Intercrystalline cation partitioning between minerals of the triplite-zwieselite-magniotriplite and the triphylite-lithiophilite series in granitic pegmatites     

Paul Keller  François Fontan  André-Mathicu Fransolet 《Contributions to Mineralogy and Petrology》1994,118(3):239-248

Minerals of the triphylite-lithiophilite, Li(Fe, Mn)PO₄, and the triplite-zwieselite-magniotriplite series, (Mn, Fe, Mg)₂PO₄F, occur in the late stage period of pegmatite evolution. Unfortunately, neither are the genetic relationships between these phosphates fully understood nor are thermodynamic data known. Consequently, phosphate associations and assemblages from 8 granitic pegmatites — Clementine II, Rubicon II and III, and Tsaobismund (Namibia); Hagendorf-Süd and Rabenstein (Germany); Valmy (France); Viitaniemi (Finland) — have been tested for compositional zoning and intercrystalline partitioning of main elements by electron microprobe techniques. Although the selected pegmatites display varying degrees of fractionation, and the intergrowth textures indicate different genetic relationships between the phosphates, the plots of mole fractions X _Fe=Fe/(Fe+Mn+Mg+Ca), X _Mn=Mn/(Fe+Mn+Mg+Ca), and X _Mg=Mg/(Fe+Mn+Mg+Ca) can be fitted relatively well with smooth curves in Roozeboom diagrams. Their deviations from symmetrical distribution curves are mainly dependent upon X _Mg or X _Ca, and upon non-ideal solutions. Surprisingly small differences between the partition coefficients were detected for intergrowths of different origin. However, the partitioning of shared components among coexisting phases is clearly dependent upon the conditions of formation. Compositional zoning is observed only when both Fe–Mn phosphates are intergrown mutually or with other Fe–Mn–Mg mineral solid-solutios. Thus, the zoning does not seem to be due to continuous crystallization, but to later diffusion processes. The triplite structure has preference for Mn, Mg, and Ca, while Fe prefers minerals of the triphylite series. A quantification of main element fractionation between minerals of the triphylite and the triplite series is possible in the cases where diffusion can be excluded. For the Fe/(Fe+Mn) ratios of core compositions an equation with a high correlation coefficient (R=0.988) was determined: Fe/(Fe+Mn)_Tr=[Fe/(Fe+Mn)_Li]/{2.737-(1.737)[Fe/(Fe+Mn)_Li]} (Tr=triplite series, Li=triphylite series). Consequently, the Fe/(Fe+Mn) ratio of the triplite series can now also be used in the interpretation of pegmatite evolution, just like that of the triphylite series which has been successfully applied in the past.  相似文献   

The origin of the high-K latites from Camp Creek,Arizona: constraints from experiments with variable fO2 and a_{{\text{H}}_{\text{2}} {\text{O}}}     

Sonia Esperança  John R. Holloway 《Contributions to Mineralogy and Petrology》1986,93(4):504-512

Near-liquidus melting experiments were performed on a high-K latite at fO₂'s ranging from iron-wustite-graphite (IWG) to nickel-nickel oxide (NNO) in the presence of a C-O-H fluid phase. Clinopyroxene is a liquidus phase under all conditions. At IWG , the liquidus at 10 kb is about 1,150° C but is depressed to 1,025° C at NNO and . Phlogopite and apatite are near-liquidus phases, with apatite crystallizing first at pressures below 10 kb. Phlogopite is a liquidus phase only at NNO and high . Under all conditions the high-K latites show a large crystallization interval with phlogopite becoming the dominant crystalline phase with decreasing temperature. Increasing fO₂ affects phlogopite crystallization but the liquidus temperature is essentially a function of . The chemical compositions of the near-liquidus phases support formation of the high-K latites under oxidizing conditions (NNO or higher) and high . It is concluded from the temperature of the H₂O-saturated liquidus at 10 kb, the groundmass: crystal ratio and presence of chilled latite margins around some xenoliths that the Camp Creek high-K latite magma passed thru the lower crust at temperatures of 1,000° C or more.  相似文献   

Middle miocene deduction and late miocene beginning of collision registered in the hengchun peninsula: Geodynamic implications for the evolution of Taiwan     

Bernard Pelletier  Jean Franois Stephan 《Tectonophysics》1986,125(1-3)

Taiwan is located in the axis of the Manila Trench. It results from an oblique collision between the northernmost part of the Luzon arc and the Chinese passive margin. This active collision follows the subduction of the Oligocene-Miocene oceanic crust of the South China Sea along the Manila Trench. The tectonized Chinese margin emerged in the Hengchun peninsula (South Taiwan). Gentle folds which are delineated by the Quaternary reefal limestones demonstrate Recent deformations. These folds deformed a thick detrital sequence of Miocene age (Ssuchung Chi series) which was previously strongly folded and thrust westward (axis NS-N20) upon the Renting mélange of Latest Miocene age. These main deformations, sealed by the Middle Pliocene, are the evidence for the onset of collision in this part of Taiwan at the end of the Miocene. Because of its obliquity, the collision started already in the northern part of Taiwan during the Late Miocene (6-7-8 Ma ?).The Ssuchung Chi series, a sequence of proximal turbidites, has contained, since the Middle Miocene (NN 6~13 Ma), fragments of an Oligocene to Lower Miocene oceanic crust. This ophiolitic material is very similar to the East Taiwan Ophiolite of the Coastal Range. It originated most probably from a slice of South China Sea crust obducted in Middle Miocene times (13–14 Ma) upon the Chinese margin (North of the Hengchun peninsula). This obduction occurred 7 to 8 Ma before the beginning of collision. These results make it possible to propose an evolutionary model for Taiwan from the Oligocene to the Recent, with the different phases of a collision between a volcanic arc and a passive margin.  相似文献   

Multispectral remote sensing of biomass burning in West Africa     

J. Ricardo  A. De França  J. -M. Brustet  J. Fontan 《Journal of Atmospheric Chemistry》1995,22(1-2):81-110

Remote sensing measurements provide a vauable means of determining the extent of burning areas and of estimating the overall distribution of pollutant sources (identified from experimental studies) in time and space. This distribution has to be taken into account in the boundary conditions of chemistry atmospheric models.Recent methods developed for the remote sensing of active fires in tropical or temperated forest zones, have been found to be completely inadequate for fire detection on West African savannas. In order to accurately estimate the active fire distribution in the function of different sorts of West African savannas (Sahelian, Sudanian and Guinean) and forests, a multispectral methodology has been developed based on NOAA/11-AVHRR satellite data, with the purpose of eliminating as much as possible the problems related to large surface heterogeneity, confusion and bias, produced by clouds, smoke, haze, background emissivities, etc.Unlike other methods, the results show that the multispectral method, in spite of its selectivity, provides realistic results, and does not under- or over-estimate the number of fires that can be sensed by the satellite. Consequently, this methodology is more appropriate than the simplest ones for a systematic sensing of this phenomenon.  相似文献   

The stratospheric quasi-biennial oscillation observed in the semidiurnal ground pressure data     

Hector Teitelbaum  François Vial  Pierre Bauer 《Annales Geophysicae》1995,13(7):740-744

Ground pressure observations made at Macao (22^○N, 113^○E) from 1953 to 1991 are analyzed and compared with the stratospheric quasi-biennial oscillation (QBO) data obtained during the same interval. The periods of the two phenomena and their time evolution are found to be close to each other. Furthermore, the time series of the stratospheric winds and the S2(p) QBO signature are highly correlated, thus confirming earlier analysis. On this basis, pressure measurements obtained at Batavia (now Djakarta: 6^○S, 107^○E) from 1870 to 1944 are used to trace back the QBO phenomenon before the advent of systematic stratospheric balloon measurements. The inferred period, which varies between 25 and 32 months, suggests that the QBO has been present in the atmosphere at least since 1870.  相似文献   

Detailed gravity study of the offshore structure of Piton de la Fournaise volcano,Reunion Island     

Dominique Rousset  Alain Bonneville  Jean-François Lenat 《Bulletin of Volcanology》1987,49(6):713-722

We present an interpretation of gravity data acquired in 1984 by the French R/V Jean Charcot on the submarine part of the eastern flank of Piton de la Fournaise volcano. We comment on the Bouguer anomaly map and give a quantitative interpretation of three gravity profiles. The main results are that a gravity high over Grand Brûlé, the lower subaerial part of the eastern flank, does not extend far offshore and that an anomalous topographic feature, discovered in 1982 on the submarine eastern flank, is characterized by a large negative anomaly. We propose three hypotheses to explain the origin of this anomaly, i. e., it marks the site of a new volcano, or it is a consequence of lateral volcanism from a volcano older than Piton de la Fournaise, or more probably, it represents a great landslide deposit.  相似文献   

A new method for sampling and analyzing volcanic sublimates — application to Merapi volcano, Java     

Franois Le Guern  Alain Bernard 《Journal of Volcanology and Geothermal Research》1982,12(1-2)

A new method for the sampling of sublimates from high-temperature volcanic gases has been used at Merapi volcano, Java, in 1978. The sublimates were collected on the inner walls of silica tubes introduced into fumarolic vents. Volcanic gases were allowed to move freely through the tubes and as they cooled, a fraction of the volatile components condensed on the inner walls of the tubes along the temperature gradient. The sublimates were then analyzed by a combination of light microscopy, scanning electron microscopy, electron microprobe and X-ray diffraction.Six successive zones of different compositions and mineralogical associations have been identified along the covered range of temperatures (900° to around 400°C). From the high to the low temperatures, these zones are composed of: (1) cristobalite, magnetite, hercynite; (2) molybdenite; (3) acmite; (4) halite, sylvite; (5) sphalerite, pyrite; and (6) galena. Equilibrium calculations show that these crystalline phases are stable for pS₂, pC₁, and pO₂, values typical of magma-buffered gases that have not been contaminated by atmospheric oxygen.The deposits observed in the tubes may be useful in aiding the understanding of the mechanisms acting during the cooling of the gaseous phase on its way to the surface and before its emission into the atmosphere.  相似文献   

Frequency-independent impedances of soil-structure systems in horizontal and rocking modes     

Mansour Ghaffar-Zadeh  Franois Chapel 《地震工程与结构动力学》1983,11(4):523-540

The frequency-independent foundation impedances, commonly used in soil-structure dynamic interaction problems, are developed for a circular footing resting on a homogeneous halfspace. As they ignore the structure attached to the foundation, the error introduced in the structural response may be 50 per cent or more in the neighbourhood of the fundamental frequency of the soil-structure system. The present study proposes a new method developed for most dynamic soil-structure interaction problems. The key idea is to retain for the frequency-independent impedances values computed for the fundamental frequency of the soil-structure system; thus these values include the dynamic characteristics of the whole soil-structure system and lead to a satisfactory approximation of the exact solution over a wide frequency range. The method is developed here for the horizontal and rocking modes of a structure with a circular base resting on a homogeneous halfspace. Numerical applications are given for a simple linear oscillator in order to make possible a thorough parametric study. The response of some idealized building-foundation systems to harmonic excitation or to a seismic input is next examined in order to illustrate the efficiency of the proposed model.  相似文献   

Authigenic smectite on diatom frustules in Bolivian saline lakes     

Denise Badaut  François Risacher 《Geochimica et cosmochimica acta》1983,47(3):363-375

Observation under the electron microscope of diatom frustules from Bolivian Altiplano saline lakes shows that many of these are coated with particles occurring as tiny sheets. The frustules can be found to be almost completely replaced by these sheets. Isolated sheet aggregates seem to have resulted from completely transformed frustules. Section observations of altered frustules bear out that the sheets have grown from biogenic silica through replacement. Selected area diffraction, dark field observation, microdiffraction, and elemental microanalysis show that the particles on the diatom frustules consist of a poorly crystallized MG-smectite.The unambiguous localisation of this authigenesis allows us to reconstruct its hydrochemical and sedimentological environment. Observation of the most recent lake sediments has pointed out that at least two main conditions are required for this authigenesis at 5°C: saturation with respect to amorphous silica, and a pH above 8.2. Variations in the Mg concentration have no significant effect.  相似文献   

Fracturation tertiaire et évolution des contraintes en Bavière orientale: le Jura franconien et la forêt bavaroise (R.F.A.)     

Dr. Françoise Bergerat  Jacques Geyssant 《International Journal of Earth Sciences》1983,72(3):935-953

Résumé L'analyse géométrique et cinématique de la fracturation dans le Jura franconien et la bordure occidentale du Massif bohémien met en évidence les mécanismes de la tectonique cassante d'âge teriaire, essentiellement ceux des grands accidents SE-NW (lignes de Pfahl et de Franconie) qui ont présenté successivement des jeux en coulissement dextre, en faille normale et en faille inverse. Cinq états de contrainte ont été caractérisés et comparés à ceux définis antérieurement dans le Jura souabe, en liaison avec la cinématique des plaques Europe et Afrique: compression N-S, distension E-W, compression NE-SW puis E-W, distension N-S.

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The analysis of both the geometric and the kinematic cenozoic faulting in the Franconian Jura and in western Bohemia enables to characterize the mechanisms of cenozoic tectonics. More especially dextral strike-slip, normal fault and reverse fault have successively occurred along large SE-NW fault line, as the Pfahl and the Franconian fault systems. Five main stress patterns have thus been identified and then compared with those previously described in Swabian Jura. They are related to the kinematic of Europe and Africa plates, i. e.: (1) N-S compression, (2) E-W distension, (3) SW-NE compression, (4) E-W compression, (5) N-S distension.

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Zusammenfassung Durch die geometrische und kinematische Analyse der Brüche wird die tertiäre Bruchtektonik (tectonique cassante) im Fränkischen Jura und am westlichen Rand des Böhmischen Massifs belegt. Es handelt sich im wesentlichen um die großen SE-NW orientierten Störungen der Linie von Pfahl und der Fränkischen Linie, die nacheinander als dextrale Blattverschiebungen, als Normalverwerfungen und als inverse Verwerfungen wirkten. Fünf Spannungszustände können charakterisiert und mit jenen, die bereits im Schwäbischen Jura definiert wurden, verglichen werden. Sie spiegeln die verschiedenen Stadien der kinematischen Entwicklung der europäischen und afrikanischen Platte wider: Kompression N-S, Zerrung E-W, Kompression NE-SW, sodann E-W, Zerrung N-S.

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