Mexico, constituting the backbone of the Oaxaquia microcontinent. Whereas the main rock-forming events were previously established at 1,150–1,200 Ma (charnockite–syenite–gabbros), 1,020 Ma (AMCG suite), 990 Ma (granulite-facies metamorphism), and ca. 970 Ma post-tectonic pegmatites, no data are yet available to establish provenance links with other Grenville-age terranes. In this work, we studied detrital zircons belonging to 12 samples, all metamorphosed under granulite facies but variably affected by retrogression. Laser ablation inductively coupled plasma mass spectrometry U–Pb geochronology was employed on selected zircons to determine their crystallization age and geochemistry. The results of the analysis of about 100 crystals per sample show that the studied zircons range between ca. 940 and 1,400 Ma, with only three samples having zircons between 1,400 and 1,600 Ma, and only one showing older zircons up to ca. 1,775 Ma. Whereas some of the slightly discordant (1–5 %) zircons in several samples show ages younger than the granulite metamorphism (probably as a result of Pb loss), and thus a disturbed geochemical pattern (abnormal enrichment in LREE, decreasing HREE), a few metamorphic zircons show flat and depleted HREE patterns, contrasting with the igneous pattern of older zircons (positive Ce anomaly, negative Eu anomaly, enriched HREE pattern). The main distributions observed using the kernel density estimator diagrams fall in the range 975–995 Ma (six samples), 1,100 Ma (four samples) and 1,120–1,170 Ma (six samples). Only the southernmost sample shows a marked peak at ca. 1,400 Ma. The application of the Kolmogorov–Smirnov (K–S) statistical test to the studied samples and particularly the comparison of obtained P values yield interesting similarities. Overall, two sample groups show internal similarities, i.e., they may belong to the same source area, whereas only one sample is dissimilar, failing to pass the K–S test. Comparison of these data with the timing of comparable events in the Sveconorwegian orogens, the Sunsas and Rondonia-San Ignacio belts of Amazonia, and some of the Precambrian massifs cropping out in the Andes help to constrain possible Mesoproterozoic conjugate margins of Oaxaquia.  相似文献   

High-resolution aquifer analog of fluvial–aeolian sediments of the Guarani aquifer system     

Dominik Höyng  Fernando Mazo D’Affonseca  Peter Bayer  Edson Gomes de Oliveira  José Alexandre J. Perinotto  Fábio Reis  Holger Weiß  Peter Grathwohl 《Environmental Earth Sciences》2014,71(7):3081-3094

The Guarani aquifer system (GAS) represents one of the biggest aquifers in the world and is the most relevant groundwater resource in South America. For the first time, by combining field and laboratory measurements, a high-resolution aquifer analog model of fluvial–aeolian sediments of the GAS in São Paulo State (Brazil) is constructed. Three parallel sections of frontal outcrops, 28 m × 5.8 m, and two parallel sections of lateral outcrops, 7 m × 5.8 m, are recorded during open-pit mining of sandy sediments and describe in detail the three-dimensional distribution of the local lithofacies and hydrofacies. Variations of hydraulic conductivity, K, and porosity, n, are resolved on the centimeter scale, and the most permeable units of the fluvial–aeolian facies association are identified. The constructed aquifer analog model shows moderate hydraulic heterogeneity and a mean K value of 1.36 × 10^?4 m/s, which is greater than the reported range of K values for the entire GAS in São Paulo State. The results suggest that the examined sedimentary unit constitutes a relevant portion of the GAS in São Paulo State in the context of groundwater extraction and pollution. Moreover, the constructed aquifer analog is considered an ideal basis for future numerical model experiments, aiming at in-depth understanding of the groundwater flow and contaminant transport patterns at this GAS portion or at comparable fluvial–aeolian facies associations.  相似文献   

CONSTAnT – A Conceptual Data Model for Semantic Trajectories of Moving Objects     

Vania Bogorny  Chiara Renso  Artur Ribeiro de Aquino  Fernando de Lucca Siqueira  Luis Otavio Alvares 《Transactions in GIS》2014,18(1):66-88

Several works have been proposed in the last few years for raw trajectory data analysis, and some attempts have been made to define trajectories from a more semantic point of view. Semantic trajectory data analysis has received significant attention recently, but the formal definition of semantic trajectory, the set of aspects that should be considered to semantically enrich trajectories and a conceptual data model integrating these aspects from a broad sense is still missing. This article presents a semantic trajectory conceptual data model named CONSTAnT, which defines the most important aspects of semantic trajectories. We believe that this model will be the foundation for the design of semantic trajectory databases, where several aspects that make a trajectory “semantic” are taken into account. The proposed model includes the concepts of semantic subtrajectory, semantic points, geographical places, events, goals, environment and behavior, to create a general concept of semantic trajectory. The proposed model is the result of several years of work by the authors in an effort to add more semantics to raw trajectory data for real applications. Two application examples and different queries show the flexibility of the model for different domains.  相似文献   

Satellite de-orbiting via controlled solar radiation pressure     

Rogerio Deienno  Diogo Merguizo Sanchez  Antonio Fernando Bertachini de Almeida Prado  Georgi Smirnov 《Celestial Mechanics and Dynamical Astronomy》2016,124(4):433-456

We analyze the families of central configurations of the spatial 5-body problem with four masses equal to 1 when the fifth mass m varies from 0 to \(+\infty \). In particular we continue numerically, taking m as a parameter, the central configurations (which all are symmetric) of the restricted spatial (\(4+1\))-body problem with four equal masses and \(m=0\) to the spatial 5-body problem with equal masses (i.e. \(m=1\)), and viceversa we continue the symmetric central configurations of the spatial 5-body problem with five equal masses to the restricted (\(4+1\))-body problem with four equal masses. Additionally we continue numerically the symmetric central configurations of the spatial 5-body problem with four equal masses starting with \(m=1\) and ending in \(m=+\infty \), improving the results of Alvarez-Ramírez et al. (Discrete Contin Dyn Syst Ser S 1: 505–518, 2008). We find four bifurcation values of m where the number of central configuration changes. We note that the central configurations of all continued families varying m from 0 to \(+\infty \) are symmetric.  相似文献   

Confounding response of macrofauna from a confluence of impacts: brine and sewage pollution     

Rodrigo Rier  Fernando Tuy  Myriam Rodr&#;guez  &#;scar Monterroso  Eva Ramos 《海洋学报(英文版)》2013,32(10):74-81

Throughout the shores of the world,a confluence of different sources of pollution is common,e.g.,through outlets releasing brine,industrial,and domestic sewage.In this study,we assessed whether a combined disposal of domestic sewage and brine altered the patterns of abundance and assemblage structure of subtidal macrofauna inhabiting sandy seabeds on the south coast of Gran Canaria(Canary Islands,NE Atlantic Ocean).Samples were collected in two surveys(May 2008 and January 2009)at three distances(0,15,and30 m)away from the discharge point.Macrofaunal abundances showed different patterns with varying proximity from the disposal point in the two surveys.In May 2008,lower abundances were observed at0 m(53.89±46.82 ind.)than at 15 m(120±91.7 ind.)and 30 m(283.89±189.33 ind.)away from the disposal point.In January 2009,however,higher abundances were observed at 0 m(131.33±58.69 ind.)than at 30 m(100±24.44 ind.)and 15 m(84.78±58.39 ind.)away from the disposal point.Significant differences in macrofaunal assemblage structure were found with varying proximity from the discharge point in both surveys.The effect of proximity from the disposal point was confounded by changes in sedimentary composition between surveys,which contributed to explain differences in macrofaunal abundances and assemblage structure with varying proximity from the discharge point.As a result,confounding drivers of macrofaunal assemblage structure,here,changes in sediment composition,accounted for changes in macrofaunal abundances and assemblage structure with varying proximity from a combined disposal point of brine and sewage.  相似文献   

The lunar gravity mission MAGIA: preliminary design and performances     

Marco?Fermi  Marco?Gregnanin  Marco?MazzolenaEmail author  Massimiliano?Chersich  Mirko?Reguzzoni  Fernando?Sansò 《Experimental Astronomy》2011,32(1):1-18

The importance of an accurate model of the Moon gravity field has been assessed for future navigation missions orbiting and/or landing on the Moon, in order to use our natural satellite as an intermediate base for next solar system observations and exploration as well as for lunar resources mapping and exploitation. One of the main scientific goals of MAGIA mission, whose Phase A study has been recently funded by the Italian Space Agency (ASI), is the mapping of lunar gravitational anomalies, and in particular those on the hidden side of the Moon, with an accuracy of 1 mGal RMS at lunar surface in the global solution of the gravitational field up to degree and order 80. MAGIA gravimetric experiment is performed into two phases: the first one, along which the main satellite shall perform remote sensing of the Moon surface, foresees the use of Precise Orbit Determination (POD) data available from ground tracking of the main satellite for the determination of the long wavelength components of gravitational field. Improvement in the accuracy of POD results are expected by the use of ISA, the Italian accelerometer on board the main satellite. Additional gravitational data from recent missions, like Kaguya/Selene, could be used in order to enhance the accuracy of such results. In the second phase the medium/short wavelength components of gravitational field shall be obtained through a low-to-low (GRACE-like) Satellite-to-Satellite Tracking (SST) experiment. POD data shall be acquired during the whole mission duration, while the SST data shall be available after the remote sensing phase, when the sub-satellite shall be released from the main one and both satellites shall be left in a free-fall dynamics in the gravity field of the Moon. SST range-rate data between the two satellites shall be measured through an inter-satellite link with accuracy compliant with current state of art space qualified technology. SST processing and gravitational anomalies retrieval shall benefit from a second ISA accelerometer on the sub-satellite in order to decouple lunar gravitational signal from other accelerations. Experiment performance analysis shows that the stated scientific requirements can be achieved with a low mass and low cost sub-satellite, with a SST gravimetric mission of just few months.  相似文献   

Alteration of Platinum-Group and Base-Metal Mineral Assemblages in Ophiolite Chromitites from the Dobromirtsi Massif,Rhodope Mountains (Bulgaria)     

José María González-Jiménez  Fernando Gervilla  Thomas Kerestedjian  Joaquín Antonio Proenza 《Resource Geology》2010,60(4):315-334

The Dobromirtsi Ultramafic Massif, located in the Rhodope Mountains (SE Bulgaria), is a portion of a Paleozoic sub-oceanic mantle affected by polyphase regional metamorphism. This massif contains several small, podiform chromitite bodies which underwent the same metamorphic evolution as their host peridotites. Like other ophiolite chromitites, those found in Dobromirtsi carry abundant platinum-group minerals (PGM) and base-metal minerals (BMM). The PGM consist mainly of Ru-, Os-, and Ir-based PGM (laurite RuS₂-erlichmanite OsS₂, Os-Ru-Ir alloys, irarsite [IrAsS], Ru-rich pentlandite, and an unknown Ir-sulfide) but minor Rh- and Pd-based PGM (hollingworthite [RhAsS] and a series of unidentified stannides and sulfantimonides) are also present. In contrast, the BMM are dominated by pentlandite (Ni,Fe)₉S₈, followed by heazlewoodite (Ni₃S₂), breithauptite (NiSb), maucherite (Ni₁₁As₈), godlevskite (Ni₇S₆), gersdorffite (NiAsS), millerite (NiS), undetermined minerals containing Ni, As and Sb, orcelite (Ni_5-XAs₂), awaruite (Ni₃Fe) and chalcopyrite (CuFeS₂). The detailed study of the textural relationships, morphology and composition of the PGM and BMM inclusions indicate the existence of two different PGM-BMM assemblages: (i) a primary or magmatic; and (ii) a secondary related with postmagmatic alteration. The PGM and BMM inclusions in unaltered zones of chromite crystals (mainly laurite-erlichmanite and pentlandite) are considered to be primary magmatic minerals formed under variable temperature (1200–1100°C) and sulfur fugacity (between −2 and −0.5 log fS₂). In contrast, PGM and BMM located along altered edges of chromite and serpentinised silicate matrix are considered to be secondary, formed from or re-equilibrated with altering fluids. Secondary PGM and BMM assemblages are considered as result of the combination of reducing and oxidising events related with regional metamorphism. Under low fO₂ states, fS₂ also drops giving place to the formation of S-poor Ni-rich sulfides and secondary Ru-alloys by desulfurisation of primary S-containing minerals. In contrast, predominance of platinum-group elements and/or base-metal arsenides and sulfarsenides associated with the altered edges of chromite (chromite strongly enriched in Fe₂O₃) is related with the fixing of remobilised PGE (mainly Ir, Rh and Pd) and base-metals (mainly Ni and Fe) when late oxidising fluids supplied As as well as Sb and Sn.  相似文献   

Clay minerals in sediments of Portuguese reservoirs and their significance as weathering products from over-eroded soils: a comparative study of the Maranhão, Monte Novo and Divor Reservoirs (South Portugal)     

Rita M. F. Fonseca  Fernando J. A. S. Barriga  Patrícia I. S. T. Conceição 《International Journal of Earth Sciences》2010,99(8):1899-1916

The Southern region of Portugal is subjected to several forms of over-erosion. Most leached products, mainly composed of fine particles containing nutrients, metals or pesticides, are easily transported by river flows. When these are hindered by a physical barrier such as a dam, the particulate load accumulates on the bottom of the reservoirs, often leading to a pronounced decrease of water quality. Bottom sediments from three reservoirs were subjected to grain-size analysis and a study of clay minerals by X-ray diffraction. Most sediments contain a diverse set of clay minerals, mostly illites, smectites, chlorites and kaolinites. The nature of the clay minerals reflects the nature of the parent rocks. During the cycles of transport and temporary deposition, they may undergo significant chemical and physical transformations, which lead to an increase of expandable properties and therefore, to a higher cationic exchange capacity, determining its important role as vehicles of environmental pollutants.  相似文献   

Late pleistocene/early holocene environments and climates,fauna, and human occupation in the argentine altiplano     

Jorge Fernndez  Vera Markgraf  Hctor O. Panarello  Miguel Albero  Fernando E. Angiolini  Susana Valencio  Mirta Arriaga 《Geoarchaeology》1991,6(3):251-272

The Barro Negro site (23°S lat., 65°37′W long.) in the Altiplano (Puna) of northwestern Argentina contains a well stratified sequence of remains of Hippidion, the American extinct horse, camelids, and archaeological materials, which is the focus of this study. In addition to establishing a reliable chronology, paleoenvironmental information was obtained based on analyses of pollen and stable isotopes (oxygen and carbon) from bone and marl. The data indicate that Hippidion was present at the site between 12,000 and 10,000 yr B. P., at a time when Altoandean grasslands had expanded to lower elevations. By 10,000 yr B.P., when modern semi-arid sub-puna scrub had replaced the Altoandean grasslands, only camelids (Lama or Vicugna) were present, simultaneous with the first evidence of local human occupation. This suggests that a climatic shift from cool and moist (winter rain regime) to warm and dry (summer rain regime) conditions took place simultaneously with the disappearance of the American horse and the appearance of camelids and man.  相似文献