Bioremediation of petroleum hydrocarbons in anoxic marine sediments: Consequences on the speciation of heavy metals   总被引：3，自引：0，他引：3  

Antonio Dell’Anno  Francesca Beolchini  Massimo Gabellini  Laura Rocchetti  Antonio Pusceddu  Roberto Danovaro 《Marine pollution bulletin》2009,58(12):1808-1814

We investigated the effects of biostimulation and bioagumentation strategies applied to harbor sediments displaying reducing conditions and high concentrations of petroleum hydrocarbons and heavy metals. We compared the microbial efficiency of hydrocarbon removal from sediments maintained for 60 days in anoxic conditions and inoculated with acetate, sulfate-reducing bacterial strains and acetate and sulfate-reducing bacteria. All treatments determined a significant increase in the microbial growth and significant decreases of hydrocarbon contents and of redox potential values. The addition of sulfate-reducing bacterial strains to the sediment was the most efficient treatment for the hydrocarbon removal. In all experiments, significant changes of the heavy metals’ phase repartition were observed. The results reported here suggest that the biodegradation of petroleum hydrocarbons in anoxic marine sediments may be enhanced by stimulating microbial anaerobic metabolism, but care should be applied to monitor the potential changes in the mobility and bioavailability of heavy metals induced by bio-treatments.  相似文献   

Estimation of load reduction factors for clay masonry walls     

Francesca da Porto  Manuel Grendene  Claudio Modena 《地震工程与结构动力学》2009,38(10):1155-1174

The in‐plane cyclic behaviour of three types of unreinforced clay masonry was characterized by means of laboratory tests on full‐scale specimens. The masonry walls were assembled with various bonding arrangements (head joints made with mortar pockets, dry head joints with mechanical interlocking, thin‐layer mortar bed joints), which are not yet inserted in seismic codes. Experimental behaviour was modelled with an analytical hysteretic model able to predict lateral load–displacement curves in case of shear failure of the unreinforced walls. According to the experimental results and those of the selected analytical model, parametric study to evaluate the reduction in lateral strength demand produced by non‐linear behaviour in masonry walls, i.e. the load reduction factor was carried out by non‐linear dynamic analyses. The calculated values of the load reduction factor were modest. The differences in values found for the three masonry types, although consistent with them, were not great. This may indicate that, in the ultimate limit state, the type of masonry cannot significantly affect the behaviour of an entire building. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

The amphipod Talitrus saltator as a bioindicator of human trampling on sandy beaches     

Ugolini A  Ungherese G  Somigli S  Galanti G  Baroni D  Borghini F  Cipriani N  Nebbiai M  Passaponti M  Focardi S 《Marine environmental research》2008,65(4):349-357

The present paper assesses the use of the supralittoral amphipod Talitrus saltator as a bioindicator of the effects of human trampling on the supralittoral sandy band. Samplings in delimited areas were carried out at sites subjected to different human impact. The results showed a strong negative correlation between the number of swimmers and the sandhopper population density, while there was no clear relationship between sandhopper abundance and the other factors considered: granulometry, compactness and organic carbon content of the sand, and trace metal contents in the sand and sandhoppers. A field test of trampling conducted in a confined space showed its direct negative effect on sandhopper survival. However, trace metal analysis confirmed the ability of T. saltator to bioaccumulate some elements (Hg, Zn, Cu, Cd). Our study demonstrates that T. saltator is a good bioindicator of human impact in the supralittoral zone of sandy shores.  相似文献   

Determination of S-wave energy release of earthquakes in the region of Friuli, Italy     

Raúl R. Castro  Francesca Pacor  Carmine Petrungaro 《Geophysical Journal International》1997,128(2):399-408

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The structure of the Campanian Plain and the activity of the Neapolitan volcanoes (Italy)     

Roberto Scandone  Francesca Bellucci  Lucio Lirer  Giuseppe Rolandi 《Journal of Volcanology and Geothermal Research》1991,48(1-2)

The central Campanian Plain is dominated by the structural depression of Acerra whose origin is tectonic, but may have been enlarged and further depressed after the eruption of the Campanian Ignimbrite (42-25 ka). The deposits of the Campanian Ignimbrite are possibly the results of multiple eruptions with huge pyroclastic deposits that covered all the Campanian Plain.The more recent activity of Vesuvius, Campi Flegrei and Procida occurred on the borders of Acerra depression and resulted from a reactivation of regional faults after the Campanian Ignimbrite cycle. The activity of Vesuvius produced the building of a stratovolcano mostly by effusive and plinian explosive eruptions. The Campi Flegrei area, on the contrary, was dominated by the eruption of the Neapolitan Yellow Tuff at 12 ka that produced a caldera collapse of the Gulf of Pozzuoli. The caldera formation controlled the emplacement of the recent activity of Campi Flegrei and the new volcanoes were formed only within the caldera or along its rim.  相似文献   

New records of cold‐water coral sites and fish fauna characterization of a potential network existing in the Mediterranean Sea          下载免费PDF全文

Gianfranco D'Onghia  Crescenza Calculli  Francesca Capezzuto  Roberto Carlucci  Angela Carluccio  Porzia Maiorano  Alessio Pollice  Pasquale Ricci  Letizia Sion  Angelo Tursi 《Marine Ecology》2016,37(6):1398-1422

New cold‐water coral (CWC) sites were recorded along the Apulian margin (Central Mediterranean). The species composition and depth distribution of CWCs were updated. A distribution of the CWC sites coincident with the course of the dense‐water masses that flow between the Southern Adriatic and Northern Ionian was confirmed. The faunal assemblages of five of these CWC sites were investigated and compared using experimental longlines during the spring–summer and autumn–winter seasons, between 2010 and 2014. Differences in ecological variables amongst the sites in each season were evaluated by means of a set of univariate and multivariate methods (analysis of variance, permutational multivariate analysis of variance, non‐metric multidimensional scaling). Although some differences were detected in relation to the different depths examined during spring–summer, the CWC sites showed similar features in terms of species richness and diversity as well as in the abundance of the same fish species (Galeus melastomus, Conger conger, Helicolenus dactylopterus, Merluccius merluccius, Phycis blennoides and Pagellus bogaraveo) most probably because of the distribution of adult specimens in structurally complex and heterogeneous habitats, which act as a potential ‘refuge network’ with respect to commercial fishing. The presence of maturing and mature individuals as well as post‐reproductive females indicates that these CWC sites also act as spawning areas, representing a potential ‘renewal network’ for the fish populations. The term ‘network’ used here refers to several similar subsystems (CWC sites) that play the same ecological role in a wider system (Apulian margin). These CWC communities need coherent conservation measures and management strategies according to the Ecosystem Approach to Fisheries.  相似文献   

Time-course evaluation of ROS-mediated toxicity in mussels, Mytilus galloprovincialis, during a field translocation experiment     

Frenzilli G  Bocchetti R  Pagliarecci M  Nigro M  Annarumma F  Scarcelli V  Fattorini D  Regoli F 《Marine environmental research》2004,58(2-5):609-613

Harbours can be considered as model environments for developing and validating field monitoring procedures and to investigate mechanistic relationships between different biological responses. In this study several biomarkers were investigated in marine mussels caged for 4 weeks (June-July 2001) into an industrialized harbour of NW Italy. Organisms were collected at different time-intervals to better characterize the sensitivity, temporal variations and interactions of analysed responses. Besides single antioxidants the total oxyradical scavenging capacity (TOSC) assay was used to analyse the capability of the whole antioxidant system to neutralize specific forms of radicals: these data were further integrated by measurement of DNA integrity, oxidized bases and the impairment of lysosomal membrane stability in haemocytes. Results showed a biphasic trend for single antioxidants and TOSC, with an increase during the first 2 weeks of exposure to the polluted site followed by a progressive decrease up to a severe depletion in the final part of the experiment.  相似文献   

Reprint of “Seasonal and daily variation of mercury evasion at coastal and off shore sites from the Mediterranean Sea”     

Maria E. Andersson  Katarina Gårdfeldt  Ingvar Wängberg  Francesca Sprovieri  Nicola Pirrone  Oliver Lindqvist 《Marine Chemistry》2007

Dissolved gaseous mercury (DGM) was measured continuously using two newly developed techniques and a manual technique. The continuous techniques were based on the equilibrium between the aqueous and gaseous phase (DGM = Hg_extr / H', Hg_extr is the measured mercury concentration in the gas phase, H' is the Henry's Law coefficient at the desired temperature). In order to calculate the annual mercury evasion from the Mediterranean Sea, diurnal and seasonal measurements of DGM, total gaseous mercury in air (TGM), water temperature and wind speed were performed. During August 2003, March–April 2004 and October–November 2004 measurements of these parameters were conducted on board the RV Urania. The continuous measurements of DGM showed a diurnal variation in concentration, at both coastal and off shore sites, with higher concentrations during daytime than nighttime. The concentration difference could be as large as 130 fM between day and night. The degree of saturation was calculated directly from the measurements, S = Hg_extr / TGM and was found to vary between the different seasons. The highest average degree of saturation (850%) and the largest variation in saturation (600–1150%) was observed during the summer. The spring showed the lowest variation (260–360%) and the lowest average degree of saturation (320%). The autumn also showed a large variation in saturation (500–1070%) but a lower average (740%) compared to the summer cruise. This might be explained by the temperature difference between the different seasons, since that parameter varied the most. The flux from the sea surface was calculated using the gas exchange model developed by Nightingale et al. [Nightingale, P.D., Malin, G., Law, C.S., Watson, A.J., Liss, P.S., Liddicoat, M.I., Boutin, J., Upstill-Goddard, R. C., 2000. In situ evaluation of air–sea gas exchange parameterization using novel conservative and volatile tracers. Global Biogeochemical Cycles, 14(1):373–387]. The evasion varied between the different seasons with the highest evasion during the autumn, 24.6 pmol m^− 2 h^− 1. The summer value was estimated to 22.3 pmol m^− 2 h^− 1 and the spring to 7.6 pmol m^− 2 h^− 1. Using this data the yearly evasion from the Mediterranean Sea surface was estimated to 77 tons.  相似文献   

A model of sand transport in Treporti channel: northern Venice lagoon     

Georg Umgiesser  Francesca De Pascalis  Christian Ferrarin  Carl L. Amos 《Ocean Dynamics》2006,56(3-4):339-351

The origin of the sands in the Venice lagoon has been the subject of an extensive field survey in parallel with numerical modelling. Four transects along Treporti and Burano canals were conducted from which 33 bottom sediment samples were collected. These samples were analysed for grain size and sorting to examine any trends in the granulometry of these sediments that might shed light on transport paths. The modelling study consists of three parts: the sediment transport model sedtrans96 was used with a finite-element hydrodynamic model (Shyfem) and an empirical wave model (US Army Corps of Engineering) to simulate sand transport in the Treporti canal. A type of link box model was created where finite elements of the hydrodynamic model have been combined to macro-boxes on which the water and sediment flux over the sections, and a mass balance has been computed. Several grain size classes were simulated; the distributions before and after the simulation were examined. Idealised wind and tidal values were initially used to force 12 h simulations to test the sediment transport sensitivity. Finally, a full-year simulation (1987) has been carried out using measured tidal and wind data. Only a part of Venice lagoon was covered by the simulation: a major channel (Treporti) running from Lido inlet towards the northern lagoon. The total sand transport through all of the sections was computed for 1 year. Sediment mass balance was determined, and the resulting trends of erosion and deposition were computed. There were no trends in the median grain diameter and sorting of bottom samples from the Treporti canal; all sands were fine (120 μm, one outlier of 300 μm was removed). The absence of a trend in grain size suggests that there is no significant import of sand to the lagoon through the Lido inlet. The results from the simulations seem therefore to confirm the hypothesis of reworking of sand within the lagoon. The computed erosion is some centimeters per year diagnostic of channel scouring and enlargement with time. The Treporti canal is subject to strong current velocities of around 1 m/s, which hold fine sand in suspension and thus prevent sedimentation.  相似文献   

New indices and calibrations derived from the distribution of crenarchaeal isoprenoid tetraether lipids: Implications for past sea surface temperature reconstructions   总被引：3，自引：0，他引：3  

Jung-Hyun Kim  Jaap van der Meer  Peer Helmke  Francesca Sangiorgi  Ellen C. Hopmans 《Geochimica et cosmochimica acta》2010,74(16):4639-4654

Several studies have shown that there is a strong relationship between the distribution of crenarchaeotal isoprenoid glycerol dibiphytanyl glycerol tetraethers (GDGTs) and sea surface temperature (SST). Based on this, a ratio of certain GDGTs, called TEX₈₆ (TetraEther indeX of tetraethers consisting of 86 carbon atoms), was developed as a SST proxy. In this study, we determined the distribution of crenarchaeotal isoprenoid GDGTs in 116 core-top sediments mostly from (sub)polar oceans and combined these data with previously published core-top data. Using this extended global core-top dataset (n = 426), we re-assessed the relationship of crenarchaeal isoprenoid GDGTs with SST. We excluded data from the Red Sea from the global core-top dataset to define new indices and calibration models, as the Red Sea with its elevated salinity appeared to behave differently compared to other parts of the oceans. We tested our new indices and calibration models on three different paleo datasets, representing different temperature ranges. Our results indicate that the crenarchaeol regio-isomer plays a more important role for temperature adaptation in (sub)tropical oceans than in (sub)polar oceans, suggesting that there may be differences in membrane adaptation of the resident crenarchaeotal communities at different temperatures. We, therefore, suggest to apply two different calibration models. For the whole calibration temperature range (−3 to 30 °C), a modified version of TEX₈₆ with a logarithmic function which does not include the crenarchaeol regio-isomer, called , is shown to correlate best with SST: (r² = 0.86, n=396, p <0.0001). Application of on sediments from the subpolar Southern Ocean results in realistic absolute SST estimates and a similar SST trend compared to a diatom SST record from the same core. , which is defined as the logarithmic function of TEX₈₆, yields the best correlation with SST, when the data from the (sub)polar oceans are removed: (r² = 00.87, n = 255, p < 0.0001). Furthermore, gives the best correlation for mescosm data with temperatures ranging between 10 and 46 °C. For Quaternary sediments from the tropical Arabian Sea, both and yield similar trends and SST estimates. However, the extrapolation of calibration on a sediment record from a greenhouse world ocean predicts more reliable absolute SST estimates and relative SST changes in agreement with estimates based on the δ¹⁸O of planktonic foraminifera. Based on the comparison of and derived SSTs using the core top data, we recommend applying above 15 °C and below 15 °C. In cases where paleorecords encompass temperatures both below and above 15 °C, we suggest to use .  相似文献