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101.
When waves impact a seawall, a vertical breakwater, an exposed jetty, a pier or a coastal bridge, they abruptly transfer their momentum into the structure. This energy transfer can be very violent and its duration exceptionally short. In the case of coastal bridges, whose spans are designed to have very short vibration period, wave impacts might have duration comparable to the natural period of oscillation of the structure, which therefore becomes prone to damage and failure. Previous forensic studies have documented the relative importance of impulsive loads on deck suspended structure, demonstrating the need to assess the effect of wave impacts on both the stability and the integrity of structural members since the early stages of the design. This requires the estimation of the dynamic characteristics of the loading pattern, and in particular the wave impulse and corresponding impact maxima and rise times. Based on the conservation of momentum, functional relationships between these parameters have been identified since pioneering work dating back to the late '30s of the 20th century. The complexity of the loading process, however, results in a significantly large variability of wave impact maxima and rise times even under similar conditions, suggesting the need for a probabilistic approach to the definition of the relationship between these two variables, to be applied when estimating the dynamic properties of wave for use in structural analysis of coastal structures. In the recent past, some effort has been made to identify functional relationships between such quantities; these require the assessment of the conditional quantiles (or similarly the conditional distribution) of wave impact maxima given the rise times. In this paper, we compare three different statistical methods proposed in the literature to accomplish this task, in order to assess the reliability of the approach and suggest guidelines for practical applications. A copula-based method, Generalized Additive Models for Location, Scale and Shape (GAMLSS), and quantile regression are applied to measurements from large-scale 3-dimensional physical model tests. The investigation suggests that quantile regression gives the simplest results to be used in practice; copula approach and GAMLSS are possible alternative when semi-parametric or fully parametric modeling is needed.  相似文献   
102.
An accurate structure refinement, using single-crystal X-ray diffraction data, on natural α- and β-dimorphites collected at Solfatara di Pozzuoli, in the Phlegraean Fields, near Naples and at Vesuvius (Italy) is reported. Theoretical calculations at various levels of sophistication have been used to calculate molecular vibrational frequencies and gas-phase specific heats, to analyze the crystal packing, and to estimate lattice energies of both phases. All computational methods contribute to demonstrate that the β-phase is the thermodynamically stable one at room temperature.  相似文献   
103.
Oxygen fugacity ( $ f_{{{\text{O}}_{ 2} }} $ f O 2 ) is a fundamental but little known intensive variable in mantle processes. It influences the P/T position of a mantle solidus and the composition of mantle-derived melts and fluids and constrains mantle-core equilibria and a number of geophysical properties of the mantle. An important source of information on oxidation states is the ferric–ferrous iron ratio in mantle spinels. Since the magnetite component is low in mantle spinels, normal analytical errors translate into considerable $ f_{{{\text{O}}_{ 2} }} $ f O 2 uncertainties. In this study, we analyzed the Fe3+–Fetot ratio of chromites present as inclusions in diamond and other mantle-related occurrences by point-source Mössbauer spectroscopy using single-crystal absorbers as well as conventional Mössbauer spectroscopy using powder absorbers. The studied spinels have been previously analyzed by single-crystal X-ray diffraction and electron microprobe. The ferric–ferrous ratios found are normally similar to the different techniques apart from some samples where a large number of grains have been used for the analyses (powder absorbers). The general agreement between the different techniques allows us to conclude that the studied chromites are stoichiometric. However, conventional Mössbauer spectroscopy on powder absorbers should be conducted with great care, since the method requires a relatively large amount of sample material. Spinel frequently occurs as small grains, and the large number of crystals required may possess different degrees of oxidation/alteration and, consequently, different ferric–ferrous ratio leading to possible errors in the interpretation of the results.  相似文献   
104.
A case study of a debris slide (estimated volume of about 35,000 m3) is described in this paper. This slide occurred in April 2009 in the North Western Italian Alps (Aosta valley) and damaged the SR25 road along the Valgrisenche valley. Ground investigations started with severe safety and logistic issues being posed. Given the need to open as soon as possible the road, the design of the landslide stabilization works was carried out using a “design as you go” approach. The stabilization measures were conceived to be flexible in order to allow for changes and integration during construction, in line with the progressive refinement of the geological–geotechnical slope model being developed. Back analysis by means of the limit equilibrium method (LEM) and the finite element method (FEM) was used. Groundwater level rise following heavy rainfall and spring snow melting was found to be the main cause of the debris slide. The stabilization works were designed by using both the LEM and FEM methods. The stability conditions of the engineered slope were assessed based on the available performance monitoring data.  相似文献   
105.
Out-of-equilibrium crystallization often produces complex compositional variability in minerals, generating zoning and other mixing phenomena. The appropriate microchemical characterization of the resulting out-of-equilibrium patterns is of critical importance in understanding the overall physical and chemical properties of the host crystalline phases. In this framework, the modeling of compositional changes assumes a fundamental role. However, when compositional data are used, their management with standard exploratory, statistical, graphical, and numerical tools may give misleading results attributable to the phenomenon of induced correlations. To avoid these problems, methods able to extract compositional data from their constrained space (the simplex) in order to apply standard statistics, have to be adopted. As an alternative, the use of tools having properties able to work in the simplex geometry has to be considered. A luzonite single crystal (ideal composition, Cu3AsS4) exhibiting concentric and sector zoning was studied using electron probe microanalysis in order to understand the mechanisms which give rise to chemical variability and conditions in the developing environment. Compositional variations were determined by collecting data along three different transects. The major and minor elements (Cu, As, S, Fe, Sb, Sn) were analyzed with the aim of characterizing their patterns of association in the crystal and, hence, crystal evolution. The whole covariance structure as well as the chemical relationships between the successive zones was investigated by means of compositional methods, considering both data transformation and the stay in the simplex approach. Results indicate that the crystal grew under quiescent conditions, where chemical control was primarily exercised by the mineral’s surface and only minor effects were due to changes in the composition of the surrounding fluid. Consequently, an oscillatory uptake of chemical components occurred in which a competition between famatinite-like (Cu3SbS4) and kuramite-like (Cu3SnS4) domains characterized the As-poor zones.  相似文献   
106.
Résumén

La découverte, dans le Nord des Marches (Italie), de nouveaux gisements de Poissons Cyprinodontidae appartenant à l’espèce Aphanius crassicaudus (AGASSIZ), conduit à réexaminer, à la lumière des données lithostratigraphiques, la signification géodynamique des ichthyofaunes messiniennes de ce secteur de l’Apennin. Après avoir précisé la position stratigraphique et la répartition paléogéographique des gisements étudiés, les auteurs montrent que le développement des faunes à Aphanius crassicaudus (AGASSIZ) dans les eaux saumâtres du domaine continental n’implique pas la disparition corrélative du milieu marin. En effet, certains genres marins sont parfois présents à côté de cette espèce, comme c’est le cas dans le gisement de Pésaro. Les auteurs contestent en outre l’interprétation selon laquelle le fait qu’aucune ichthyofaune marine ne soit connue dans le Messinien supérieur d’Italie puisse suffire à conclure que la Méditerranée était asséchée pendant le dépôt de la « Formation à colombacci »  相似文献   
107.
108.
Sandy shores on the West coast of the North Adriatic Sea are extensively protected by different types of defence structures to prevent coastal erosion. Coastal defence schemes modify the hydrodynamic regime, the sediment structure and composition thus affecting the benthic assemblages. This study examines the effectiveness in detecting changes in soft bottom assemblages caused by coastal defence structures by using different levels of taxonomic resolution, polychaetes and/or bivalves as surrogates and different data transformations. A synoptic analyses of three datasets of subtidal benthic macrofauna used in studies aimed at assessing the impact of breakwaters along the North Adriatic coast has been done. Analyses of similarities and correlations between distance matrices were done using matrices with different levels of taxonomic resolution, and with polychaetes or bivalves data alone. Lentidium mediterraneum was the most abundant species in all datasets. Its abundance was not consistently related to the presence of defence structures. Moreover, distribution patterns of L. mediterraneum were masking the structure of the whole macrofaunal assemblages. Removal of L. mediterraneum from the datasets allowed the detection of changes in benthic assemblages due to coastal defences. Analyses on different levels of taxonomic resolution showed that the level of family maintained sufficient information to detect the impacts of coastal defence structures on benthic assemblages. Moreover, the outcomes depended on the transformation used. Patterns of distribution of bivalves, used as surrogates, showed low correlations with the patterns of the total macrofaunal species assemblages. Patterns of polychaetes, if identified to the species or genus level showed higher correlations with the whole dataset. However, the identification of polychaetes to species and genus level is as costly as the identification of all macrobenthic taxa at family level.This study provided additional evidences that taxonomic sufficiency is a useful tool in environmental monitoring, also in investigations on the impacts of coastal defence structures on subtidal macrofauna. The use of coarser taxonomic level, being time-efficient, would allow improving sampling designs of monitoring programs by increasing replication in space and time and by allowing long term monitoring studies.  相似文献   
109.
A comprehensive parametric approach to study the probability distribution of rainfall data at scales of hydrologic interest (e.g. from few minutes up to daily) requires the use of mixed distributions with a discrete part accounting for the occurrence of rain and a continuous one for the rainfall amount. In particular, when a bivariate vector (X, Y) is considered (e.g. simultaneous observations from two rainfall stations or from two instruments such as radar and rain gauge), it is necessary to resort to a bivariate mixed model. A quite flexible mixed distribution can be defined by using a 2-copula and four marginals, obtaining a bivariate copula-based mixed model. Such a distribution is able to correctly describe the intermittent nature of rainfall and the dependence structure of the variables. Furthermore, without loss of generality and with gain of parsimony this model can be simplified by some transformations of the marginals. The main goals of this work are: (1) to empirically explore the behaviour of the parameters of marginal transformations as a function of time scale and inter-gauge distance, by analysing data from a network of rain gauges; (2) to compare the properties of the regression curves associated to the copula-based mixed model with those derived from the model simplified by transformations of the marginals. The results from the investigation of transformations’ parameters are in agreement with the expected theoretical dependence on inter-gauge distance, and show dependence on time scale. The analysis on the regression curves points out that: (1) a copula-based mixed model involves regression curves quite close to some non-parametric models; (2) the performance of the parametric regression decreases in the same cases in which non-parametric regression shows some instability; (3) the copula-based mixed model and its simplified version show similar behaviour in term of regression for mid-low values of rainfall. An erratum to this article can be found at  相似文献   
110.
3-D images of P velocity and P - to S -velocity ratio have been produced for the upper crust of the Friuli area (northeastern Italy) using local earthquake tomography. The data consist of 2565 P and 930 S arrival times of high quality. The best-fitting V P and V P / V S 1-D models were computed before the 3-D inversion. V P was measured on two rock samples representative of the investigated upper layers of the Friuli crust. The tomographic V P model was used for modelling the gravity anomalies, by converting the velocity values into densities along three vertical cross-sections. The computed gravity anomalies were optimized with respect to the observed gravity anomalies. The crust investigated is characterized by sharp lateral and deep V P and V P / V S anomalies that are associated with the complex geological structure. High V P / V S values are associated with highly fractured zones related to the main faulting pattern. The relocated seismicity is generally associated with sharp variations in the V P / V S anomalies. The V P images show a high-velocity body below 6 km depth in the central part of the Friuli area, marked also by strong V P / V S heterogeneities, and this is interpreted as a tectonic wedge. Comparison with the distribution of earthquakes supports the hypothesis that the tectonic wedge controls most of the seismicity and can be considered to be the main seismogenic zone in the Friuli area.  相似文献   
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