Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO₂ levels     

Shane M. Ohline  Malcolm R. Reid  Shamus L.G. Husheer  Kim I. Currie  Keith A. Hunter 《Marine Chemistry》2007

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].  相似文献   

Muddy-bottom meiofauna responses to metal concentrations and organic enrichment in New Caledonia South-West Lagoon   总被引：2，自引：0，他引：2  

A.G. Dalto  A. Grmare  A. Dinet  D. Fichet 《Estuarine, Coastal and Shelf Science》2006,67(4):629-644

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Diversity and community structure of epibenthic invertebrates and fish in the North Sea   总被引：5，自引：3，他引：5  

Callaway  R.; Alsvag  J.; de Boois  I.; Cotter  J.; Ford  A.; Hinz  H.; Jennings  S.; Kroncke  I.; Lancaster  J.; Piet  G.; Prince  P.; Ehrich  S. 《ICES Journal of Marine Science》2002,59(6):1199-1214

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Structural monitoring of offshore platforms using impulse and relaxation response     

Lalu Mangal  V. G. Idichandy  C. Ganapathy 《Ocean Engineering》2001,28(6)

Monitoring offshore platforms, long span bridges, high rise buildings, TV towers and other similar structures is essential for ensuring their safety in service. Continuous monitoring assumes even greater significance in the case of offshore platforms, which are highly susceptible to damage due to the corrosive environment and the continuous action of waves. Also, since a major part of the structure is under water and covered by marine growth, even a trained diver cannot easily detect damage in the structure. In the present work, vibration criterion is adopted for structural monitoring of jacket platforms. Artificial excitation of these structures is not always practicable and ambient excitation due to wind and waves may not be sufficient for collecting the required vibration data. Alternate methods can be adopted for the same purpose, for example, the application of an impact or a sudden relaxation of an applied force for exciting the structure. For jacket platforms, impact can be applied by gently pushing the structure at the fender while relaxation can be accomplished by pulling the structure and then suddenly releasing it using a tug or a supply vessel in both cases. The present study is an experimental investigation on a laboratory model of a jacket platform, for exploring the feasibility of adapting vibration responses due to impulse and relaxation, for structural monitoring. Effects of damage in six members of the platform as well as changes in deck masses were studied. A finite element model of the structure was used to analyze all the cases for comparison of the results as well as system identification. A data acquisition and analysis procedure for obtaining the response signatures of the platform due to the impulse and relaxation procedure was also developed for possible adoption in on-line monitoring of offshore platforms. From the study, it has been concluded that both impulse and relaxation responses are useful tools for monitoring offshore jacket platforms. The present work forms the basis for the development of an automated, on-line monitoring system for offshore platforms, using neural networks.  相似文献   

Carbon-isotope composition of sediments from the Gulf of Papua     

M. I. Bird  A. R. Chivas  G. J. Brunskill 《Geo-Marine Letters》1995,15(3-4):153-159

Rivers draining into the Gulf of Papua (GOP) from the Papua New Guinea mainland deliver approximately 340 × 10⁶ t yr^–1 of sediment to the marine environment. The terrestrially derived sediment contains 1.1 ± 0.2% particulate organic carbon with a carbon-isotope composition of –26.5 ± 0.2, and amounts to 3.7 ± 0.7 × 10⁶ t yr^–1. The carbon-isotope composition of sediments in the Gulf of Papua indicates that 40% of the sediment cover contains 75% or more terrestrially derived carbon. Suspended sediments that are transported beyond the delta complex of the Fly River are transported north and northwest, augmented by sediments from other rivers along the coast of the GOP. The carbon-isotope results suggest that a significant quantity of terrestrially derived sediment escapes from the GOP, either along the coastlines to east and west or into the deep ocean via the Moresby and Pandora troughs. Little sediment travels south onto the Great Barrier Reef shelf. Extrapolating the results from this study to the region of Oceania suggests a total flux of particulate organic carbon to the world's oceans from the islands of Oceania of ~ 90 × 10⁶ t yr^–1 or twice the flux of riverine POC from the major rivers of North America, South America, and Africa combined. While such a calculation must be considered illustrative only, the similar tectonic, geomorphologic, and climatic features of the islands of Oceania suggest that the calculation is unlikely to be grossly in error and that the rivers of Oceania therefore represent a major but poorly documented source of sediment and organic carbon to the global ocean.  相似文献   

Cometary collisions and the dark material on Iapetus     

Ronald G. Tabak  Warren M. Young 《Earth, Moon, and Planets》1989,44(3):251-264

Iapetus (S8) is unique in our solar system in that the albedo of its leading hemisphere is only 0.05 while that of the trailing side is 0.5. Several existing hypotheses are examined and found inadequate. Photometric studies of the dark side are compared to comet nuclei and class D asteroids. It is hypothesized that in the last 10⁶–10⁸ yrs the leading side suffered a high-velocity collision with a cometary body of mass 10¹³–10¹⁵ kg and traveling at a speed of 20 km s^–1. About 5–16% of the excavated material was ejected into space, where the vaporized ices dissipated while the dark carbonaceous/silicate material was reaccreted on the leading side. The collision, although not sufficient to break Iapetus' tidal lock, resulted in a period of oscillation of about 5 yr. Until tidal friction reasserted a lock, the oscillation gave rise to the longitude effect, viz., the observed fact that the dark material covers more than 220 of longitude but only 110 of latitude.  相似文献   

Interpretation of a special fine structure in type-IV solar radio bursts     

G. Mann  K. Baumgaertel  G. P. Chernov  M. Karlický 《Solar physics》1989,120(2):383-391

A special fine structure (slowly drifting chains of narrowband fiber bursts), firstly observed during the solar type-IV radio burst on April 24, 1985, is interpreted as the radio signature of whistler waves periodically excited by a switch-on/switch-off process of a loss-cone instability in a localized wave packet of the fast magnetoacoustic mode.  相似文献   

Motions in the field of two rotating magnetic dipoles. III: Zero-velocity curves and surfaces     

C. L. Goudas  M. leftaki  E. G. Petsagourakis 《Celestial Mechanics and Dynamical Astronomy》1989,47(1):1-14

The zero-velocity curves and surfaces created by two parallel or antiparallel magnetic dipoles moving on concentric circles are computed. It is found that for all combinations of values of the mass parameter µ and the ratio of the magnitudes of the magnetic moments of the two dipoles, there exist closed regions inside of which charged particles are permanently trapped.  相似文献   

The University of Durham Southern Hemisphere VHE gamma ray telescope     

K. T. Brazier  A. Carramiñana  P. M. Chadwick  T. R. Currell  N. A. Dipper  E. W. Lincoln  V. G. Mannings  T. J. L. McComb  K. J. Orford  S. M. Rayner  K. E. Turver 《Experimental Astronomy》1989,1(2):77-99

The design of very high energy (VHE) gamma ray telescopes is discussed and it is shown that a triple-mirror telescope operating in threefold fast coincidence provides an effective instrument. The design, construction and operation of a large VHE gamma ray telescope with an energy threshold of 300 GeV (at the zenith) and incorporating several novel features is described. The use of a coincidence guard ring technique is shown to result in the rejection of about 50% of the off-source (proton) events which form a high background and limit the sensitivity of such telescopes.  相似文献   

Helium resonance lines in the flare of 15 June, 1973     

Jason G. Porter  Katharine B. Gebbie  Laurence J. November 《Solar physics》1989,120(2):309-341

Time sequences of He i and He ii resonance line intensities at several sites within the flare of 15 June, 1973 are derived from observations obtained with the Naval Research Laboratory's Slitless Spectroheliograph on Skylab. The data are compared with predictions in six model flare atmospheres based on two values for the heating rate and three for the flux of photoionizing coronal X-rays and EUV. A peak ionizing flux more than 10³ times that in the quiet Sun is indicated. For most conditions in flare kernels the He ii L and L lines are found to be formed by collisional excitation, thereby contributing to the local cooling of the plasma at temperatures above 6 × 10⁴ K. Emission in the higher Lyman lines is generally the result of a mixture of collisional excitation at these temperatures and photoionization and recombination at temperatures near 2.5 × 10⁴ K. We discuss implications for the common practice of deriving stellar coronal fluxes from He ii 1640 Å fluxes assuming dominance of the recombination mechanism.Chief, Quantum Physics Division, National Institute of Standards and Technology.Operated jointly by the National Institute of Standards and Technology and the University of Colorado.Operated by the National Optical Astronomy Observatories of the Association of Universities for Research in Astronomy, Inc. under contract with the National Science Foundation.  相似文献