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The effect of intragranular diffusion on chemical zoning in garnet and on P-T paths calculated from that zoning was evaluated using a numerical model of multicomponent diffusion in combination with simulations of garnet growth. Syn-and post-growth diffusion of Mg–Fe–Mn–Ca species in garnet was calculated for a model pelitic assemblage over a range of temperatures from 485 to 635°C. Compositions from zoned garnet, as modified by diffusion, hypothetical inclusions of plagioclase within garnet and matrix phases were used to reconstruct pressure-temperature (P-T) paths from isobaric and polybaric model histories. P-T path calculations, based on numerical simulations conducted over an input isobaric heating path that reached peak temperatures between 585 and 635°C, show that relaxation of garnet compositional gradients by diffusion can induce modest to appreciable curvature in the inferred paths. Retrieved paths also indicated somewhat smaller overall temperature changes relative to the actual temperature difference of the input path. The magnitude of these distortions is shown to depend upon the heating and cooling rate and garnet crystal size as well as the actual peak temperature condition. The effect of diffusion on path trajectories in simulations with thermal histories that also included cooling were comparable to heating-only models that reached peak temperatures approximately 15–30°C higher. Compositions of garnets with radii less than 1 mm, that reached actual peak temperatures of 605°C along temperature-time histories characteristic of regional metamorphism, experienced sufficient diffusional relaxation to introduce errors of hundreds of bars to in excess of one kilobar in path trajectories. Path distortions were significant at heating/cooling rates less than 10°C/Ma, but rapidly diminished for rates faster than this. In polybaric simulations diffusion effects were least noticeable when the actual pressure-temperature conditions changed in a clockwise sense (i.e., convex to higher P and higher T), but apprecciable modification was seen in path models that underwent counterclockwise changes in P and T. Reequilibration of garnet rim compositions occurred during cooling on all paths, and temperature maxima obtained from garnet-biotite geothermometry underestimated actual peak conditions by 40 to 70°C. Calculations suggest that P-T path trajectories calculated from garnets of at least 1 mm size, and that experienced actual thermal maxima below 585°C, are not likely to be distorted by diffusional effects during regional metamorphism. However, P-T path reconstructions based on garnet zonation with smaller grains or higher temperatures may lead to misinterpretation of crystallization history. The partitioning record of peak metamorphic temperatures may be destroyed by diffusional reequilibration of garnet rim compositions during cooling, seriously complicating the task of quantitatively estimating diffusion effects on path calculations.  相似文献   
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Radiocarbon dates indicate a Farmdalian through Woodfordian age for fossil white spruce (Picea glauca) in the Tunica Hills, a greater time span than previously documented. These dates, furthermore, require revision of the ages of fluvial terrace deposits in the region. Spruce-bearing Terrace 1 sediments, previously regarded as late Woodfordian to Holocene age, are of Farmdalian to late Holocene age. Terrace 2 sediments, previously assigned a Sangamonian or Farmdalian age, are of probable Altonian age. Plant fossils in Terrace 1 sediments represent two climatically and temporally distinct assemblages: a cool-temperate, Farmdalian-Woodfordian assemblage dominated by white spruce but including deciduous hardwoods suggestive of an oak-hickory association; and a warm-temperate Holocene assemblage composed of southern hardwoods and nonarboreal species representative of the modern flora of the Tunica Hills. Locally, fossils of white spruce have been reworked into younger Terrace 1 sediments containing the warm-temperate plant assemblage. The transition from the cool-temperate flora to the modern warm-temperate flora in the Tunica Hills probably occurred around 12,000 yr B.P.  相似文献   
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This study examines the spatial distribution and impact of nonroutine accidental releases of hazardous materials relative to the demographic composition of residents in nearby communities. First, atmospheric dispersion modeling methods are used to delineate the impact zones of worst‐case accidents in two New York counties over the last ten years. Next, using accidental reports for 1997, GIS and statistical operations are used at the census tract level of the two counties to determine whether these incidents disproportionately affected disadvantaged neighborhoods. The results suggest that the areas of high‐impact from accidental releases of hazardous materials are best characterized by a large proportion of families below the poverty line, Hispanics, and other minorities.  相似文献   
16.
Our current lack of understanding of the partitioning behavior of Sc, Y and the REE (rare-earth elements) can be attributed directly to the lack of a sufficiently large or chemically diverse experimental data set. To address this problem, we conducted a series of experiments using several different natural composition lavas, doped with the elements of interest, as starting compositions. Microprobe analyses of orthopyroxene, pigeonite, olivine, magnetite, ilmenite and co-existing glasses in the experimental charges were used to calculate expressions that describe REE partitioning as a function of a variety of system parameters. Using expressions that represent mineral-melt reactions (versus element ratio distribution coefficients) it is possible to calculate terms that express low-Ca pyroxene-melt partitioning behavior and are independent of both pyroxene and melt composition. Compositional variations suggest that Sc substitution in olivine involves either a paired substitution with Al or, more commonly, with vacancies. The partitioning of Sc is dependent both on melt composition and temperature. Our experimentally determined olivine-melt REE Ds (partition coefficients) are similar to, but slightly higher than those reported by McKay (1986) and support their conclusions that olivines are strongly LREE depleted. Y and REE mineral/melt partition coefficients for magnetite range from 0.003 for La to 0.02 for Lu. Ilmenite partition coefficients range from 0.007 for La to 0.029 for Lu. These experimental values are two orders of magnitude lower than many of the published values determined by phenocryst/matrix separation techniques.  相似文献   
17.
An ESR experimental study of artificial optical bleaching of sedimentary quartz has shown that the aluminum center was maximally bleached after a 6-month illumination equivalent to natural light. This duration seems too long to apply in natural conditions. Nevertheless, the measurement of the ESR intensity of aluminum centers in quartz extracted from modern sediments and deposited in sandy bars shows that the maximum bleaching has effectively been reached.

In order to determine the relationship between the bleaching and the distance covered by a quartz grain in a river, samples were collected along the Creuse River (France) from its spring to about 170 km downstream, where maximum bleaching levels were observed in previous studies. The ESR intensities of the aluminum and titanium centers in quartz were measured, using X-band spectroscopy, before and after artificial bleaching. The difference measured between these sub-samples shows that the maximum bleaching level is obtained in the course of the first kilometer. Hence, the assumption that ESR dating of fluvial sediment is based on the optical bleaching was validated.  相似文献   

18.
A dense array experiment for the observation of waveform perturbations   总被引:1,自引:0,他引:1  
We analyze observed three-component seismograms recorded by a dense array of 21 short-period receivers (f>2 Hz) installed on a homogeneous Quaternary plain with 1.5×3.5 km2 horizontal dimensions. The experiment was conducted in the district of Caille, in SE France for 3 months. The observed waveform data are related to diffraction and refraction of the direct wavefield by different geological structures and topographic morphologies surrounding the array. The origin of the coda energy following the energetic Pg or Sg arrivals is either influenced by heterogeneities close to and inside of the valley, for instance thrust of Jurassic limestones over Cretaceous marls in the northern and southern limits of the valley, or by heterogeneities located outside of the valley such as the interface unconformity between crystalline basement and sedimentary cover in the northern border of the Maures–Tanneron ranges. The main energetic arrivals of the seismograms arrive at the array with a definite range of azimuths that is not correlated with the event back-azimuth. Moreover, these arrivals do not appear with azimuths related to the characteristic NS and EW valley orientations, and thus may be related to heterogeneities located outside of the valley.  相似文献   
19.
Dunite samples have been deformed non-coaxially at high temperatures and pressures. In samples which were deformed by translation glide on {Okl}[100], olivine [100] = Z-axes rotated toward the maximum extensile-strain axis. In samples which were partly or completely recrystallized syntectonically the new olivine grains attained preferred orientations with [010] = X and [100] = Z parallel to the maximum and least principal compressive stress axes, respectively. These results may be used for kinematic and dynamic analysis of naturally deformed dunites and peridotites.  相似文献   
20.
Small, steep, uplifting coastal watersheds are prolific sediment producers that contribute significantly to the global marine sediment budget. This study illustrates how sedimentation evolves in one such system where the continental shelf is largely sediment-starved, with most terrestrial sediment bypassing the shelf in favor of deposition in deeper basins. The Santa Barbara–Ventura coast of southern California, USA, is considered a classic area for the study of active tectonics and of Tertiary and Quaternary climatic evolution, interpretations of which depend upon an understanding of sedimentation patterns. High-resolution seismic-reflection data over >570 km2 of this shelf show that sediment production is concentrated in a few drainage basins, with the Ventura and Santa Clara River deltas containing most of the upper Pleistocene to Holocene sediment on the shelf. Away from those deltas, the major factor controlling shelf sedimentation is the interaction of wave energy with coastline geometry. Depocenters containing sediment 5–20 m thick exist opposite broad coastal embayments, whereas relict material (bedrock below a regional unconformity) is exposed at the sea floor in areas of the shelf opposite coastal headlands. Locally, natural hydrocarbon seeps interact with sediment deposition either to produce elevated tar-and-sediment mounds or as gas plumes that hinder sediment settling. As much as 80% of fluvial sediment delivered by the Ventura and Santa Clara Rivers is transported off the shelf (some into the Santa Barbara Basin and some into the Santa Monica Basin via Hueneme Canyon), leaving a shelf with relatively little recent sediment accumulation. Understanding factors that control large-scale sediment dispersal along a rapidly uplifting coast that produces substantial quantities of sediment has implications for interpreting the ancient stratigraphic record of active and transform continental margins, and for inferring the distribution of hydrocarbon resources in relict shelf deposits.  相似文献   
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