High‐pressure metamorphic evolution of eclogite and associated metapelite from the Chuacús complex (Guatemala Suture Zone): Constraints from phase equilibria modelling coupled with Lu‐Hf and U‐Pb geochronology          下载免费PDF全文

Roberto Maldonado  Bodo Weber  Fernando Ortega‐Gutiérrez  Luigi A. Solari 《Journal of Metamorphic Geology》2018,36(1):95-124

As is common in suture zones, widespread high‐pressure rocks in the Caribbean region reached eclogite facies conditions close to ultrahigh‐pressure metamorphism. Besides eclogite lenses, abundant metapelitic rocks in the Chuacús complex (Guatemala Suture Zone) also preserve evidence for high‐pressure metamorphism. A comprehensive petrological and geochronological study was undertaken to constrain the tectonometamorphic evolution of eclogite and associated metapelite from this area in central Guatemala. The integration of field and petrological data allows the reconstruction of a previously unknown segment of the prograde P–T path and shows that these contrasting rock types share a common high‐pressure evolution. An early stage of high‐pressure/low‐temperature metamorphism at 18–20 kbar and 530–580°C is indicated by garnet core compositions as well as the nature and composition of mineral inclusions in garnet, including kyanite–jadeite–paragonite in an eclogite, and chloritoid–paragonite–rutile in a pelitic schist. Peak high‐pressure conditions are constrained at 23–25 kbar and 620–690°C by combining mineral assemblages, isopleth thermobarometry and Zr‐in‐rutile thermometry. A garnet/whole‐rock Lu‐Hf date of 101.8 ± 3.1 Ma in the kyanite‐bearing eclogite indicates the timing of final garnet growth at eclogite facies conditions, while a Lu‐Hf date of 95.5 ± 2.1 Ma in the pelitic schist reflects the average age of garnet growth spanning from an early eclogite facies evolution to a final amphibolite facies stage. Concordant U‐Pb LA‐ICP‐MS zircon data from the pelitic schist, in contrast, yield a mean age of 74.0 ± 0.5 Ma, which is equivalent to a U‐Pb monazite lower‐intercept age of 73.6 ± 2.0 Ma in the same sample, and comparable within errors with a less precise U‐Pb lower‐intercept age of 80 ± 13 Ma obtained in post‐eclogitic titanite from the kyanite‐bearing eclogite. These U‐Pb metamorphic ages are interpreted as dating an amphibolite facies overprint. Protolith U‐Pb zircon ages of 167.1 ± 4.2 Ma and 424.6 ± 5.0 Ma from two eclogite samples reveal that mafic precursors in the Chuacús complex originated in multiple tectonotemporal settings from the Silurian to Jurassic. The integration of petrological and geochronological data suggests that subduction of the continental margin of the North American plate (Chuacús complex) beneath the Greater Antilles arc occurred during an Albian‐Cenomanian pre‐collisional stage, and that a subsequent Campanian collisional stage is probably responsible of the amphibolite facies overprint and late syncollisional exhumation.  相似文献   

Changing debris flow activity after sudden sediment input: a case study from the Swiss Alps          下载免费PDF全文

Patrick Baer  Christian Huggel  Brian W. McArdell  Florian Frank 《Geology Today》2017,33(6):216-223

On 27 December 2011, a rock avalanche in the upper Val Bondasca in the southern Swiss Alps deposited 1.5–1.7 million m³ of rock debris. The following summer, debris flow activity in Val Bondasca was unusually high with four events after a 90‐year period of debris flow inactivity. This was an exceptional situation for the valley. Analysing the 2012 events, the long‐term record of meteorological conditions such as rainfall intensity and duration, in comparison with debris flow activity, suggests that the meteorological conditions in summer 2012 would not have triggered the high intensity debris flow events without additional sediment input. Consequently, the suddenly increased debris availability can be considered a major factor in these events. Interestingly, rainfall events of similar magnitude in the subsequent years 2013–2015 did not trigger additional debris flow events, indicating that debris flow initiation thresholds are increasing again, back towards pre‐rock avalanche levels. This study aims to help in understanding the so far poorly understood temporal evolution of debris flow triggering thresholds and the effect of sudden changes in sediment availability.  相似文献   

Litho- and biofacies analysis of postglacial marine mud using CT-Scanning     

Marie Gagnoud  Patrick Lajeunesse  Gaston Desrosiers  Bernard Long  Suzanne Dufour  Jacques Labrie  Florian Mermillod-Blondin  Georges Stora 《Engineering Geology》2009,103(3-4):106-111

Marine silty clay deposited during the Late-Wisconsinian postglacial marine transgression of eastern Québec (Goldthwait Sea) is ubiquitous in the sedimentary column of intertidal zones of the St-Lawrence Estuary. This mud is very compact and limits the penetration of organisms composing the modern Macoma balthica community. In order to describe the characteristics of intertidal sediments containing Goldthwait Sea mud, axial tomography (CT-Scan) is used. CT-Scan is a non-destructive method that can be used to describe sediment characteristics (grain size, mineralogy, primary and secondary sedimentary structures, fabric, shape and roundness, bedding contact), and to obtain high resolution, 3D representations of structures within sediment cores. Based on differences in the densities of analysed materials, the different lithologies, lithofacies, and organisms within the core can be discriminated, and a quantification of the volume occupied by the different components of the material can be made. Here, CT-Scan images provide information on the distribution, orientation and interweaving of thanatocœnosis shell beds that alternate with massive or faintly laminated postglacial marine mud beds, as well as on ichnofacies characteristics. In addition, we show 3D images of bioturbation structures within the recent sediment layer, which is distinguished from the underlying Goldthwait Sea mud. When coupled with conventional sedimentary (grain size statistics) and radiochronological (¹⁴C) analyses, these data provide information which is valuable for identifying depositional processes within sedimentary environments.  相似文献   

Isotopic evidence (Sr/Sr, δLi) for alteration of the oceanic crust at deep-rooted mud volcanoes in the Gulf of Cadiz, NE Atlantic Ocean     

Florian Scholz  Christian Hensen  Rolf L. Romer  Anette Meixner  Matthias Haeckel 《Geochimica et cosmochimica acta》2009,73(18):5444-206

The chemical and isotopic composition of pore fluids is presented for five deep-rooted mud volcanoes aligned on a transect across the Gulf of Cadiz continental margin at water depths between 350 and 3860 m. Generally decreasing interstitial Li concentrations and ⁸⁷Sr/⁸⁶Sr ratios with increasing distance from shore are attributed to systematically changing fluid sources across the continental margin. Although highest Li concentrations at the near-shore mud volcanoes coincide with high salinities derived from dissolution of halite and late-stage evaporites, clayey, terrigenous sediments are identified as the ultimate Li source to all pore fluids investigated. Light δ⁷Li values, partly close to those of hydrothermal vent fluids (δ⁷Li: +11.9‰), indicate that Li has been mobilized during high-temperature fluid/sediment or fluid/rock interactions in the deep sub-surface. Intense leaching of terrigenous clay has led to radiogenic ⁸⁷Sr/⁸⁶Sr ratios (∼0.7106) in pore fluids of the near-shore mud volcanoes. In contrast, non-radiogenic ⁸⁷Sr/⁸⁶Sr ratios (∼0.7075) at the distal locations are attributed to admixing of a basement-derived fluid component, carrying an isotopic signature from interaction with the basaltic crust. This inference is substantiated by temperature constraints from Li isotope equilibrium calculations suggesting exchange processes at particularly high temperatures (>200 °C) for the least radiogenic pore fluids of the most distal location.Advective pore fluids in the off-shore reaches of the Gulf of Cadiz are influenced by successive exchange processes with both oceanic crust and terrigenous, fine-grained sediments, resulting in a chemical and isotopic signature similar to that of fluids in near-shore ridge flank hydrothermal systems. This suggests that deep-rooted mud volcanoes in the Gulf of Cadiz represent a fluid pathway intermediate between mid-ocean ridge hydrothermal vent and shallow, marginal cold seep. Due to the thicker sediment coverage and slower fluid advection rates, the overall geochemical signature is shifted towards the sediment-diagenetic signal compared to ridge flank hydrothermal environments.  相似文献   

Assessing the Perth Basin geothermal opportunity: Preliminary results from simulations of heat transfer and fluid flow     

Heather A. Sheldon  Thomas Poulet  J. Florian Wellmann  Klaus Regenauer-Lieb  Mike Trefry  Franklin G. Horowitz  Klaus Gessner 《Journal of Geochemical Exploration》2009

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Defining biominerals and organominerals: Direct and indirect indicators of life. Perry et al., Sedimentary Geology, 201, 157–179     

Wladyslaw Altermann  Christine Böhmer  Frank Gitter  Florian Heimann  Inga Heller  Benjamin Läuchli  Constanze Putz 《Sedimentary Geology》2009,213(3-4):150-151

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Distribution patterns and stable carbon isotopic composition of alkanes and alkan-1-ols from plant waxes of African rain forest and savanna C3 species     

Angela Vogts  Heiko Moossen  Florian Rommerskirchen  Jürgen Rullkötter 《Organic Geochemistry》2009,40(10):1037-1054

Leaf wax components of terrestrial plants are an important source of biomass in the geological records of soils, lakes and marine sediments. Relevant to the emerging use of plant wax derived biomarkers as proxies for past vegetation composition this study provides key data for C₃ plants of tropical and subtropical Africa. We present analytical results for 45 savanna species and 24 rain forest plants sampled in their natural habitats. Contents and distribution patterns of long chain n-alkanes (n-C₂₅ to n-C₃₅) and n-alkan-1-ols (n-C₂₄ to n-C₃₄) as well as bulk and molecular carbon isotopic data are presented. The variations of the analysed parameters among different growth forms (herb, shrub, liana and tree) are small within the vegetation zones, whereas characteristic differences occur between the signatures of rain forest and savanna plants. Therefore, we provide averaged histogram representations for rain forest and savanna C₃ plants.The findings were compared to previously published data of typical C₄ grass waxes of tropical and subtropical Africa. Generally, trends to longer n-alkane chains and less negative carbon isotopic values are evident from rain forest over C₃ savanna to C₄ vegetation. For n-alkanols of rain forest plants the maximum of the averaged distribution pattern is between those of C₃ savanna plants and C₄ grasses. The averaged presentations for tropical and subtropical vegetation and their characteristics may constitute useful biomarker proxies for studies analysing the expansion and contraction of African vegetation zones.  相似文献   

Contrasting fluid evolution of granulite-facies marbles: implications for a high-T intermediate-P terrain in the Famatinian Range, San-Juan, Argentina     

Florian Gallien  Aberra Mogessie  Ernesto Bjerg  Sergio Delpino  Brigida Castro de Machuca 《Mineralogy and Petrology》2009,95(1-2):135-157

High-temperature, intermediate-pressure calc-silicate marbles occur in the granulite-facies terrain of the La Huerta Range in the Province of San Juan, NW-Argentina, in three bulk-compositional varieties: Type (1) dolomite-absent scapolite-wollastonite-grandite-clinopyroxene-quartz—calcite marbles; Type (2) diopside-forsterite-spinel-corundum—calcite marbles with dolomite exolution lamellae in calcite; Type (3) serpentinized forsterite-spinel-dolomite marbles. An isobaric cooling path from peak-metamorphic conditions of 860°C to 750°C at 6.5 kbar is inferred from scapolite-wollastonite-grandite reaction textures in Type (1) and is consistent with cooling after an advective heat input from related gabbroic and tonalitic intrusive bodies. Stable carbon and oxygen isotope geochemistry was used to decipher the fluid/rock evolution of the three marble types. An interpreted four-stage temperature-time-fluid flow path comprises: (1) infiltration of pre-peak-metamorphic fluids, depleted in δ¹⁸O, that caused a shift of primary sedimentary δ¹⁸O ratios to lower values (19.6–20.0); (2) syn-metamorphic fluid liberation from Type (1) marbles with evidence for processes close to batch devolatilization that caused a weak coupled ¹³C and ¹⁸O depletion during prograde metamorphism. A different devolatilization behaviour, close to Rayleigh fractionation, texturally associated with fold settings indicates that granulite-facies fluid flow was focused rather than pervasive; (3) H₂O-absent conditions were dominant when coronal grandite formed during incipient high-temperature isobaric cooling at the expense of scapolite and wollastonite in the Type (1) marbles; (4) intense post-peak- hydration of Type (2) and Type (3) marbles is the last recognizable metasomatic event. In combination, the three marble types record fluid infiltration both before and after the metamorphic peak.  相似文献   

Textural, chemical, and isotopic effects of late-magmatic carbonatitic fluids in the carbonatite–syenite Tamazeght complex, High Atlas Mountains, Morocco     

Michael A. W. Marks  Florian Neukirchen  Torsten Vennemann  Gregor Markl 《Mineralogy and Petrology》2009,97(1-2):23-42

Carbonatites of the Eocene Tamazeght complex, High Atlas Mountains, Morocco, consist of calciocarbonatites (alvikite and sövite dykes) and magnesiocarbonatites (diatreme breccias and dykes rocks). These are associated with ultramafic, shonkinitic, gabbroic to monzonitic and various foid syenitic silicate units. Stable and radiogenic isotope compositions for carbonatites and silicate rocks indicate that they share a common source in the mantle, although for some carbonatitic samples contamination with sedimentary rocks seems important. The observed isotopic heterogeneity is mainly attributed to source characteristics, fractional crystallization (accompanied by various degrees of assimilation), and late- to post-magmatic fluid–rock interaction. During the late fluid–rock interaction, Sr, Mn, and possibly also Fe were mobilized and redistributed to form secondary carbonate minerals in carbonatites. These fluids also penetrated into the adjacent syenitic rocks, causing enrichment in the same elements.  相似文献   

Variability and alterations of water temperatures across the Elbe and Danube River Basins     

Danijela Markovic  Ulrike Scharfenberger  Stefan Schmutz  Florian Pletterbauer  Christian Wolter 《Climatic change》2013,119(2):375-389

Climate change is predicted to be a major threat to river ecosystems in the 21st century, but long-term records of water temperature in streams and rivers are rare. This study uses long-term water temperature series from the Elbe and the Danube River Basin to quantify the variability, magnitude, and extent of temperature alterations at different time scales. The observed patterns in monthly and daily water temperatures have been successfully described through statistical models based on air temperature, river discharge and the North Atlantic Oscillation Index. These models reveal that air temperature variability describes more than 80 % of the total water-temperature variability, linking anticipated changes in water temperature mainly to those in air temperature. The North Atlantic Oscillation effect deteriorates with decreasing latitude, while the discharge effect becomes more important and increases with the increase in discharge amount. The detected water temperature alterations include a phase shift in spring warming of almost 2 weeks, an increase in the number of days with temperatures above 25 °C and an increase in the duration of summer heat stress. These findings underline a significant risk for fundamental changes in river ecosystems, specifically in disruption of established patterns in food-web synchrony, and may lead to significant distortions in community structure and composition.  相似文献